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1. 发明授权

US09186633B2 Method for producing porous thermosetting resin sheet, porous thermosetting resin sheet and composite semipermeable membrane using same 有权
标题翻译：多孔热固性树脂片的制造方法，多孔热固性树脂片和使用其的复合半透膜
公开(公告)号：US09186633B2
公开(公告)日：2015-11-17
申请号：US13125639
申请日：2009-10-23
申请人： Noriaki Harada , Atsushi Hiro , Katsumi Ishii , Yoshihide Kawaguchi , Atsuko Mizuike , Osamu Hayashi
发明人： Noriaki Harada , Atsushi Hiro , Katsumi Ishii , Yoshihide Kawaguchi , Atsuko Mizuike , Osamu Hayashi
IPC分类号： B01D69/12 , B01D71/56 , C08J5/18 , B01D61/02
CPC分类号： B01D71/56 , B01D61/025 , B01D69/12 , B01D2323/18 , B01D2323/225 , B01D2323/42 , C08J5/18 , C08J2201/046 , C08J2300/24 , C08J2363/00 , C08J2471/00 , Y10T428/249921 , Y10T428/269
摘要： Disclosed is a method for easily producing a long porous thermosetting resin sheet which has no resin coating film on the surface. Also disclosed are a porous thermosetting resin sheet produced by the method, and a composite semipermeable membrane having excellent chemical resistance and practical water permeability and salt-blocking property. The porous thermosetting resin sheet can be produced by forming a cylindrical or columnar resin block which is composed of a cured product of a thermosetting resin composition containing a thermosetting resin, a curing agent and a porogen; then forming a long thermosetting resin sheet by cutting the surface of the resin block at a certain thickness; and then removing the porogen from the thermosetting resin sheet.
摘要翻译：公开了一种容易制造表面上没有树脂涂膜的长孔多孔热固性树脂片的方法。还公开了通过该方法制造的多孔热固性树脂片和具有优异的耐化学性和实用的水渗透性和防盐性的复合半透膜。多孔热固性树脂片可以通过形成由包含热固性树脂，固化剂和致孔剂的热固性树脂组合物的固化产物构成的圆柱形或柱状树脂块来制造; 然后通过将树脂块的表面切割成一定厚度而形成长的热固性树脂片; 然后从热固性树脂片上除去致孔剂。

2. 发明申请

US20110174723A1 COMPOSITE SEMI-PERMEABLE MEMBRANE AND METHOD FOR PRODUCING SAME 有权
标题翻译：复合半透膜及其制造方法
公开(公告)号：US20110174723A1
公开(公告)日：2011-07-21
申请号：US13121007
申请日：2009-09-25
申请人： Yoshihide Kawaguchi , Atsushi Hiro , Noriaki Harada , Osamu Hayashi , Atsuko Mizuike , Katsumi Ishii
发明人： Yoshihide Kawaguchi , Atsushi Hiro , Noriaki Harada , Osamu Hayashi , Atsuko Mizuike , Katsumi Ishii
IPC分类号： B01D69/10 , B01D69/12 , B01D71/46 , B01D71/60 , B05D5/00
CPC分类号： B01D69/02 , B01D69/12 , B01D71/46 , B01D71/56 , B01D2325/30 , C02F1/441 , C02F2103/04 , C02F2103/08 , Y02A20/131
摘要： It is an object of the present invention to provide a composite semi-permeable membrane exhibiting excellent chemical resistance and having practical water permeability and salt-blocking property, and a method for producing the same. The present invention relates to a composite semi-permeable membrane, including a porous support and a skin layer formed on a surface of the porous support, wherein the porous support contains a thermosetting resin porous sheet having a three-dimensional network structure and pores communicating with each other and wherein the thermosetting resin porous sheet has an average pore diameter of 0.01 to 0.4 μm.
摘要翻译：本发明的目的是提供具有优异的耐化学性并具有实用的透水性和耐盐性的复合半渗透膜及其制造方法。复合半透膜技术领域本发明涉及一种复合半透膜，其包括多孔载体和形成在所述多孔载体的表面上的表层，其中所述多孔载体包含具有三维网状结构的热固性树脂多孔片，并且与并且其中所述热固性树脂多孔片的平均孔径为0.01至0.4μm。

