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1. 发明授权

US3951648A Process for recovering palladium, more particularly from alumina containing catalysts 失效
标题翻译：更具体地从含氧化铝的催化剂中回收钯的方法
公开(公告)号：US3951648A
公开(公告)日：1976-04-20
申请号：US455078
申请日：1974-03-27
申请人： Robert Stern , Jean-Pierre Franck , Jean-Francois Le Page
发明人： Robert Stern , Jean-Pierre Franck , Jean-Francois Le Page
IPC分类号： C22B11/00 , B01J37/24 , B01J38/00 , C01G55/00 , C22B11/02
CPC分类号： B01J37/24 , C22B11/026 , Y02P10/214
摘要： Process for recovering palladium from a catalyst having a palladium content of less than 5 %, comprising contacting said catalyst with a gaseous chlorinated organic compound at a temperature sufficient for vaporizing the palladium and cooling the gaseous phase so as to recover the formed chlorinated palladium derivative.
摘要翻译：从钯含量小于5％的催化剂中回收钯的方法，包括在足以汽化钯并冷却气相的温度下使所述催化剂与气态氯化有机化合物接触，以回收形成的氯化钯衍生物。

2. 发明授权

US4140621A Maintaining or increasing the isobutane content of a cut subjected to selective hydrogenolysis 失效
标题翻译：保持或提高经过选择性氢解的切割的异丁烷含量
公开(公告)号：US4140621A
公开(公告)日：1979-02-20
申请号：US835076
申请日：1977-09-20
申请人： Jean-Pierre Franck , Jean-Francois Le Page , Germain Martino , Jean Miquel
发明人： Jean-Pierre Franck , Jean-Francois Le Page , Germain Martino , Jean Miquel
IPC分类号： B01J23/00 , C07C1/00 , C07C4/06 , C07C11/09 , C07C67/00 , C10G47/14 , C07C9/08 , B01J27/04
CPC分类号： C07C4/06 , C07C2521/04 , C07C2521/08 , C07C2523/46 , C10G2400/26
摘要： A saturated hydrocarbon charge containing both butane and isobutane is subjected to selective hydrogenolysis in the presence of a catalyst comprising a specific carrier and 0.1 - 10 % b.w. of rhodium. Butane is thus selectively converted to ethane and propane, while isobutane is preserved or formed and can be recovered from the reaction product.
摘要翻译：在含有特定载体和0.1-10％b.w的催化剂存在下，将含有丁烷和异丁烷的饱和烃电荷进行选择性氢解。的铑。因此，丁烷选择性地转化为乙烷和丙烷，而异丁烷被保存或形成，并且可以从反应产物中回收。

3. 发明授权

US4092371A Process for manufacturing a catalyst comprising aluminum oxide and boron oxide, the resulting catalyst and the use thereof in alkylation reactions 失效
标题翻译：用于制造包含氧化铝和氧化硼的催化剂的方法，所得催化剂及其在烷基化反应中的用途
公开(公告)号：US4092371A
公开(公告)日：1978-05-30
申请号：US815350
申请日：1977-07-07
申请人： Jean-Pierre Franck , Jean-Francois Le Page
发明人： Jean-Pierre Franck , Jean-Francois Le Page
IPC分类号： B01J27/08 , B01J37/22 , C07C2/68 , C07C3/52
CPC分类号： C07C2/68 , B01J27/08 , B01J37/22 , C07C2521/02 , C07C2521/04 , C07C2527/126 , C07C2531/14 , Y02P20/582
摘要： A catalyst useful for the alkylation of aromatic hydrocarbons is produced by reacting a compound of the formula AlX.sub.y R.sub.(3 - y), where X is halogen, R is a hydrocarbon radical and y is 1, 3/2, 2 or 3, except 3 when X is fluorine, with a carrier comprising aluminum oxide and boron oxide.
摘要翻译：用于芳族烃烷基化的催化剂是通过使式AlXyR（3-y）的化合物（其中X是卤素，R是烃基）和y是1,3 / 2,2或3，除了3 当X是氟时，具有包含氧化铝和氧化硼的载体。

