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    • 93. 发明授权
    • Transferring dyes for thermal printing: tri-cyano-vinyl aniline dyes
    • 用于热敏印刷的转移染料:三氰基乙烯基苯胺染料
    • US4999026A
    • 1991-03-12
    • US384095
    • 1989-07-24
    • Bernhard AlbertKarl-Heinz EtzbachRuediger Sens
    • Bernhard AlbertKarl-Heinz EtzbachRuediger Sens
    • B41M5/385B41M5/26B41M5/388B41M5/39C09B23/14C09B29/03C09B29/033C09D5/26D06P5/13
    • B41M5/385B41M5/3854B41M5/388Y10S8/922
    • Dyes are transferred from a carrier by sublimation/vaporization to plastic-coated papers by a process in which the dyes used are of the general formula (I) ##STR1## where A is D--N.dbd.N-- or ##STR2## R.sup.1 and R.sup.2 are each hydrogen, alkyl, alkoxy, alkylthio or halogen and R.sup.1 and R together may furthermore form a 5-membered or 6-membered heterocyclic ring, and R and R' independently of one another are each hydrogen, phenyl which is unsubstituted or substituted by methyl or methoxy, or C.sub.5 - or C.sub.6 -cycloalkyl or C.sub.1 -C.sub.6 -alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.2 -C.sub.5 -alkanoyloxy, C.sub.1 -C.sub.4 -alkoxycarbonyloxy, C.sub.1 -C.sub.4 -alkoxy-C.sub.2 -or C.sub.3 -alkoxycarbonyloxy, hydroxyl, cyano, halogen, phenyl or C.sub.5 - or C.sub.6 -cycloalkyl, or ##STR3## is a 5-membered or 6-membered saturated heterocyclic ring where D is a radical of a diazo component of the thiophene, thiazole, isothiazole or 1,2,4-thiadiazole series and R.sup.3 is hydrogen or CN.In the process, the dyes (I) give strong dyeings which have good light fastness and are resistant to chemical substances.
    • 染料通过升华/蒸发从载体转移到塑料涂布的纸上,其中使用的染料具有通式(I)的化合物(I),其中A是DN = N-或R1和 R 2各自为氢,烷基,烷氧基,烷硫基或卤素,R 1和R可以另外形成5元或6元杂环,R和R'彼此独立地为氢,未取代或取代的苯基 C 1 -C 4 - 烷氧羰基,C 2 -C 5 - 烷酰氧基,C 1 -C 4 - 烷氧基羰基氧基,C 1 -C 4 - 烷氧基羰基氧基,C 1 -C 4 - C 4-烷氧基-C 2 - 或C 3 - 烷氧基羰基氧基,羟基,氰基,卤素,苯基或C 5 - 或C 6 - 环烷基,或者是5元或6元饱和杂环,其中D是重氮基团 噻吩,噻唑,异噻唑或1,2,4-噻二唑系列的组分,R 3为氢或CN。 在此过程中,染料(I)产生强烈的染色,耐光性好,耐化学物质。
    • 94. 发明授权
    • Azo dyes with a diazo component of the 3-amino thiophene series and a
coupling component of the pyridine, pyridone or pyrazole series
    • 具有3-氨基噻吩系列的重氮组分的偶氮染料和吡啶,吡啶酮或吡唑系的偶联组分
    • US4994564A
    • 1991-02-19
    • US269646
    • 1988-11-10
    • Karl-Heinz EtzbachHelmut ReicheltGuenter HansenErnst SchefczikHelmut HagenGunther Lamm
    • Karl-Heinz EtzbachHelmut ReicheltGuenter HansenErnst SchefczikHelmut HagenGunther Lamm
    • C09B29/09C09B29/00C09B29/42C09B29/48
    • C09B29/0059C09B29/3621C09B29/3634C09B29/3656
    • Thien-3-ylazo dyes of the formula: ##STR1## where X is cyano, nitro, C.sub.1 -C.sub.6 -alkanoyl, substituted or unsubstituted benzoyl, substituted or unsubstituted phenyl or the radical COOR.sup.1 or CONR.sup.1 R.sup.2 where R.sup.1 and R.sup.2 are identical or different and each is independently of each other substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, C.sub.3 -C.sub.4 -alkenyl, substituted or unsubstituted phenyl or together with the nitrogen atom linking them a 5- or 6-membered saturated heterocyclic radical, and R.sup.2 may additionally be hydrogen, Y is hydrogen, cyano, C.sub.1 -C.sub.6 -alkanoyl, substituted or unsubstituted benzoyl, C.sub.1 -C.sub.4 -alkylsulfonyl, substituted or unsubstituted phenylsulfonyl, substituted or unsubstituted phenyl or the radical COOR.sup.1 or CONR.sup.1 R.sup.2 where R.sup.1 and R.sup.2 are each as defined above, Z is hydrogen, substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl, substituted or unsubstituted phenyl, substituted or unsubstituted C.sub.1 -C.sub.6 -alkylthio, substituted or unsubstituted phenylthio, substituted or unsubstituted C.sub.1 -C.sub.6 -alkylsulfonyl or phenylsulfonyl or together with the radical Y a fused benzo ring which may be substituted, and K is the radical of a coupling component of the 2,6-diaminopyridine, 6-hydroxypyrid-2-one or 5-aminopyrazole series, are used for dyeing synthetic fiber materials, in particular synthetic polyesters, in yellow to red shades and are notable for good light fastness, fastness to dry heat setting and pleating and for good affinity.