3. 发明申请

US20110192788A1 METHOD FOR PRODUCING POROUS THERMOSETTING RESIN SHEET, POROUS THERMOSETTING RESIN SHEET AND COMPOSITE SEMIPERMEABLE MEMBRANE USING SAME 有权
标题翻译：多孔热固性树脂片的制造方法，多孔热固性树脂片和使用其的复合膜可切割膜
公开(公告)号：US20110192788A1
公开(公告)日：2011-08-11
申请号：US13125639
申请日：2009-10-23
申请人： Noriaki Harada , Atsushi Hiro , Katsumi Ishii , Yoshihide Kawaguchi , Atsuko Mizuike , Osamu Hayashi
发明人： Noriaki Harada , Atsushi Hiro , Katsumi Ishii , Yoshihide Kawaguchi , Atsuko Mizuike , Osamu Hayashi
IPC分类号： C08J9/26 , B01D71/46 , B01D71/56 , B01D69/12 , B32B5/18 , B29C37/00
CPC分类号： B01D71/56 , B01D61/025 , B01D69/12 , B01D2323/18 , B01D2323/225 , B01D2323/42 , C08J5/18 , C08J2201/046 , C08J2300/24 , C08J2363/00 , C08J2471/00 , Y10T428/249921 , Y10T428/269
摘要： Disclosed is a method for easily producing a long porous thermosetting resin sheet which has no resin coating film on the surface. Also disclosed are a porous thermosetting resin sheet produced by the method, and a composite semipermeable membrane having excellent chemical resistance and practical water permeability and salt-blocking property. The porous thermosetting resin sheet can be produced by forming a cylindrical or columnar resin block which is composed of a cured product of a thermosetting resin composition containing a thermosetting resin, a curing agent and a porogen; then forming a long thermosetting resin sheet by cutting the surface of the resin block at a certain thickness; and then removing the porogen from the thermosetting resin sheet.
摘要翻译：公开了一种容易制造表面上没有树脂涂膜的长孔多孔热固性树脂片的方法。还公开了通过该方法制造的多孔热固性树脂片和具有优异的耐化学性和实用的水渗透性和防盐性的复合半透膜。多孔热固性树脂片可以通过形成由包含热固性树脂，固化剂和致孔剂的热固性树脂组合物的固化产物构成的圆柱形或柱状树脂块来制造; 然后通过将树脂块的表面切割成一定厚度而形成长的热固性树脂片; 然后从热固性树脂片上除去致孔剂。

4. 发明申请

US20120228213A1 SEPARATION MEMBRANE UNIT AND SEPARATION MEMBRANE ELEMENT WITH SAME 审中-公开
标题翻译：分离膜单元和分离膜单元
公开(公告)号：US20120228213A1
公开(公告)日：2012-09-13
申请号：US13509245
申请日：2010-06-22
申请人： Katsumi Ishii , Atsushi Hiro , Yoshihide Kawaguchi , Noriaki Harada , Osamu Hayashi , Atsuko Mizuike
发明人： Katsumi Ishii , Atsushi Hiro , Yoshihide Kawaguchi , Noriaki Harada , Osamu Hayashi , Atsuko Mizuike
IPC分类号： B01D71/56 , B01D63/14
CPC分类号： B01D69/12 , B01D63/082 , B01D63/14 , B01D71/56 , B01D2313/12
摘要： A separation membrane unit is provided with two separation membranes (1) which each have a separation active layer (4) formed on one surface of a sheet-like porous base material (3) and which are superposed on each other so that the separation active layers (4) face each other. The two separation membranes (1) are folded multiple times into pleats, and as a result, folds (5) are formed alternately on one side and the other side (top side and bottom side in FIG. 4A) of the two separation membranes (1). As a result of the two separation membranes (1) being superposed on each other so that the separation active layers (4) face each other, the separation active layers (4) are not exposed, and the simple configuration can prevent the separation active layers (4) from being damaged.
摘要翻译：分离膜单元设置有两个分离膜（1），每个隔膜具有在片状多孔基材（3）的一个表面上形成的彼此重叠的分离活性层（4），使得分离活性层层（4）彼此面对。将两个分离膜（1）多次折叠成褶，结果，在两个分离膜的一侧和另一侧（图4A中的顶侧和底侧）交替地形成折痕（5） 1）。由于两个分离膜（1）彼此叠合以使分离活性层（4）彼此面对，所以分离活性层（4）不暴露，并且简单的构造可以防止分离活性层（4）不被损坏。

