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1. 发明授权

US5162045A Transferring dyes for thermal printing 失效
标题翻译：转印用于热敏印刷的染料
公开(公告)号：US5162045A
公开(公告)日：1992-11-10
申请号：US606840
申请日：1990-10-31
申请人： Bernhard Albert , Karl-Heinz Etzbach , Ruediger Sens
发明人： Bernhard Albert , Karl-Heinz Etzbach , Ruediger Sens
IPC分类号： B41M5/26 , B41M5/385 , B41M5/388 , C09B29/03 , C09B29/033 , D06P5/13
CPC分类号： B41M5/385 , B41M5/3854 , B41M5/388 , Y10S8/922
摘要： Dyes are transferred from a carrier by sublimation/vaporization to plastic-coated papers by a process in which the dyes used are of the general formula (I) ##STR1## where A is D--N=N-- or ##STR2## R.sup.1 and R.sup.2 are each hydrogen, alkyl, alkoxy, alkylthio or halogen and R.sup.1 and R together may furthermore form a 5-membered or 6-membered heterocyclic ring, and R and R' independently of one another are each hydrogen, phenyl which is unsubstituted or substituted by methyl or methoxy, or C.sub.5 - or C.sub.6 -cycloalkyl or C.sub.1 -C.sub.6 -alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.2 -C.sub.5 -alkanoyloxy, C.sub.1 -C.sub.4 -alkoxycarbonyloxy, C.sub.1 -C.sub.4 -alkoxy-C.sub.2 - or C.sub.3 -alkoxycarbonyloxy, hydroxyl, cyano, halogen, phenyl or C.sub.5 - or C.sub.6 cycloalkyl, or ##STR3## is a 5-membered or 6-membered saturated heterocyclic ring where D is a radical of a diazo component of the thiophene, thiazole, isothiazole or 1,2,4-thiadiazole series and R.sup.3 is hydrogen or CN.In the process, the dyes (I) give strong dyeings which have good light fastness and are resistant to chemical substances.
摘要翻译：染料通过升华/蒸发从载体转移到塑料涂布的纸上，其中使用的染料具有通式（I）的化合物（I），其中A是DN = N-或R1和 R 2各自为氢，烷基，烷氧基，烷硫基或卤素，R 1和R可以另外形成5元或6元杂环，R和R'彼此独立地为氢，未取代或取代的苯基 C 1 -C 4 - 烷氧羰基，C 2 -C 5 - 烷酰氧基，C 1 -C 4 - 烷氧基羰基氧基，C 1 -C 4 - 烷氧基羰基氧基，C 1 -C 4 - C 4 - 烷氧基-C 2 - 或C 3 - 烷氧基羰基氧基，羟基，氰基，卤素，苯基或C 5 - 或C 6环烷基，或者IMAGE是5元或6元饱和杂环，其中D是重氮组分噻吩，噻唑，异噻唑或1,2,4-噻二唑系列，R3为氢或CN。在此过程中，染料（I）产生强烈的染色，耐光性好，耐化学物质。

