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91. 发明授权

US07338918B2 Catalyst having a silver-vanadium oxide phase and a promoter phase 失效
标题翻译：具有银 - 钒氧化物相和助催化剂相的催化剂
公开(公告)号：US07338918B2
公开(公告)日：2008-03-04
申请号：US10594128
申请日：2005-03-24
申请人： Samuel Neto , Frank Rosowski , Sebastian Storck , Stefan Bauer
发明人： Samuel Neto , Frank Rosowski , Sebastian Storck , Stefan Bauer
IPC分类号： B01J23/50 , C07C51/255 , C07C65/00 , C07C45/00
CPC分类号： B01J23/682 , B01J23/002 , B01J35/0006 , B01J37/0045 , B01J37/0215 , B01J37/0219 , B01J37/0223 , B01J2523/00 , C07C51/265 , C07C63/16 , B01J2523/15 , B01J2523/47 , B01J2523/55 , B01J2523/18
摘要： A catalyst is described which has a catalytically active composition which contains a phase A and a phase B in the form of three-dimensional delimited regions, wherein phase A is a silver-vanadium oxide bronze and phase B a mixed oxide phase based on titanium dioxide and vanadium pentoxide. The catalyst serves to prepare aldehydes, carboxylic acids and/or carboxylic anhydrides from aromatic or heteroaromatic hydrocarbons by gas phase oxidation.
摘要翻译：描述了一种具有催化活性组合物的催化剂，其包含三维定界区域的A相和B相，其中A相是银 - 钒氧化物青铜，B相是基于二氧化钛的混合氧化物相和五氧化二钒。催化剂用于通过气相氧化从芳族或杂芳族烃制备醛，羧酸和/或羧酸酐。

92. 发明申请

US20080019892A1 Multimetal Oxide Containing Silver, Vanadium And A Phosphor Group Element And The Use Thereof 审中-公开
标题翻译：包含银，钒和荧光体组元素的多金属氧化物及其用途
公开(公告)号：US20080019892A1
公开(公告)日：2008-01-24
申请号：US11629379
申请日：2005-06-14
申请人： Samuel Neto , Hartmut Hibst , Frank Rosowski , Sebastian Storck , Jurgen Zuhlke
发明人： Samuel Neto , Hartmut Hibst , Frank Rosowski , Sebastian Storck , Jurgen Zuhlke
IPC分类号： C01G31/00 , B01J23/00
CPC分类号： C01G31/00 , B01J23/002 , B01J23/682 , B01J27/198 , B01J2523/00 , C01P2002/72 , C01P2002/74 , C01P2006/12 , B01J2523/18 , B01J2523/51 , B01J2523/55
摘要： Multimetal oxides corresponding to the general formula (I), processes for their preparation, precatalysts containing such oxides and catalysts made therefrom for gas phase partial oxidation of hydrocarbons: Aga-cQbMcV12Od.eH2O (I)wherein a represents a number having a value of 5 to 9; Q represents an element selected from the group consisting of P, As, Sb, Bi and mixtures thereof; b represents a number having a value of 0.2 to 3; M represents a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni, Ce, Mn, Nb, W, Ta, Mo and mixtures thereof; c represents a number having a value of less than 1; d represents a number having a value of which is determined by the valency and frequency of Ag, Q, M and V in the formula (I); and e represents a number having a value of 0 to 20; wherein the multimetal oxide has a crystal structure wherein its powder X-ray diffractogram includes reflections at at least 5 interplanar spacings selected from the group of 7.13 Å, 5.52 Å, 5.14 Å, 3.57 Å, 3.25 Å, 2.83 Å, 2.79 Å, 2.73 Å, 2.23 Å and 1.71 Å, each interplanar spacing value±0.04 Å.
摘要翻译：对应于通式（I）的多金属氧化物，其制备方法，含有此类氧化物的预催化剂和由其制备的催化剂用于烃的气相部分氧化：<？in-line-formula description =“In-line Formulas”end =“ 导线“>> Ag C C 其中a表示数值为5〜9的数字，其中a表示0〜5的整数。 Q表示选自P，As，Sb，Bi及其混合物的元素; b表示数值为0.2〜3的数; M表示选自Li，Na，K，Rb，Cs，Tl，Mg，Ca，Sr，Ba，Cu，Zn，Cd，Pb，Cr，Au，Al，Fe，Co，Ni， Ce，Mn，Nb，W，Ta，Mo及其混合物; c表示小于1的数字; d表示数值，其数值由式（I）中Ag，Q，M和V的化合价和频率决定; e表示0〜20的数，其中所述多金属氧化物具有晶体结构，其中其粉末X射线衍射图包括选自7.13，5.52，5.14，3.57，3.25，2.83，2.79，2.73的至少5个面间距的反射 Å，2.23Å和1.71Å，每个晶面间距值±0.04Å。