5. 发明授权

US09504966B2 Composite semi-permeable membrane and method for producing same 有权
标题翻译：复合半透膜及其制造方法
公开(公告)号：US09504966B2
公开(公告)日：2016-11-29
申请号：US13121007
申请日：2009-09-25
申请人： Yoshihide Kawaguchi , Atsushi Hiro , Noriaki Harada , Osamu Hayashi , Atsuko Mizuike , Katsumi Ishii
发明人： Yoshihide Kawaguchi , Atsushi Hiro , Noriaki Harada , Osamu Hayashi , Atsuko Mizuike , Katsumi Ishii
IPC分类号： B01D71/56 , B01D71/46 , B01D69/02 , B01D69/12 , C02F1/44 , C02F103/04 , C02F103/08
CPC分类号： B01D69/02 , B01D69/12 , B01D71/46 , B01D71/56 , B01D2325/30 , C02F1/441 , C02F2103/04 , C02F2103/08 , Y02A20/131
摘要： It is an object of the present invention to provide a composite semi-permeable membrane exhibiting excellent chemical resistance and having practical water permeability and salt-blocking property, and a method for producing the same. The present invention relates to a composite semi-permeable membrane, including a porous support and a skin layer formed on a surface of the porous support, wherein the porous support contains a thermosetting resin porous sheet having a three-dimensional network structure and pores communicating with each other and wherein the thermosetting resin porous sheet has an average pore diameter of 0.01 to 0.4 μm.
摘要翻译：本发明的目的是提供具有优异的耐化学性并具有实用的透水性和耐盐性的复合半渗透膜及其制造方法。复合半透膜技术领域本发明涉及一种复合半透膜，其包括多孔载体和形成在所述多孔载体的表面上的表层，其中所述多孔载体包含具有三维网状结构的热固性树脂多孔片，并且与并且其中所述热固性树脂多孔片的平均孔径为0.01至0.4μm。

6. 发明申请

US20130248442A1 METHOD FOR PRODUCING POROUS EPOXY RESIN SHEET 审中-公开
标题翻译：生产多孔环氧树脂片的方法
公开(公告)号：US20130248442A1
公开(公告)日：2013-09-26
申请号：US13991695
申请日：2011-12-05
申请人： Noriaki Harada , Yoshihide Kawaguchi , Atsushi Hiro , Atsuko Mizuike , Osamu Hayashi , Katsumi Ishii , Chiaki Harada
发明人： Noriaki Harada , Yoshihide Kawaguchi , Atsushi Hiro , Atsuko Mizuike , Osamu Hayashi , Katsumi Ishii , Chiaki Harada
IPC分类号： B01D67/00
CPC分类号： B01D67/003 , B01D71/46 , B01D2323/18 , C08J9/286 , C08J2201/026 , C08J2201/0464 , C08J2363/02 , C08L63/00
摘要： Provided is a porous epoxy resin sheet produced by cutting a cured epoxy resin body to a predetermined thickness, the porous epoxy resin sheet having a large surface area and a uniform in-plane pore size distribution. A method for producing a porous epoxy resin sheet, comprising forming a cylindrical or columnar cured resin body from a resin mixture containing an epoxy resin, a curing agent, and a porogen, cutting the surface of the cured resin body at a predetermined thickness to make an epoxy resin sheet, and then removing the porogen from the sheet to render the sheet porous, wherein when the cured resin body is formed from the resin mixture, curing is performed in a state where the viscosity of the mixture is at least 1,000 mPa·s.
摘要翻译：本发明提供一种通过将固化的环氧树脂体切割成预定厚度而生产的多孔环氧树脂片，具有大的表面积和均匀的面内孔径分布的多孔环氧树脂片。一种多孔环氧树脂片的制造方法，其特征在于，包括由含有环氧树脂，固化剂，致孔剂的树脂混合物形成圆筒状或柱状的固化树脂体，将树脂固化体的表面切割成规定的厚度，环氧树脂片，然后从片材中除去致孔剂以使片材多孔，其中当由树脂混合物形成固化树脂体时，在混合物的粘度至少为1000mPa·s的状态下进行固化 s。