2. 发明授权

US4999026A Transferring dyes for thermal printing: tri-cyano-vinyl aniline dyes 失效
标题翻译：用于热敏印刷的转移染料：三氰基乙烯基苯胺染料
公开(公告)号：US4999026A
公开(公告)日：1991-03-12
申请号：US384095
申请日：1989-07-24
申请人： Bernhard Albert , Karl-Heinz Etzbach , Ruediger Sens
发明人： Bernhard Albert , Karl-Heinz Etzbach , Ruediger Sens
IPC分类号： B41M5/385 , B41M5/26 , B41M5/388 , B41M5/39 , C09B23/14 , C09B29/03 , C09B29/033 , C09D5/26 , D06P5/13
CPC分类号： B41M5/385 , B41M5/3854 , B41M5/388 , Y10S8/922
摘要： Dyes are transferred from a carrier by sublimation/vaporization to plastic-coated papers by a process in which the dyes used are of the general formula (I) ##STR1## where A is D--N.dbd.N-- or ##STR2## R.sup.1 and R.sup.2 are each hydrogen, alkyl, alkoxy, alkylthio or halogen and R.sup.1 and R together may furthermore form a 5-membered or 6-membered heterocyclic ring, and R and R' independently of one another are each hydrogen, phenyl which is unsubstituted or substituted by methyl or methoxy, or C.sub.5 - or C.sub.6 -cycloalkyl or C.sub.1 -C.sub.6 -alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.2 -C.sub.5 -alkanoyloxy, C.sub.1 -C.sub.4 -alkoxycarbonyloxy, C.sub.1 -C.sub.4 -alkoxy-C.sub.2 -or C.sub.3 -alkoxycarbonyloxy, hydroxyl, cyano, halogen, phenyl or C.sub.5 - or C.sub.6 -cycloalkyl, or ##STR3## is a 5-membered or 6-membered saturated heterocyclic ring where D is a radical of a diazo component of the thiophene, thiazole, isothiazole or 1,2,4-thiadiazole series and R.sup.3 is hydrogen or CN.In the process, the dyes (I) give strong dyeings which have good light fastness and are resistant to chemical substances.
摘要翻译：染料通过升华/蒸发从载体转移到塑料涂布的纸上，其中使用的染料具有通式（I）的化合物（I），其中A是DN = N-或R1和 R 2各自为氢，烷基，烷氧基，烷硫基或卤素，R 1和R可以另外形成5元或6元杂环，R和R'彼此独立地为氢，未取代或取代的苯基 C 1 -C 4 - 烷氧羰基，C 2 -C 5 - 烷酰氧基，C 1 -C 4 - 烷氧基羰基氧基，C 1 -C 4 - 烷氧基羰基氧基，C 1 -C 4 - C 4-烷氧基-C 2 - 或C 3 - 烷氧基羰基氧基，羟基，氰基，卤素，苯基或C 5 - 或C 6 - 环烷基，或者是5元或6元饱和杂环，其中D是重氮基团噻吩，噻唑，异噻唑或1,2,4-噻二唑系列的组分，R 3为氢或CN。在此过程中，染料（I）产生强烈的染色，耐光性好，耐化学物质。

3. 发明授权

US5580980A N-aminopyridone dyes 失效
标题翻译： N-氨基吡啶酮染料
公开(公告)号：US5580980A
公开(公告)日：1996-12-03
申请号：US140021
申请日：1993-11-01
申请人： Karl-Heinz Etzbach , Ernst Schefczik , Ruediger Sens , Matthias Wiesenfeldt
发明人： Karl-Heinz Etzbach , Ernst Schefczik , Ruediger Sens , Matthias Wiesenfeldt
IPC分类号： B41M5/385 , B41M5/26 , B41M5/388 , B41M5/39 , C07B57/00 , C07D213/89 , C07D265/36 , C09B23/00 , C09B23/02 , C09B23/04 , C09B53/00 , C09B55/00 , C09B57/00 , C07D215/38 , C07D277/38
CPC分类号： B41M5/3856 , C09B23/02 , C09B23/04 , C09B55/009 , B41M5/3854 , B41M5/39
摘要： Pyridone dyes useful for thermal transfer have the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, Y, X and Z are defined in the specification.
摘要翻译： PCT No.PCT / EP92 / 00505 Sec。 371日期：1993年11月1日 102（e）1993年11月1日PCT PCT。出版物WO92 / 19684 日期：1992年11月12日可用于热转移的吡啶酮染料具有式（I）其中R1，R2，R3，Y，X和Z在本说明书中定义。

4. 再颁专利

USRE34877E Azo dyes for thermotransfer printing 失效
标题翻译：用于热转印的偶氮染料
公开(公告)号：USRE34877E
公开(公告)日：1995-03-14
申请号：US166103
申请日：1993-12-14
申请人： Volker Bach , Karl-Heinz Etzbach , Sabine Gruettner , Gunther Lamm , Helmut Reichelt , Ruediger Sens
发明人： Volker Bach , Karl-Heinz Etzbach , Sabine Gruettner , Gunther Lamm , Helmut Reichelt , Ruediger Sens
IPC分类号： B41M5/385 , B41M5/035 , B41M5/132 , B41M5/26 , B41M5/30 , B41M5/388 , B41M5/39 , C09B29/36 , C09B53/00 , D06P5/13 , B41M5/38
CPC分类号： B41M5/388 , Y10S428/913 , Y10S428/914
摘要： Azo dyes useful for thermotransfer printing have the formula ##STR1##
摘要翻译：用于热转印印刷的偶氮染料具有式（1）式