4. 发明授权

US4254294A Polymerization reactions in the presence of a catalyst containing aluminum oxide, boron oxide and halogen 失效
标题翻译：在含有氧化铝，氧化硼和卤素的催化剂存在下的聚合反应
公开(公告)号：US4254294A
公开(公告)日：1981-03-03
申请号：US096588
申请日：1979-11-21
申请人： Bernard Juguin , Jean-Pierre Franck , Jean-Francois Le Page , Gabriel de Gaudemaris
发明人： Bernard Juguin , Jean-Pierre Franck , Jean-Francois Le Page , Gabriel de Gaudemaris
IPC分类号： C08F4/00 , C07C1/00 , C07C2/22 , C07C11/02 , C07C67/00 , C08F4/06 , C08F8/04 , C08F10/00 , C08F240/00 , C10G50/00 , C08F4/52 , C08F4/12
CPC分类号： C08F240/00 , C08F10/00 , C08F8/04 , Y02P20/582
摘要： Process for polymerizing olefinic hydrocarbons at a temperature from 0.degree. to 90.degree. C., preferably from 20.degree. to 80.degree. C. in the presence of a catalyst containing aluminum oxide and, per part by weight thereof, boron oxide in a proportion of 0.01 to 1, preferably 0.07 to 0.15 part by weight and halogen in a proportion of 0.5 to 20%, preferably 4 to 12%, said catalyst resulting from the reaction of an aluminum compound of formula AlX.sub.y R.sub.(3-y) where X is halogen, R is a hydrocarbon radical and y is selected from 1, 3/2, 2 and 3, with a carrier containing aluminum oxide and boron oxide in a proportion to aluminum oxide from 1 to 100%.
摘要翻译：在含有氧化铝的催化剂存在下，在0〜90℃，优选20〜80℃的温度下使烯烃聚合的方法，按重量份计，氧化硼的比例为0.01 至1，优选0.07至0.15重量份，卤素以0.5至20重量％，优选4至12重量％的比例，由式AlXyR（3-y）的铝化合物（其中X为卤素， R是烃基，y选自1,3 / 2,2和3，其中含有氧化铝和氧化硼的载体与氧化铝的比例为1至100％。

5. 发明授权

US4180453A Process for the steam-cracking of heavy feedstocks 失效
标题翻译：重质原料蒸汽裂解的工艺
公开(公告)号：US4180453A
公开(公告)日：1979-12-25
申请号：US876825
申请日：1978-02-10
申请人： Jean-Pierre Franck , Edouard Freund , Jean-Francois Le Page , Jean Miquel
发明人： Jean-Pierre Franck , Edouard Freund , Jean-Francois Le Page , Jean Miquel
IPC分类号： B01J27/00 , C10G65/06 , C10G69/06 , C10G37/00
CPC分类号： C10G65/06 , C10G2400/20
摘要： A fresh charge containing aromatic hydrocarbons is hydrotreated in admixture with a recycle fraction, in the presence of a bifunctional catalyst, a portion of the effluent is subjected to steam-cracking, thereby recovering a gas oil fraction which is subjected to hydrogenation and forms said recycle fraction. The mixture of recycle fraction and charge is advantageously treated with hydrogen in the presence of a monofunctional catalyst to hydrogenate olefins, at a lower temperature than the hydrotreatment, and then passed to the hydrotreatment zone.
摘要翻译：将含有芳烃的新鲜电荷与再循环部分混合加氢处理，在双官能催化剂存在下，将一部分流出物进行蒸汽裂化，从而回收粗制油馏分进行氢化并形成所述再循环分数。有利的是，在单官能催化剂存在下，用氢气处理再循环部分和装料的混合物，以在比加氢处理的温度更低的温度下氢化烯烃，然后通入加氢处理区。

6. 发明授权

US4062805A Process for manufacturing a catalyst comprising aluminum oxide and boron oxide, the resulting catalyst and the use thereof in alkylation reactions 失效
标题翻译：用于制造包含氧化铝和氧化硼的催化剂的方法，所得催化剂及其在烷基化反应中的用途
公开(公告)号：US4062805A
公开(公告)日：1977-12-13
申请号：US699454
申请日：1976-06-24
申请人： Jean-Pierre Franck , Jean-Francois Le Page
发明人： Jean-Pierre Franck , Jean-Francois Le Page
IPC分类号： B01J27/08 , B01J31/14 , B01J37/22 , C07B61/00 , C07C1/00 , C07C2/66 , C07C2/68 , C07C15/02 , C07C67/00 , B01J21/02
CPC分类号： B01J37/22 , B01J27/08 , C07C2/66 , C07C2/68 , C07C2521/02 , C07C2521/04 , C07C2527/126 , C07C2531/14 , Y02P20/582
摘要： A catalyst useful for the alkylation of aromatic hydrocarbons is produced by reacting a compound of the formula AlX.sub.y R.sub.(3 - y) , where X is halogen, R is a hydrocarbon radical and y is 1, 3/2, or 2, except, with a carrier comprising aluminum oxide and boron oxide.
摘要翻译：可用于芳族烃烷基化的催化剂是通过使式AlXyR（3-y）化合物（其中X是卤素，R是烃基，y是1,3/2或2）与式包含氧化铝和氧化硼的载体。