93. 发明授权

US07271279B2 Method for the production of unsaturated nitriles from alkanes 失效
标题翻译：从烷烃生产不饱和腈的方法
公开(公告)号：US07271279B2
公开(公告)日：2007-09-18
申请号：US10482326
申请日：2002-06-25
申请人： Frieder Borgmeier , Frank Rosowski , Goetz-Peter Schindler
发明人： Frieder Borgmeier , Frank Rosowski , Goetz-Peter Schindler
IPC分类号： C07C253/18 , C07C255/08
CPC分类号： C07C253/26 , B01J27/199 , C07C45/33 , C07C45/35 , Y02P20/52 , C07C47/22 , C07C255/08
摘要： The invention relates to a process for preparing unsaturated nitrites from the corresponding alkanes which comprises the steps: a) feeding an alkane into a dehydrogenation zone and catalytically dehydrogenating the alkane to the corresponding alkene to obtain a product gas stream A which comprises the alkene, unconverted alkane and possibly one or more further gas components selected from the group consisting of steam, hydrogen, carbon oxides, hydrocarbons having a lower boiling point than the alkane or the alkene (low-boilers), nitrogen and noble gases, b) at least partially removing further gas components from the product gas stream A to give a feed gas stream B which comprises the alkane and the alkene, c) feeding the feed gas stream B, ammonia, an oxygen-containing gas and, if desired, steam into an oxidation zone and catalytically ammoxidizing the alkene to the corresponding unsaturated nitrile to give a product gas stream C which comprises the unsaturated nitrile, ammoxidation by-products, unconverted alkane and alkene and possibly one or more further gas components selected from the group consisting of steam, oxygen, carbon oxides, ammonia, nitrogen and noble gases, d) optionally removing ammonia from the product gas stream C to give an ammonia-depleted product gas stream D, e) removing the unsaturated nitrile and ammoxidation by-products from the product gas stream C or D by absorption in an aqueous absorbent to give a gas stream E which comprises unconverted alkane and alkene and possibly one or more further gas components selected from the group consisting of oxygen, carbon oxides, ammonia, nitrogen and noble gases, and an aqueous stream which comprises the nitrile and the by-products, and recovery of the unsaturated nitrile from the aqueous stream, f) recycling the gas stream E into the dehydrogenation zone.
摘要翻译：本发明涉及从相应的烷烃制备不饱和亚硝酸盐的方法，其包括以下步骤：a）将烷烃进料到脱氢区中，并将烷烃催化脱氢至相应的烯烃，得到产物气流A，其包含未转化的烯烃烷烃和可能的一种或多种另外的气体组分，其选自蒸汽，氢气，碳氧化物，沸点低于烷烃或烯烃（低沸点）的烃，氮气和惰性气体，b）至少部分从产物气流A中除去进一步的气体组分，得到包含烷烃和烯烃的进料气流B，c）将进料气流B，氨，含氧气体和如果需要的话进料到氧化物并将烯烃催化氨基化成相应的不饱和腈，得到包含不饱和腈的产物气流C，通过 - 产物，未转化的烷烃和烯烃以及可能的一种或多种另外的气体组分，其选自蒸汽，氧气，碳氧化物，氨，氮气和惰性气体，d）任选地从产物气流C除去氨，得到氨分离的产物气流D，e）通过在含水吸收剂中吸收从产物气流C或D中除去不饱和腈和氨氧化副产物，得到包含未转化的烷烃和烯烃的气流E，以及可能一个或多个另外的选自氧，碳氧化物，氨，氮和惰性气体的气体组分和包含腈和副产物的水流，以及从水流中回收不饱和腈，f）将气体再循环流E进入脱氢区。