5. 发明授权

US5306815A Azo dyes with a coupling component of the quinoline series 失效
标题翻译：具有喹啉系偶合成分的偶氮染料
公开(公告)号：US5306815A
公开(公告)日：1994-04-26
申请号：US947533
申请日：1992-09-21
申请人： Erwin Hahn , Clemens Grund , Andreas Geisberger , Helmut Reichelt , Andreas Guldner , Mathias Wiesenfeldt , Karl-Heinz Etzbach , Ruediger Sens , Helmut Hagen
发明人： Erwin Hahn , Clemens Grund , Andreas Geisberger , Helmut Reichelt , Andreas Guldner , Mathias Wiesenfeldt , Karl-Heinz Etzbach , Ruediger Sens , Helmut Hagen
IPC分类号： C09B29/033 , C09B29/00 , C09B29/042 , C09B29/045 , C09B29/44 , D06P1/18
CPC分类号： C09B29/0059 , C09B29/0074 , C09B29/3643
摘要： Azo dyes useful for dyeing or printing textile fibers or fabrics and for thermal transfer have the formula ##STR1## where R.sup.1 and R.sup.2 are each substituted or unsubstituted C.sub.1 -C.sub.10 -alkyl or substituted or unsubstituted C.sub.3 -C.sub.4 -alkenyl or R.sup.1 may also be hydrogen,R.sup.3 is hydrogen or C.sub.1 -C.sub.6 -alkyl,R.sup.4 and R.sup.5 are each hydrogen, C.sub.1 -C.sub.6 -alkyl, halogen, C.sub.1 -C.sub.6 -alkoxy, amino or mono- or di(C.sub.1 -C.sub.4 -alkyl)amino, andD is a radical of the thiophene, thiazole, isothiazole, benzothiophene, thienothiophene or thienothiazole series.
摘要翻译：可用于染色或印刷纺织纤维或织物和热转印的偶氮染料具有式（*化学结构*），其中R 1和R 2各自为取代或未取代的C 1 -C 10 - 烷基或取代或未取代的C 3 -C 4 - 烯基或R 1可以也可以是氢，R 3是氢或C 1 -C 6烷基，R 4和R 5各自是氢，C 1 -C 6烷基，卤素，C 1 -C 6烷氧基，氨基或单或二（C 1 -C 4烷基）氨基， D是噻吩，噻唑，异噻唑，苯并噻吩，噻吩并噻吩或噻吩并噻唑系的基团。

6. 发明授权

US5302577A Transfer of anthraquinone dyes 失效
标题翻译：转移蒽醌染料
公开(公告)号：US5302577A
公开(公告)日：1994-04-12
申请号：US038867
申请日：1993-03-29
申请人： Ruediger Sens , Thomas Werner , Karl-Heinz Etzbach
发明人： Ruediger Sens , Thomas Werner , Karl-Heinz Etzbach
IPC分类号： B41M5/385 , B41M5/035 , B41M5/26 , B41M5/382 , B41M5/388 , B41M5/39 , B41M5/50 , B41M5/52 , C09B1/26 , D06P5/13 , B41M5/38
CPC分类号： B41M5/3852 , Y10S428/913 , Y10S428/914
摘要： Anthraquionone dyes are transferred by diffusion or sublimation from a carrier to a plastic-coated substrate with the aid of an energy source by using a carrier on which one or more anthraquinone dyes I ##STR1## where X is hydrogen or cyano,R.sup.1, R.sup.2 and R.sup.3 independently of one another are each hydrogen,alkyl, alkanoyloxyalkyl, alkoxycarbonyloxyalkyl or alkoxycarbonylalkyl, each of which may be of up to 20 carbon atoms and may be substituted by halogen, hydroxyl or cyano,phenyl or benzyl, each of which may be substituted by C.sub.1 -C.sub.15 -alkyl or C.sub.1 -C.sub.15 -alkoxy anda radical of the formula II[--W--O]n--R.sup.4 IIwhereW is identical or different C.sub.2 -C.sub.6 -alkylene radicals,n is from 1 to 6 andR.sup.4 is C.sub.1 -C.sub.4 -alkyl or unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted or C.sub.1 -C.sub.4 -alkoxy-substituted phenyl, are present.
摘要翻译：通过使用其上X是氢或氰基的一种或多种蒽醌染料I（* CHEMICAL STRUCTURE *）I的载体，借助能量源，通过扩散或升华将载体扩散或升华从载体转移到塑料涂覆的基材上， R 1，R 2和R 3彼此独立地各自为氢，烷基，烷酰氧基烷基，烷氧基羰氧基烷基或烷氧基羰基烷基，其各自可以具有至多20个碳原子，并且可以被卤素，羟基或氰基，苯基或苄基取代，可以被C 1 -C 15 - 烷基或C 1 -C 15 - 烷氧基和式II（-WO）n -R 4 ii的基团取代，其中W是相同或不同的C 2 -C 6亚烷基，n是1至6，R 4 是C1-C4烷基或未取代的或C1-C4-烷基取代或C1-C4-烷氧基取代的苯基。

