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1. 发明授权

US5430143A Preparation of metal phthalocyanines by reacting ortho-dinitriles with metal complexes 失效
标题翻译：邻苯二腈与金属配合物反应制备金属酞菁
公开(公告)号：US5430143A
公开(公告)日：1995-07-04
申请号：US135335
申请日：1993-10-13
申请人： Joachim Kranz , Wolfgang Habermann
发明人： Joachim Kranz , Wolfgang Habermann
IPC分类号： C09B47/067
CPC分类号： C09B47/067
摘要： A process is described for preparing metal phthalocyanines by reacting orthodinitriles dissolved or suspended in organic solvents or pulverulent mixtures of ortho-dinitriles with anhydrous ammine-metal carboxylate salts or metal-aminocarboxylic acid complexes without alkaline or chloride-containing additaments using an ortho-dinitrile excess of from 0.1 to 5% by weight.
摘要翻译：描述了一种通过将溶解或悬浮在有机溶剂中的正三元素或邻二腈的粉状混合物与无碱金属 - 金属羧酸盐或金属 - 氨基羧酸络合物反应而制备金属酞菁的方法，而不使用邻二丁腈过量的碱或含氯化合物为0.1〜5重量％。

2. 发明授权

US4451339A Preparation of blue iron hexacyanoferrate-III pigments, and the pigments obtained 失效
标题翻译：制备蓝色六氰合铁酸盐铁III-III颜料，得到的颜料
公开(公告)号：US4451339A
公开(公告)日：1984-05-29
申请号：US361431
申请日：1982-03-24
申请人： Joachim Kranz , Wolfgang Habermann , Harry Distler , Helmut Knittel , Karl-Ludwig Hock , Fritz Brunnmueller , Rolf Schneider
发明人： Joachim Kranz , Wolfgang Habermann , Harry Distler , Helmut Knittel , Karl-Ludwig Hock , Fritz Brunnmueller , Rolf Schneider
IPC分类号： C09C1/00 , C01C3/12 , C09C1/22 , C25B1/00
CPC分类号： C25B1/00
摘要： Blue iron hexacyanoferrate-III pigments (I) are prepared by anodic oxidation of metallic iron in hydrogen cyanide, or a reaction medium containing hydrogen cyanide, at pH 8.The process gives readily dispersible pigments (I) which are of high color strength and give brilliant, glossy colorations.
摘要翻译：蓝色铁六氰基铁酸盐-III颜料（I）通过金属铁在氰化氢中的阳极氧化或含有氰化氢的反应介质在pH <7和阳极电位为<0. = 0.76V（相对于标准氢测量电极）复合到铁-II六氰基铁酸盐-II化合物（II）中，然后以常规方式将其氧化成（I）。（II）的氧化有利地在空气或氧气中在pH 0-4和70至95℃下进行，但也可以在pH> 8下进行。该方法提供易于分散的颜料（I），其具有高的着色强度并且产生明亮的光泽着色。

3. 发明授权

US4145264A Preparation of metal-free phthalocyanines 失效
标题翻译：无金属酞菁的制备
公开(公告)号：US4145264A
公开(公告)日：1979-03-20
申请号：US884892
申请日：1978-03-09
申请人： Peter Thoma , Wolfgang Habermann , Joachim Kranz
发明人： Peter Thoma , Wolfgang Habermann , Joachim Kranz
IPC分类号： C09B47/30 , C09B47/067 , C25B3/04 , C07D207/00 , C09B47/04
CPC分类号： C09B47/067
摘要： Metal-free phthalocyanines (PC) are prepared by electrolysis, at inert electrodes, of aromatic o-dinitriles in organic liquids which contain small amounts of dissolved electrolytically conductive compounds, in the presence of hydrogen or of a compound which eliminates hydrogen under the reaction conditions and in the presence of alkaline compounds (as activators). The PC formed may be isolated in the pure form by filtration. The product contains from 90 to 99% of PC. It is used for the preparation of PC-based pigments.