94. 发明授权

US07253310B2 Preparation of (meth)acrylic acid 有权
标题翻译：（甲基）丙烯酸的制备
公开(公告)号：US07253310B2
公开(公告)日：2007-08-07
申请号：US10920428
申请日：2004-08-18
申请人： Frieder Borgmeier , Frank Rosowski , Hans-Guenther Lintz , Ina Grisstede , Elisabet Bacells Cabre
发明人： Frieder Borgmeier , Frank Rosowski , Hans-Guenther Lintz , Ina Grisstede , Elisabet Bacells Cabre
IPC分类号： C07C51/16
CPC分类号： C07C51/215 , C07C57/04
摘要： A process for preparing (meth)acrylic acid by heterogeneously catalyzed gas phase partial oxidation of a saturated hydrocarbon precursor compound, in which the charging gas mixture contains from 5 to 25% by volume of steam and the molar ratio of molecular oxygen present in the charging gas mixture to saturated hydrocarbon precursor compound present in the charging gas mixture is from 1.5:1 to 2.5:1.
摘要翻译：一种通过饱和烃前体化合物的非均相催化气相部分氧化制备（甲基）丙烯酸的方法，其中装料气体混合物含有5至25体积％的蒸汽和在充料中存在的分子氧的摩尔比与充填气体混合物中存在的饱和烃前体化合物的气体混合物为1.5:1至2.5:1。

95. 发明申请

US20070041795A1 Device for the mixing, drying and coating of powdered, granular or moulded bulk material in a fluid bed and method for production of supported catalysts with such a device 审中-公开
公开(公告)号：US20070041795A1
公开(公告)日：2007-02-22
申请号：US10573479
申请日：2004-09-24
申请人： Samuel Neto , Wolfgang Rummel , Sebastian Storck , Jurgen Zuhlke , Frank Rosowski
发明人： Samuel Neto , Wolfgang Rummel , Sebastian Storck , Jurgen Zuhlke , Frank Rosowski
IPC分类号： B65G53/40
CPC分类号： B01J23/002 , B01J2/16 , B01J23/22 , B01J27/199 , B01J35/023 , B01J37/0219 , B01J37/0221 , B01J37/0232 , B01J2523/00 , F26B3/0926 , B01J2523/15 , B01J2523/47 , B01J2523/51 , B01J2523/53 , B01J2523/55
摘要： The invention relates to an apparatus for mixing, drying and coating pulverulent, granular or shaped loose material in a fluidized bed, in particular for use in a process for producing supported catalysts for gas-phase oxidations, which comprises a container (10) for accommodating the loose material, with a bowl-like depression (17) being provided in a lower region (13) of the container (10), a central tube (27) for introducing a gas, with the central tube entering the container in an upper region (12) of the container (10), extending essentially axially downward in the container (10) and opening into the depression (17), an essentially annular deflection shield (29) which is fixed to the central tube (27) in the upper region (12) of the container (10), a guide ring (31) which is located in the lower region (13) of the container (10) and surrounds the central tube (27) essentially concentrically at a distance (L) for part of its length so that a first opening (34) is formed between the wall of the container (10) at the upper edge (22) of the depression and the lower end (33) of the guide ring (31) and a second opening (36) is formed between the deflection shield (29) and the upper edge (35) of the guide ring (31), and means, for example valves (21), for introducing a fluid into the container (10). In the apparatus of the present invention, the outer wall of the central tube (27) is at least partly provided with an adhesion-reducing coating (38). In a preferred embodiment, the distance (L) between the wall of the central tube (27) and the wall of the guide ring (27) is greater than the open height (H3) of the first opening (34). The invention also provides a process for producing supported catalysts using such an apparatus.

