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    • 1. 发明授权
    • Catalytic composition comprising a metal sulfide suspended in a liquid
containing asphaltenes and hydrovisbreaking process of a hydrocarbon
charge
    • 催化组合物包含悬浮在含有沥青质的液体中的金属硫化物和烃装料的加氢裂化过程
    • US5024751A
    • 1991-06-18
    • US353836
    • 1989-05-18
    • Pierre GiulianiJean-Francois Le PageJean-Claude PlumailMarcellin Espaillac
    • Pierre GiulianiJean-Francois Le PageJean-Claude PlumailMarcellin Espaillac
    • B01J27/049B01J27/051B01J37/20C10G47/06C10G49/12C10G65/12
    • B01J37/20C10G49/12
    • The invention relates to a process of catalytic hydrovisbreaking of a hydrocarbon charge comprising the following stages:a) Mixing the charge to be treated with a gas containing hydrogen in an amount sufficient for carrying out the hydrovisbreaking reaction,b) introducing into the hydrogen-hydrocarbon charge mixture an amount of a catalytic composition that is sufficient for obtaining a content of metals in the charge to be treated ranging from about 10 to 2,000 ppm by weight in relation to the weight of the charge, said catalytic composition being obtained with a method comprising the following stages:1) subjecting to a thermal treatment under the globally reducing atmosphere of a gas containing hydrogen, the mixture obtained by contacting, in any order, at least one compound other than a sulfide of at least one metal with a hydrocarbon charge containing asphaltenes and with at least one organic polysulfide2) heating the product resulting from statge (b) in the presence of a gas containing hydrogen, andc) subjecting the product resulting from stage (b) to hydrovisbreaking conditions for a time sufficient for carrying out the hydrovisbreaking of the charge to be treated.
    • 本发明涉及一种烃装料的催化加氢脱硫方法,包括以下阶段:a)将待处理的装料与含氢气体混合,其量足以进行加氢脱硫反应,b)向氢 - 烃 给予混合物一定量的催化组合物,该催化组合物足以获得相对于电荷重量约10-2000ppm重量的待处理电荷中的金属含量,所述催化组合物的含量为 以下阶段:1)在全球还原气氛下对含氢气体进行热处理,所述混合物通过以任何顺序将至少一种除了至少一种金属的硫化物之外的化合物与含有 沥青质和至少一种有机多硫化物2)加热在气体c存在下由(b)引起的产物 接受氢气,以及c)使从阶段(b)获得的产品经受加氢破坏条件足够长时间进行待处理电荷的加氢破坏。