4. 发明授权

US4466867A Production of blue iron hexacyanoferrate-III pigments 失效
标题翻译：生产蓝铁六氰酸铁-III颜料
公开(公告)号：US4466867A
公开(公告)日：1984-08-21
申请号：US467744
申请日：1983-02-18
申请人： Wolfgang Habermann , Peter Hammes , Joachim Felger , Karl-Ludwig Hock , Friedrich Brunnmueller , Helmut Knittel , Joachim Kranz , Rolf Schneider , Peter Thoma
发明人： Wolfgang Habermann , Peter Hammes , Joachim Felger , Karl-Ludwig Hock , Friedrich Brunnmueller , Helmut Knittel , Joachim Kranz , Rolf Schneider , Peter Thoma
IPC分类号： C09C1/26 , C25B1/00
CPC分类号： C25B1/00 , C09C1/26 , C01P2006/80
摘要： Blue iron hexacyanoferrate-III pigments are produced by a process wherein complex iron-II hexacyanoferrate-II (Berlin white) is prepared by electrolysis of an aqueous catholyte solution containing (a) an iron-II salt, (b) an alkali metal salt, an ammonium salt or a mixture of these, and (c) hydrogen cyanide, in an electrolysis cell in which the anode chamber and cathode chamber are separated by an ion exchange membrane, using an electrically conductive aqueous liquid in the anode chamber, and the iron-II hexacyanoferrate-II obtained is then converted to the blue pigment.The process gives Berlin white, which is substantially free from salt, in high yield and high purity. Pollution caused by the process is very low, since only a small amount of salt is produced. Compared with the corresponding blue pigments produced by prior art processes, the pigments obtained give purer colorations with better gloss, and are of higher color strength.
摘要翻译：通过电解含有（a）铁-II盐，（b）碱金属盐的水性阴极电解液的方法制备复合铁 - 六氰基铁酸盐-II（柏林白）的方法制备蓝色六氰合铁酸盐III- 铵盐或它们的混合物，和（c）氰化氢在电解池中，其中阳极室和阴极室由离子交换膜分离，使用阳极室中的导电含水液体，铁 -II六氰基铁酸盐-II然后转化成蓝色颜料。该方法给出柏林白色，其基本上不含盐，以高产率和高纯度。该过程造成的污染非常低，因为只产生少量的盐。与通过现有技术方法生产的相应的蓝色颜料相比，获得的颜料产生更好的着色，并具有较高的着色强度。

5. 发明授权

US4789739A Preparation of polyhalocopper phthalocyanine pigments of high color strength 失效
标题翻译：高色强度的聚氧化酞菁颜料的制备
公开(公告)号：US4789739A
公开(公告)日：1988-12-06
申请号：US111615
申请日：1987-10-23
申请人： Joachim Kranz , Karl Schmeidl
发明人： Joachim Kranz , Karl Schmeidl
IPC分类号： C09B67/20 , C09B67/00 , C09B67/12 , C09B47/04 , C09B47/08
CPC分类号： C09B67/0032 , C09B67/0016
摘要： Polyhalocopper phthalocyanine pigments of high color strength are prepared by recrystallizing the finely divided agglomerated crude pigment in a heterogeneous aqueous organic phase at elevated temperatures by a process in which the aqueous organic phase used is a heterogeneous mixture of an aliphatic ketone having a total of 3 to 9 carbon atoms and water. The process gives the pigments in the form of spherical granules which are dust-free or have a low dust content. The pigments give deep, brilliant colorations of pure hues.
摘要翻译：通过以下方法制备高色强度的聚氧化酞菁酞菁颜料，该方法是将高分子量聚集的粗颜料在高分子含水有机相中重结晶，其中使用的有机相是有机相， 9个碳原子和水。该方法得到无灰尘或具有低粉尘含量的球形颗粒形式的颜料。这些颜料可以产生纯色调的深刻，辉煌的色彩。

6. 发明授权

US4256507A Pigment formulations 失效
标题翻译：颜料配方
公开(公告)号：US4256507A
公开(公告)日：1981-03-17
申请号：US116382
申请日：1980-01-29
申请人： Joachim Kranz , Rudolf Polster , Reinhard Sappok , Alois Wiesenberger
发明人： Joachim Kranz , Rudolf Polster , Reinhard Sappok , Alois Wiesenberger
IPC分类号： C09B69/00 , C09B67/22 , C09B67/00
CPC分类号： C09B67/0036 , C09B67/0034
摘要： Formulations of flavanthrone, pyranthrone, indanthrone, indigo, quinacridone, perylene-3,4,9,10-tetracarboxylic acid dianhydride and perylene-3,4,9,10-tetracarboxylic acid diimide pigments which contain, as additives, one or more compounds of the formula ##STR1## where X is an n-valent radical of a flavanthrone, pyranthrone, indigo, quinacridone, perylene-3,4,9,10-tetracarboxylic acid dianhydride or perylene-3,4,9,10-tetracarboxylic acid diimide pigment, R.sup.1, R.sup.3 and R.sup.4 are hydrogen or chlorine, R.sup.2 is hydrogen, chlorine, carboxyl, bromine, nitro, N-C.sub.1 -C.sub.5 -alkylcarbamyl, N-phenylcarbamyl or benzoylamino and n is 1, 2, 3 or 4.In solutions of surface-coating binders or of surface coatings, the above formulations give very deep colorations, coupled with high gloss and high transparency of the resulting films.
摘要翻译：黄烷酮，吡喃酮，阴丹酮，靛蓝，喹吖啶酮，苝-3,4,9,10-四羧酸二酐和苝-3,4,9,10-四羧酸二酰亚胺颜料的制剂，其包含作为添加剂的一种或多种化合物式（I）其中X是黄烷酮，吡喃酮，靛蓝，喹吖啶酮，苝-3,4,9,10-四羧酸二酐或苝-3,4,9,10的n价基团 - 四羧酸二酰亚胺颜料，R1，R3和R4是氢或氯，R2是氢，氯，羧基，溴，硝基，N-C1-C5-烷基氨基甲酰基，N-苯基氨基甲酰基或苯甲酰基氨基，n是1,2,3或在表面涂层粘合剂或表面涂层的溶液中，上述配方产生非常深的着色，加上所得膜的高光泽度和高透明度。