96. 发明申请

US20060247446A1 Multi-metal oxide containing silver, vanadium and a promoter metal and use thereof 失效
标题翻译：含有银，钒和助催化剂金属的多金属氧化物及其用途
公开(公告)号：US20060247446A1
公开(公告)日：2006-11-02
申请号：US10566019
申请日：2004-07-23
申请人： Samuel Neto , Hartmut Hibst , Frank Rosowski , Sebastian Storck
发明人： Samuel Neto , Hartmut Hibst , Frank Rosowski , Sebastian Storck
IPC分类号： C07D307/89 , C07C51/255 , C07C51/16
CPC分类号： C07C51/313 , B01J23/002 , B01J23/682 , B01J23/688 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J37/0045 , B01J37/0223 , B01J2523/00 , C01G31/006 , C07C51/265 , C07C63/16 , B01J2523/18 , B01J2523/3712 , B01J2523/55 , B01J2523/72 , B01J2523/47
摘要： A multimetal oxide of the formula I, Aga-cQbMcV2Od*eH2O, I where a is from 0.3 to 1.9, Q is an element selected from among P, As, Sb and/or Bi, is from 0 to 0.3, M is a metal selected from among Nb, Ce, W, Mn, Ta, Pd, Pt, Ru and/or Rh, c is from 0.001 to 0.5, with the proviso that (a-c)≧0.1, d is a number which is determined by the valence and abundance of the elements other than oxygen in the formula I and e is from 0 to 20, and also precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are described.
摘要翻译：式I的多金属氧化物，<？in-line-formula description =“In-line Formulas”end =“lead”？> Ag ？V V V V V * O O O O O，，------------------------------------- 其中a为0.3〜1.9，Q为选自P，As，Sb和/或Bi的元素，为0〜0.3，M为选自Nb， Ce，W，Mn，Ta，Pd，Pt，Ru和/或Rh，c为0.001至0.5，条件是（ac）> = 0.1，d为由化合价描述了式I中的氧以外的元素和e为0至20，并且还描述了由其制备的用于芳族烃的部分氧化的预催化剂和催化剂。

97. 发明授权

US07019169B2 Preparation of (meth)acrylic acid 失效
标题翻译：（甲基）丙烯酸的制备
公开(公告)号：US07019169B2
公开(公告)日：2006-03-28
申请号：US10934442
申请日：2004-09-07
申请人： Frieder Borgmeier , Frank Rosowski , Hans-Günther Lintz , Ina Grisstede
发明人： Frieder Borgmeier , Frank Rosowski , Hans-Günther Lintz , Ina Grisstede
IPC分类号： C07C51/16
CPC分类号： C07C51/215 , C07C57/04
摘要： A process for preparing (meth)acrylic acid by conducting a saturated hydrocarbon precursor compound through a catalyst bed I whose catalysts I have, as the active composition, a multimetal oxide I which has a specific X-ray diffractogram and contains the elements Mo and V, at least one of the elements Te and Sb, and also at least one of the elements from the group consisting of Nb, Ta, W, Ce and Ti, wherein the catalyst bed I is interrupted by at least one catalyst bed II whose catalysts II have, as the active composition, a multimetal oxide II which contains the elements Mo, Bi and Fe.
摘要翻译：通过使催化剂床I（其具有催化剂床I）作为活性组合物，通过具有特定的X射线衍射图并含有元素Mo和V的多金属氧化物I来导入饱和烃前体化合物来制备（甲基）丙烯酸的方法，元素Te和Sb中的至少一种，以及来自Nb，Ta，W，Ce和Ti的元素中的至少一种元素，其中催化剂床I被至少一个催化剂床II中断，催化剂床II的催化剂床作为活性组合物，II具有包含元素Mo，Bi和Fe的多金属氧化物II。