7. 发明授权

US5208210A Thermal transfer printing 失效
标题翻译：热转印
公开(公告)号：US5208210A
公开(公告)日：1993-05-04
申请号：US763638
申请日：1991-09-23
申请人： Ruediger Sens , Karl-Heinz Etzbach
发明人： Ruediger Sens , Karl-Heinz Etzbach
IPC分类号： B41M5/385 , B41M5/035 , B41M5/26 , B41M5/388 , B41M5/39 , C09B1/51 , D06P5/13
CPC分类号： B41M5/3852 , Y10S428/913 , Y10S428/914
摘要： Anthraquinone dyes I useful for thermal transfer printing have the formula ##STR1## where R is alkyl, alkoxyalkyl, aryloxyalkyl, alkanoyloxyalkyl, alkoxycarbonyloxyalkyl or alkoxycarbonylalkyl, which may each contain up to 20 carbon atoms and whose carbon chains may be interrupted by form one to four oxygen atoms in ether function, or is C.sub.5 -C.sub.8 -cycloalkyl or phenyl which may each be substituted by C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy.
摘要翻译：可用于热转移印刷的蒽醌染料I具有式Ia：其中R是烷基，烷氧基烷基，芳氧基烷基，烷酰氧基烷基，烷氧基羰氧基烷基或烷氧基羰基烷基，其各自含有至多20个碳原子，并且其碳链可以被一个四个氧原子在醚中起作用，或者是C 5 -C 8 - 环烷基或苯基，其各自可被C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基取代。

8. 发明授权

US5147845A Triazolopyridine dyes and thermal transfer of methine dyes 失效
标题翻译：三唑并吡啶染料和甲基染料的热转移
公开(公告)号：US5147845A
公开(公告)日：1992-09-15
申请号：US743191
申请日：1991-08-09
申请人： Ruediger Sens , Ernst Schefczik , Karl-Heinz Etzbach , Gunther Lamm , Helmut Reichelt , Matthias Wiesenfeldt
发明人： Ruediger Sens , Ernst Schefczik , Karl-Heinz Etzbach , Gunther Lamm , Helmut Reichelt , Matthias Wiesenfeldt
IPC分类号： C09B26/02 , B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , C07D471/04 , C09B23/00 , C09B23/04 , C09B23/16 , C09B53/00 , C09B55/00 , C09B57/00 , D06P5/00 , D06P5/13
CPC分类号： B41M5/3856 , C09B23/04 , C09B55/009 , B41M5/3854 , B41M5/39 , Y10S428/913 , Y10S428/914
摘要： Triazolopyridine dyes useful for thermal transfer of methine dyes have the formula ##STR1## where R.sup.1 is C.sub.1 -C.sub.20 -alkyl, which may be substituted and interrupted by one or more oxygen atoms, or is substituted or unsubstituted phenyl or hydroxyl,R.sup.2 is a 5- or 6-membered carbocyclic or heterocyclic ring which may be substituted and benzofused,R.sup.3 is cyano, carbamoyl, carboxyl or C.sub.1 -C.sub.4 -alkoxycarbonyl,R.sup.4 is oxygen or a radical of the formula ##STR2## where L.sup.1 is in each case C.sub.1 -C.sub.8 -alkyl which may be interrupted by 1 or 2 oxygen atoms, andX is CH or nitrogen.