7. 发明授权

US4132745A Process for isomerizing 1-butene to 2-butene 失效
标题翻译：将1-丁烯异构化为2-丁烯的方法
公开(公告)号：US4132745A
公开(公告)日：1979-01-02
申请号：US879579
申请日：1978-02-21
申请人： Pierre Amigues , Jean Gaillard , Jean-Francois Le Page , Robert Stern
发明人： Pierre Amigues , Jean Gaillard , Jean-Francois Le Page , Robert Stern
IPC分类号： B01J23/40 , B01J37/20 , C07C5/22 , C07C5/25 , C07C5/24 , C07C5/30
CPC分类号： C07C5/226 , B01J23/40 , B01J37/20 , C07C5/2556 , C07C2521/04 , C07C2523/40 , C07C2523/44
摘要： Process for isomerizing 1-butene to 2-butene by contacting 1-butene, at a temperature from 50 to 140.degree. C, in the presence of hydrogen, with an isomerization catalyst containing a noble metal from group VIII of the periodic classification of elements, which catalyst was previously contacted with a sulfur compound at a temperature from 50 to 400.degree. C and then with hydrogen at a temperature of at least 50.degree. C.
摘要翻译：通过在氢存在下，在50-140℃的温度下使1-丁烯与包含元素周期分类的VIII族的贵金属的异构化催化剂接触，将1-丁烯异构化为2-丁烯的方法，该催化剂预先在50-400℃的温度下与硫化合物接触，然后在至少50℃的温度下与氢气接触。

8. 发明授权

US4230897A Process for selectively hydrogenating a hydrocarbon cut containing at least one diolefinic hydrocarbon and at least one acetylenic hydrocarbon using a palladium catalyst with crystallites of at least 50 angstroms 失效
标题翻译：使用具有至少50埃的微晶的钯催化剂选择性氢化含有至少一种二烯烃和至少一种炔烃的烃馏分
公开(公告)号：US4230897A
公开(公告)日：1980-10-28
申请号：US26984
申请日：1979-04-04
申请人： Jean Cosyns , Robert Stern , Jean-Francois Le Page
发明人： Jean Cosyns , Robert Stern , Jean-Francois Le Page
IPC分类号： C07C7/167 , B01J23/44 , C07C1/00 , C07C5/08 , C07C11/12 , C07C67/00 , C10G45/40 , C07C7/00
CPC分类号： C07C5/08 , B01J23/44 , C07C2521/04 , C07C2523/44
摘要： Process for selectively hydrogenating acetylenic hydrocarbons such as vinylacetylene contained in an unsaturated hydrocarbon fraction such as a C.sub.4 fraction also containing a diolefinic hydrocarbon such as butadiene, without substantially hydrogenating said diolefinic hydrocarbon, comprising the step of contacting said fraction, at least partially in the liquid phase, in the presence of hydrogen, with a catalyst of palladium on alumina whose palladium crystallites have an average size of at least 50 Angstroms, said step being optionally followed with a step of contacting the resultant fraction from the preceding step, in the presence of hydrogen, with a catalyst of palladium an alumina whose palladium crystallites have an average size of at most 45 Angstroms.
摘要翻译：用于选择性氢化不饱和烃馏分中的炔属烃如乙烯基乙炔的方法，所述不饱和烃馏分例如也含有二烯烃如丁二烯的C4馏分，而基本上不氢化所述二烯烃，包括使所述馏分至少部分地接触液体的步骤在氢气存在下与钯钯微晶的平均尺寸至少为50埃的氧化钯催化剂相接触，所述步骤任选地在下述步骤中使之与前述步骤的所得部分接触：在氢气，钯催化剂，其钯微晶具有至多45埃的平均尺寸的氧化铝。