    • 噻吩-3-基偶氮染料,其结构式如下:其中X为氰基,硝基,C 1 -C 6烷酰基,取代或未取代的苯甲酰基,取代或未取代的苯基或基团COOR1或CONR1R2,其中R 1和R 2相同或不同, 各自独立地为取代或未取代的C 1 -C 8 - 烷基,C 5 -C 7 - 环烷基,C 3 -C 4 - 烯基,取代或未取代的苯基或与连接它们的氮原子一起形成5-或6-元饱和杂环基, R 2可另外为氢,Y为氢,氰基,C 1 -C 6烷酰基,取代或未取代的苯甲酰基,C 1 -C 4 - 烷基磺酰基,取代或未取代的苯基磺酰基,取代或未取代的苯基或基团COOR1或CONR1R2,其中R1和R2为 Z是氢,取代或未取代的C 1 -C 8 - 烷基,取代或未取代的苯基,取代或未取代的C 1 -C 6 - 烷硫基,取代或未取代的苯硫基,取代或未取代的C 1 -C 6 - 烷基磺酰基 或与苯基磺酰基或与基团Y一起可以被取代的稠合苯并环,K是2,6-二氨基吡啶,6-羟基吡啶-2-酮或5-氨基吡唑系列的偶联组分的基团 用于将合成纤维材料,特别是合成聚酯染色为黄色至红色,并且具有良好的耐光性,耐干燥定型和打褶的牢度以及良好的亲和力。
    • 95. 发明授权
    • Dyes containing 3,4-disubstituted-2-diaza-thiophene radicals
    • 含有3,4-取代-2-二氮杂-苯并呋喃的染料
    • US4952681A
    • 1990-08-28
    • US205359
    • 1988-07-27
    • Guenter HansenErnst SchefczikKarl-Heinz EtzbachHelmut ReicheltHermann Loeffler
    • Guenter HansenErnst SchefczikKarl-Heinz EtzbachHelmut ReicheltHermann Loeffler
    • C09B29/00C09B62/35C09B29/033C09B29/33C09B29/36
    • C09B29/0059
    • Compounds of the formula I ##STR1## where X is fluorine, chlorine, bromine, SO.sub.2 E or unsubstituted or substituted hydroxyl or mercapto, E is alkyl, alkenyl, cycloalkyl, aralkyl, aryl, chlorine or unsubstituted or substituted hydroxyl or amino, Y is cyano, nitro, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl, T is hydrogen, C.sub.1 -C.sub.4 -alkyl, a radical which can be introduced by electrophilic substitution or a radical of the formula --CH.dbd.B, in which B is a radical of a methylene-active compound or of an amine, and K is a radical of a coupling component, are disclosed. They are useful for dyeing synthetic fibers or plastics.