98. 发明申请

US20050148782A1 Preparation of phthalic anhydride 有权
标题翻译：邻苯二甲酸酐的制备
公开(公告)号：US20050148782A1
公开(公告)日：2005-07-07
申请号：US10503983
申请日：2003-02-04
申请人： Sebastian Storck , Frank Rosowski , Michael Baier , Andreas Tenten , hans-Josef Wolf
发明人： Sebastian Storck , Frank Rosowski , Michael Baier , Andreas Tenten , hans-Josef Wolf
IPC分类号： C07D307/89 , B01J23/22 , B01J35/00 , C07B61/00 , C07C51/265 , C07C51/31
CPC分类号： C07C51/265 , B01J23/22 , B01J35/0006 , C07C51/313 , C07C63/16
摘要： Process for preparing phthalic anhydride by gas-phase oxidation of xylene, naphthalene or mixtures thereof in a shell-and-tube reactor thermostatted by means of a heat transfer medium over three or more different fixed-bed catalysts arranged in zones, wherein the process is carried out so that the maximum temperature in the second catalyst zone in the flow direction is up to 50° C. lower than the maximum temperature in the first catalyst zone and the maximum temperature in the third zone from the gas inlet is from 30 to 100° C. lower than that in the first catalyst zone. The process of the present invention makes it possible to prepare phthalic anhydride in high yields under industrially relevant conditions.
摘要翻译：在通过在三个或更多个不同的固定床催化剂上排列的区域中的传热介质进行恒温的壳管式反应器中通过气相氧化二甲苯，萘或其混合物来制备邻苯二甲酸酐的方法，其中该方法是使得第二催化剂区域在流动方向上的最高温度比第一催化剂区域中的最高温度低至50℃，并且从气体入口处的第三区域中的最高温度为30至100℃ ℃，低于第一催化剂区域。本发明的方法可以在工业上相关的条件下以高收率制备邻苯二甲酸酐。

99. 发明申请

US20050065372A1 Preparation of (meth)acrylic acid 失效
标题翻译：（甲基）丙烯酸的制备
公开(公告)号：US20050065372A1
公开(公告)日：2005-03-24
申请号：US10934624
申请日：2004-09-07
申请人： Frieder Borgmeier , Frank Rosowski , Hans Martan , Klaus Muller-Engel
发明人： Frieder Borgmeier , Frank Rosowski , Hans Martan , Klaus Muller-Engel
IPC分类号： B01J23/00 , B01J23/28 , B01J23/887 , B01J27/057 , B01J35/00 , B01J37/00 , C07C51/215 , C07C51/16 , C07C51/235
CPC分类号： C07C51/215 , B01J23/002 , B01J23/28 , B01J23/8877 , B01J27/0576 , B01J35/0006 , B01J37/0045 , B01J2523/00 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/847 , B01J2523/32
摘要： A process for preparing (meth)acrylic acid, in which a saturated hydrocarbon precursor compound is conducted through a catalyst charge which consists of two spatially successive catalyst beds I, II in the flow direction of the reaction mixture, each of which contains different catalysts and has different reaction-selectivity behavior.
摘要翻译：一种制备（甲基）丙烯酸的方法，其中饱和烃前体化合物通过催化剂装料进行，催化剂装料由反应混合物流动方向上的两个空间连续的催化剂床I，II组成，每个催化剂床含有不同的催化剂和具有不同的反应选择性行为。

100. 发明申请

US20050043567A1 Preparation of (meth)acrylic acid 有权
标题翻译：（甲基）丙烯酸的制备
公开(公告)号：US20050043567A1
公开(公告)日：2005-02-24
申请号：US10920428
申请日：2004-08-18
申请人： Frieder Borgmeier , Frank Rosowski , Hans-Gunther Lintz , Ina Grisstede , Elisabet Cabre
发明人： Frieder Borgmeier , Frank Rosowski , Hans-Gunther Lintz , Ina Grisstede , Elisabet Cabre
IPC分类号： C07C51/215 , C07C51/16 , C07C51/235
CPC分类号： C07C51/215 , C07C57/04
摘要： A process for preparing (meth)acrylic acid by heterogeneously catalyzed gas phase partial oxidation of a saturated hydrocarbon precursor compound, in which the charging gas mixture contains from 5 to 25% by volume of steam and the molar ratio of molecular oxygen present in the charging gas mixture to saturated hydrocarbon precursor compound present in the charging gas mixture is from 1.5:1 to 2.5:1.
摘要翻译：一种通过饱和烃前体化合物的非均相催化气相部分氧化制备（甲基）丙烯酸的方法，其中装料气体混合物含有5至25体积％的蒸汽和在充料中存在的分子氧的摩尔比与充填气体混合物中存在的饱和烃前体化合物的气体混合物为1.5:1至2.5:1。

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