9. 发明授权

US5830400A Method of manufacturing a hollow structure for storing pressurized fluids 失效
标题翻译：制造用于储存加压流体的中空结构的方法
公开(公告)号：US5830400A
公开(公告)日：1998-11-03
申请号：US568360
申请日：1995-12-06
申请人： Michel Huvey , Jean-Francois Le Page
发明人： Michel Huvey , Jean-Francois Le Page
IPC分类号： F16J12/00 , F16L11/115 , F17C1/00 , F17C1/06 , B29C53/34 , B29C63/18 , B29C71/02
CPC分类号： F16J12/00 , F16L11/115 , F17C1/00 , F17C1/06 , F17C2201/0138 , F17C2201/054 , F17C2201/056 , F17C2203/012 , F17C2203/013 , F17C2203/0329 , F17C2203/0607 , F17C2203/0617 , F17C2203/0619 , F17C2203/0621 , F17C2203/0643 , F17C2203/0656 , F17C2203/0658 , F17C2203/066 , F17C2203/0663 , F17C2203/067 , F17C2203/0673 , F17C2205/0111 , F17C2205/0119 , F17C2205/0323 , F17C2209/21 , F17C2209/2154 , F17C2209/232 , F17C2221/014 , F17C2223/0123 , F17C2223/035 , F17C2223/036 , F17C2260/012 , F17C2270/0147 , F17C2270/0165 , F17C2270/0168
摘要： A method for manufacturing a hollow structure suitable for example as reservoir for pressurized fluids, which structure is obtained by curving over a part of its length a corrugated tube provided circumferentially in the hollow of its waves with a hardenable fiber reinforced composition, then subjecting the tube thus curved over at least a part of its length to a treatment for hardening the hardenable composition. The tube may comprise longitudinal reinforcements (braid or layers of widely spaced helical wires), the ends of the tube being possibly equipped with systems for communicating with the outside or for sealing, the final shaping being followed by a treatment for hardening said composition. The winding of the tube may be carried out about a central core or drum.
摘要翻译：一种制造中空结构的方法，该中空结构适用于例如用于加压流体的储存器，该结构通过在其一部分长度上弯曲波纹管获得，波纹管在其波浪的中空中以可硬化纤维增强的组合物设置，然后对管从而在其长度的至少一部分上弯曲以硬化可硬化组合物的处理。管可以包括纵向加强件（编织层或间隔宽的螺旋丝的层），管的端部可以配备有用于与外部连通或用于密封的系统，最终成形之后是用于硬化所述组合物的处理。管的绕组可以围绕中心芯或滚筒进行。

10. 发明授权

US5024751A Catalytic composition comprising a metal sulfide suspended in a liquid containing asphaltenes and hydrovisbreaking process of a hydrocarbon charge 失效
标题翻译：催化组合物包含悬浮在含有沥青质的液体中的金属硫化物和烃装料的加氢裂化过程
公开(公告)号：US5024751A
公开(公告)日：1991-06-18
申请号：US353836
申请日：1989-05-18
申请人： Pierre Giuliani , Jean-Francois Le Page , Jean-Claude Plumail , Marcellin Espaillac
发明人： Pierre Giuliani , Jean-Francois Le Page , Jean-Claude Plumail , Marcellin Espaillac
IPC分类号： B01J27/049 , B01J27/051 , B01J37/20 , C10G47/06 , C10G49/12 , C10G65/12
CPC分类号： B01J37/20 , C10G49/12
摘要： The invention relates to a process of catalytic hydrovisbreaking of a hydrocarbon charge comprising the following stages:a) Mixing the charge to be treated with a gas containing hydrogen in an amount sufficient for carrying out the hydrovisbreaking reaction,b) introducing into the hydrogen-hydrocarbon charge mixture an amount of a catalytic composition that is sufficient for obtaining a content of metals in the charge to be treated ranging from about 10 to 2,000 ppm by weight in relation to the weight of the charge, said catalytic composition being obtained with a method comprising the following stages:1) subjecting to a thermal treatment under the globally reducing atmosphere of a gas containing hydrogen, the mixture obtained by contacting, in any order, at least one compound other than a sulfide of at least one metal with a hydrocarbon charge containing asphaltenes and with at least one organic polysulfide2) heating the product resulting from statge (b) in the presence of a gas containing hydrogen, andc) subjecting the product resulting from stage (b) to hydrovisbreaking conditions for a time sufficient for carrying out the hydrovisbreaking of the charge to be treated.
摘要翻译：本发明涉及一种烃装料的催化加氢脱硫方法，包括以下阶段：a）将待处理的装料与含氢气体混合，其量足以进行加氢脱硫反应，b）向氢 - 烃给予混合物一定量的催化组合物，该催化组合物足以获得相对于电荷重量约10-2000ppm重量的待处理电荷中的金属含量，所述催化组合物的含量为以下阶段：1）在全球还原气氛下对含氢气体进行热处理，所述混合物通过以任何顺序将至少一种除了至少一种金属的硫化物之外的化合物与含有沥青质和至少一种有机多硫化物2）加热在气体c存在下由（b）引起的产物接受氢气，以及c）使从阶段（b）获得的产品经受加氢破坏条件足够长时间进行待处理电荷的加氢破坏。

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