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    • 1. 发明申请
    • METHOD FOR NITRIDATION PRETREATMENT
    • 硝化预处理方法
    • US20100099251A1
    • 2010-04-22
    • US12256235
    • 2008-10-22
    • XINYU FUJick M. Yu
    • XINYU FUJick M. Yu
    • H01L21/768
    • H01L21/76826H01L21/76814H01L21/76831H01L23/53238H01L2924/0002H01L2924/00
    • In one embodiment, a method for fabricating a damascene structure is provided which includes exposing a dielectric surface on a substrate to a nitrogen plasma to form a nitrided dielectric layer, wherein the dielectric surface contains a plurality of openings therein, depositing a barrier layer on the nitrided dielectric surface, and depositing a seed layer over the barrier layer. In some examples, the nitrogen plasma is formed from nitrogen gas or a mixture of nitrogen gas and hydrogen gas. The nitrogen plasma may be formed in a barrier deposition chamber or by a reactive preclean chamber. In another embodiment, a bulk layer may be deposited to fill the openings after depositing the seed layer. In one example, the bulk layer may contain copper, tungsten, or alloys thereof, and be deposited by an electrochemical plating process.
    • 在一个实施例中,提供了一种用于制造镶嵌结构的方法,其包括将衬底上的电介质表面暴露于氮等离子体以形成氮化介电层,其中电介质表面包含多个开口,在其上沉积阻挡层 氮化电介质表面,并且在阻挡层上沉积种子层。 在一些实例中,氮等离子体由氮气或氮气和氢气的混合物形成。 氮等离子体可以形成在阻挡沉积室中或通过反应性预清洗室形成。 在另一个实施例中,沉积种子层之后可沉积体层以填充开口。 在一个实例中,本体层可以包含铜,钨或其合金,并且通过电化学电镀工艺沉积。