    • 1.式I的化合物参见图示:EP0201896,P71,F3,其中X是氟,氯,溴,SO2E,OH,OCH3,OC2H5,OC3H7,OC4H9,OCH2 C6H5,OC6H11,OC6H5 ,OC 6 H 4 CH 3,OC 6 H 4 Cl,SH,SCH 3,SC 2 H 5,SC 3 H 7,SC 4 H 9,SCH 2 C 6 H 5,SC 2 H 4 OH,SCH 2 COOCH 3,SCH 2 COOC 2 H 5,SC 6 H 11,SC 6 H 5或SC 6 H 4 CH 2,E是烷基 ,链烯基,环烷基,芳烷基,芳基,氯,OH,CH3O,C2H5O,C3H7O,C4H9O,C6H5 -CH2O,C6H5 -CH2 -CH2O,C6H5O,CIC6H4O, CH 3 C 4 H 4 O,NH 2,NHCH 3,N(CH 3)2,NHC 2 H 5,N(C 2 H 5)2,NCH 4 H 9,N(C 4 H 9)2,NHC 6 H 5,NHC 6 H 4 -CH 3,NHC 6 H 4 Cl或NCH 3 C 6 H 5 ,Y是氰基,硝基,烷酰基,芳酰基,烷基磺酰基,芳基磺酰基,羧基,羧酸酯基或未取代或取代的氨基甲酰基,T是氢,C 1 -C 4烷基,NO,NO 2,SO 3 H,CHO,CN, ,C 2 H 5 CO,C 6 H 5 CO,CH 3 SO 2,C 2 H 5 SO 2,C 6 H 5 SO 2或式-CH = B的基团,其中B是亚甲基活性化合物或胺的基团,K是 激进或 耦合部件。
    • 96. 发明授权
    • Trisazo dyes
    • 三唑类染料
    • US4952678A
    • 1990-08-28
    • US113910
    • 1987-10-29
    • Karl-Heinz Etzbach
    • Karl-Heinz Etzbach
    • C09B35/35C09B35/362C09K19/60
    • C09B35/35C09K19/601
    • Trisazo dyes of the formula ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and each, independently of the others, is hydrogen, methyl, ethyl, methoxy or chlorine, R.sup.5 is C.sub.2 -C.sub.4 -alkyl, X is C.sub.1 -C.sub.24 -mono- or dialkylamino, monobenzylamino, mono-(phenyl-ethyl)-amino, monophenylamino, N-(C.sub.1 -C.sub.12 -alkyl)-N-benzylamino, N-(C.sub.1 -C.sub.12 -alkyl)-N-(phenylethyl)amino or N-(C.sub.1 -C.sub.12 -alkyl)-N-phenylamino or each of the phenyls substituted by C.sub.1 -C.sub.12 -alkyl, cyclo-hexyl, 4-(C.sub.1 -C.sub.12 -alkyl)cyclohexyl, C.sub.1 -C.sub.24 -alkyloxy, phenoxy or C.sub.1 -C.sub.24 -alkanoyloxyl, or is OR, where R is C.sub.1 -C.sub.24 -alkyl, unsubstituted or C.sub.1 -C.sub.12 -alkyl-, cyclohexyl-, 4-(C.sub.1 -C.sub.12 -alkyl)cyclohexyl-, C.sub.1 -C.sub.24 -alkoxy-, phenoxy- or C.sub.1 -C.sub.24 -alkanoyl-oxy-substituted benzyl or phenylethyl, and A is a radical of the formula ##STR2## where R and X each have the above-mentioned meanings, and R.sup.6 is hydrogen or C.sub.1 -C.sub.14 -alkyl, R.sup.7 is hydrogen, methyl, ethyl, methoxy or chlorine, R.sup.8 is hydrogen, methyl, hydroxy or C.sub.1 -C.sub.8 -alkoxy and R.sup.9 is hydrogen or methyl, or the rings B, or B and C being benzofused, are used in liquid crystalline media and for dyeing synthetic polymers.
    • 其中R 1,R 2,R 3和R 4相同或不同并且各自独立地为氢,甲基,乙基,甲氧基或氯,式为“IMAGE”的三唑类染料为R5,C为C2-C4烷基,X为C1 (C 1 -C 12烷基)-N-苄基氨基,N-(C 1 -C 12烷基)-N-(苯基乙基)-N-(苯基 - 乙基) - 氨基, 氨基或N-(C 1 -C 12 - 烷基)-N-苯基氨基或被C 1 -C 12 - 烷基,环己基,4-(C 1 -C 12 - 烷基)环己基,C 1 -C 24 - 烷氧基, 苯氧基或C 1 -C 24 - 烷酰氧基,或是OR,其中R是C 1 -C 24 - 烷基,未取代的或C 1 -C 12 - 烷基 - ,环己基 - ,4-(C 1 -C 12 - 烷基)环己基 - ,C 1 -C 24 - 烷氧基 - 苯氧基 - 或C 1 -C 24 - 烷酰基 - 氧基取代的苄基或苯基乙基,A是下式的基团,其中R和X各自具有上述含义,R6是氢 或C 1 -C 14 - 烷基,R 7是氢,甲基,乙基,甲氧基或氯,R 8是氢,甲基,羟基或C 1 -C 8 - 烷氧基,R 9是氢或甲基 或环B或B和C为苯并稠合,用于液晶介质和染色合成聚合物。