7. 发明申请

US20130177817A1 SEPARATOR FOR NONAQUEOUS ELECTROLYTE ELECTRICITY STORAGE DEVICES, NONAQUEOUS ELECTROLYTE ELECTRICITY STORAGE DEVICE, AND PRODUCTION METHODS THEREOF 审中-公开
标题翻译：非水电解电力储存装置的分离器，非水电解电力存储装置及其制造方法
公开(公告)号：US20130177817A1
公开(公告)日：2013-07-11
申请号：US13822883
申请日：2011-11-11
申请人： Shunsuke Noumi , Atsushi Hiro , Noriaki Harada , Yoshihide Kawaguchi
发明人： Shunsuke Noumi , Atsushi Hiro , Noriaki Harada , Yoshihide Kawaguchi
IPC分类号： H01M2/16 , H01M2/14
CPC分类号： H01M2/16 , C08J9/286 , C08J2201/0464 , C08J2363/00 , H01G11/52 , H01M2/145 , H01M2/1653 , H01M10/052 , Y02E60/13 , Y10T29/49108
摘要： The present invention aims to provide a method for producing a separator for nonaqueous electrolyte electricity storage devices, the method allowing avoidance of use of a solvent that places a large load on the environment, and also allowing relatively easy control of parameters such as the porosity and the pore diameter.The present invention relates to a method for producing a separator for nonaqueous electrolyte electricity storage devices that has a thickness ranging from 10 to 50 μm, the method including the steps of: producing an epoxy resin composition containing an epoxy resin, a curing agent, and a porogen; forming a cured product of the epoxy resin composition into a sheet shape or curing a sheet-shaped formed body of the epoxy resin composition, so as to obtain an epoxy resin sheet; and removing the porogen from the epoxy resin sheet by means of a halogen-free solvent.
摘要翻译：本发明的目的在于提供一种非水电解液蓄电装置用隔膜的制造方法，其特征在于，能够避免使用对环境造成负荷的负荷较大的溶剂的使用方法，孔径。本发明涉及一种具有10〜50μm厚度的非水电解质蓄电装置用隔膜的制造方法，其特征在于，包括以下工序：制造含有环氧树脂，固化剂和致孔剂; 将环氧树脂组合物的固化物形成片状或固化环氧树脂组合物的片状成形体，得到环氧树脂片; 并通过无卤素溶剂从环氧树脂片上除去致孔剂。

8. 发明申请

US20130098830A1 METHOD FOR PRODUCING POROUS THERMOSETTING RESIN SHEET AND COMPOSITE SEPARATION MEMBRANE USING SAME 审中-公开
标题翻译：用于制造多孔热固性树脂片的方法和使用其的复合分离膜
公开(公告)号：US20130098830A1
公开(公告)日：2013-04-25
申请号：US13807569
申请日：2011-06-30
申请人： Yuuzou Muraki , Atsushi Hiro , Noriaki Harada
发明人： Yuuzou Muraki , Atsushi Hiro , Noriaki Harada
IPC分类号： B01D69/12 , C08J9/28 , B01D63/10
CPC分类号： B01D69/12 , B01D63/10 , B01D63/103 , B01D67/003 , B01D69/10 , B01D71/46 , B01D2323/08 , B32B5/18 , B32B27/34 , B32B27/38 , C08G59/56 , C08J5/18 , C08J9/28 , C08J2201/0464 , C08J2300/24 , C08J2363/00 , C08L63/00
摘要： In the step of extracting and removing a porogen from a thermosetting resin sheet 1 containing the porogen, the porogen is extracted and removed by bringing the thermosetting resin sheet 1 into contact with a first liquid that has a relatively low temperature, and subsequently bringing the thermosetting resin sheet 1 into contact with a second liquid that has a relatively high temperature. Preferably, the temperatures of the first liquid and the second liquid are lower than or equal to the glass-transition temperature of the thermosetting resin sheet 1.
摘要翻译：在从含有致孔剂的热固性树脂片1中提取和除去致孔剂的步骤中，通过使热固性树脂片1与具有较低温度的第一种液体接触，提取并除去致孔剂，随后将热固性树脂片1与具有较高温度的第二液体接触。优选地，第一液体和第二液体的温度低于或等于热固性树脂片材1的玻璃化转变温度。