9. 发明授权

US4760049A Dye transfer 失效
标题翻译：染色转印
公开(公告)号：US4760049A
公开(公告)日：1988-07-26
申请号：US113909
申请日：1987-10-29
申请人： Karl-Heinz Etzbach , Ruediger Sens
发明人： Karl-Heinz Etzbach , Ruediger Sens
IPC分类号： B44C1/17 , B32B27/00 , B32B27/10 , B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , C09B44/20 , D06P5/13
CPC分类号： B41M5/3854 , Y10S428/913 , Y10S428/914
摘要： Dyes are transferred from a substrate to a plastics-coated paper by sublimation or vaporization using a thermal printing head by using a substrate of which there are dyes of the formula ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 each have defined meanings.
摘要翻译：通过使用具有式（IMAGE）的染料的底物，使用热敏打印头，通过升华或蒸发将染料从基材转移到塑料涂布纸上，其中R 1，R 2，R 3，R 4和R 5各自具有定义的含义。

10. 发明授权

US5612465A Phenylazotriazolopyridine dyestuffs 失效
标题翻译：苯偶氮三唑并吡啶染料
公开(公告)号：US5612465A
公开(公告)日：1997-03-18
申请号：US592310
申请日：1996-02-12
申请人： Ernst Schefczik , Ruediger Sens , Karl-Heinz Etzbach , Helmut Reichelt , Clemens Grund
发明人： Ernst Schefczik , Ruediger Sens , Karl-Heinz Etzbach , Helmut Reichelt , Clemens Grund
IPC分类号： B41M5/388 , C07D471/04 , C09B29/36 , C09B29/42 , D06P1/18
CPC分类号： B41M5/388 , C07D471/04 , C09B29/3617
摘要： Azo dyestuffs of the formula ##STR1## where R.sup.1 is unsubstituted or substituted C.sub.1 -C.sub.20 -alkyl, unsubstituted or substituted phenyl, or unsubstituted or substituted mercapto,R.sup.2 is hydroxyl or mercapto andD is the radical of a diazo component which is selected from the group consisting of the radicals of the formulae ##STR2## where L.sup.1 is C.sub.1 -C.sub.4 -alkyl, unsubstituted or substituted C.sub.1 -C.sub.4 -alkoxy or unsubstituted or substituted amino, one of the two radicals L.sup.2 and L.sup.3 is hydrogen and the other is C.sub.1 -C.sub.4 -alkyl, unsubstituted or substituted C.sub.1 -C.sub.4 -alkoxy or unsubstituted or substituted amino, L.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl, L.sup.5 is unsubstituted or substituted C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkylthio and L.sup.6 is unsubstituted or substituted C.sub.8 -C.sub.13 -alkyl or phenoxy,their use for dyeing or printing textile materials and novel mercaptotriazolopyridines are described.
摘要翻译： PCT No.PCT / EP94 / 02634。 371日期：1996年2月12日 102（e）日期1996年2月12日PCT 1994年8月9日PCT公布。公开号WO95 / 05420 日期2月23日，1995年2月23日的偶氮染料，其中R1是未取代或取代的C1-C20烷基，未取代或取代的苯基，或未取代或取代的巯基，R2是羟基或巯基，D是重氮组分的基团其选自由式为“IMAGE”的基团，其中L 1为C 1 -C 4 - 烷基，未取代或取代的C 1 -C 4 - 烷氧基或未取代或取代的氨基，两个基团L2和L3之一为氢，另一个是C 1 -C 4 - 烷基，未取代或取代的C 1 -C 4 - 烷氧基或未取代或取代的氨基，L 4是氢或C 1 -C 4 - 烷基，L 5是未取代的或取代的C 1 -C 4 - 烷氧基或C 1 -C 4 - 烷硫基， L6是未取代的或取代的C 8 -C 13 - 烷基或苯氧基，它们用于染色或印刷纺织材料和新型巯基三唑并吡啶类的用途。

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