9. 发明授权

US08608964B2 Spiral reverse osmosis membrane element, method of manufacturing the same, and its use method 有权
标题翻译：螺旋反渗透膜元件及其制造方法及其使用方法
公开(公告)号：US08608964B2
公开(公告)日：2013-12-17
申请号：US11216051
申请日：2005-09-01
申请人： Atsushi Hiro , Hiroki Fujioka , Atsuhito Koumoto
发明人： Atsushi Hiro , Hiroki Fujioka , Atsuhito Koumoto
IPC分类号： B01D63/00 , B01D63/10
CPC分类号： B01D63/10 , B01D65/003
摘要： A spiral reverse osmosis membrane element that improves impregnation property of a sealing resin at edges of a membrane leaf and can effectively prevent micro-leaks. The spiral reverse osmosis membrane element comprises a cylindrically wound body comprising a perforated core tube and, spirally wound therearound, a separation membrane, a feed-side passage material and a permeation-side passage material in a laminated state, and a sealing portion for preventing a feed-side liquid and a permeation-side liquid from being mixed together, wherein the separation membrane facing the permeation-side passage material has a structure that a porous support and a skin layer are successively laminated on a non-woven fabric layer, and the sealing portion sealed with a sealing resin is provided at the edges of the separation membrane, wherein the separation membrane is impregnated with the sealing resin at least up to the vicinity of the skin layer through the porous support.
摘要翻译：一种提高密封树脂在膜片边缘的浸渍性能的螺旋反渗透膜元件，可有效防止微漏。所述螺旋反渗透膜元件包括圆筒形卷绕体，所述圆筒形卷绕体包括穿孔芯管，并且在其周围螺旋地缠绕有层压状态的分离膜，进料侧通道材料和渗透侧通道材料，以及用于防止进料侧液体和渗透侧液体混合在一起，其中面向渗透侧通道材料的分离膜具有多孔载体和表皮层依次层压在无纺布层上的结构，以及在分离膜的边缘处设置用密封树脂密封的密封部分，其中分离膜通过多孔载体至少直到皮肤层附近浸渍密封树脂。

10. 发明申请

US20060169634A1 Reverse osmosis membrane and method for producing the same 审中-公开
标题翻译：反渗透膜及其制造方法
公开(公告)号：US20060169634A1
公开(公告)日：2006-08-03
申请号：US11242049
申请日：2005-10-04
申请人： Atsushi Hiro , Masahiko Hirose , Masakatsu Takata
发明人： Atsushi Hiro , Masahiko Hirose , Masakatsu Takata
IPC分类号： B01D71/00
CPC分类号： B01D69/02 , B01D67/0093 , B01D69/125 , B01D71/56 , B01D2323/30
摘要： A reverse osmosis membrane that has alkali resistance, and therefore can maintain high boron rejection performance even at high pH region, and a method for producing the membrane are disclosed. The reverse osmosis membrane has an initial performance that a rate of change Rf (%) determined by the following equation is within ±10%: Rf(%)=((F1-F0)/F0)×100 wherein F0 is a permeation flux (m3/(m2/day)) at the initiation of operation when a sodium hydroxide aqueous solution adjusted to pH 12.0 as raw water is continuously circulated at 25° C. under pressure of 0.75 MPa, and F1 is permeation flux (m3/(m2/day)) after one week operation.
摘要翻译：具有耐碱性的反渗透膜，即使在高pH区域也能够保持高的脱硼性能，也可以公开膜的制造方法。反渗透膜具有以下等式确定的变化率Rf（％）在±10％以内的初始性能：<？in-line-formula description =“In-line Formulas”end =“lead”？> Rf（％）=（（F 1 1 -F 0）/ F 0 0）x 100 <βin-line-formula description =“In 线式“end =”tail“？>其中F 0 0是渗透通量（m 3/4 /（m 2 /天））在氢氧化钠水溶液调节至pH12.0作为原水的情况下，在25℃，0.75MPa的压力下连续循环，F 1 O 1是渗透通量（m < 3天/（m 2 /天/天））。

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