7. 发明授权

US4350534A Fluid, stable formulations of copper phthalocyanine or indanthrone 失效
标题翻译：流体，铜酞菁或阴丹酮的稳定配方
公开(公告)号：US4350534A
公开(公告)日：1982-09-21
申请号：US279778
申请日：1981-07-02
申请人： Wolf D. Fechner , Joachim Kranz , Rudolf Polster
发明人： Wolf D. Fechner , Joachim Kranz , Rudolf Polster
IPC分类号： C09B67/44 , C09B67/00 , C09B67/22 , C09B47/04
CPC分类号： C09B67/0035 , C09B67/0032
摘要： A stable fluid formulation which comprises (a) finely divided .alpha.- or .beta.-copper phthalocyanines or finely divided indanthrone, one or more C.sub.6 -C.sub.18 -alkylbenzenesulfonic acids (b), a basic copper phthalocyanine (c) of the formula ##STR1## where CuPc is an n-valent copper phthalocyanine radical, R.sup.1 and R.sup.2 independently of one another are H or C.sub.1 -C.sub.8 -alkyl and n is 1, 2, 3 or 4, one or more compounds (d) which are obtained by Mannich condensation of 2-hydroxy-naphthalene, which may or may not contain 1 or 2 additional .beta.-hydroxyl groups, formaldehyde and primary or secondary aliphatic, cycloaliphatic or aromatic monoamines, diamines, triamines or polyamines or 5-membered or 6-membered heterocyclic compounds which contain an >NH-- group as a ring member and which contain from 1 to 6 .beta.-hydroxynaphthyl groups, and one or more organic liquids (e). The weight ratio (b):(c):(d) is from 1:1:1 to 2.5:1.25:1.The formulations give very deeply colored finishes with which very glossy and highly transparent coatings are obtained.
摘要翻译：一种稳定的流体制剂，其包含（a）细分的α-或β-酞菁酞菁或细碎的阴丹酮，一种或多种C 6 -C 18烷基苯磺酸（b），碱式酞菁铜（c），其具有式 CuPc是n价铜酞菁基，R1和R2彼此独立地是H或C1-C8-烷基，n是1,2,3或4，一种或多种化合物（d）是通过曼尼希缩合得到的 2-羟基 - 萘，其可以或可以不含有1或2个另外的β-羟基，甲醛和伯或仲脂族，脂环族或芳族单胺，二胺，三胺或多胺或5元或6元杂环化合物，其含有一个> NH-基团作为环成员并且含有1至6个β-羟基萘基和一种或多种有机液体（e）。重量比（b）：（c）：（d）为1:1至2.5:1.25:1。配方赋予非常深色的表面处理，从而获得非常光滑和高度透明的涂层。

8. 发明授权

US4523958A Pigment formulations and their use of pigmenting gravure printing inks and finishes 失效
标题翻译：颜料配方及其使用着色凹版印刷油墨和表面处理剂
公开(公告)号：US4523958A
公开(公告)日：1985-06-18
申请号：US475698
申请日：1983-03-15
申请人： Wolf D. Fechner , Rudolf Polster , Joachim Kranz , Eduard Hartmann
发明人： Wolf D. Fechner , Rudolf Polster , Joachim Kranz , Eduard Hartmann
IPC分类号： C09D11/00 , C09B67/20 , C09B67/22 , C09D11/02 , C09D17/00 , C09B47/04 , C09B47/08
CPC分类号： C09B67/006 , C09B67/0033 , C09D17/003
摘要： Readily dispersible formulations comprising (a) finely divided copper phthalocyanine and (b) an iron hexacyanoferrate-III pigment are obtained by thoroughly milling a mixture of (a) and (b).The performance characteristics and tinctorial properties of the formulations comprising (a) and (b) can be improved by incorporating (c) a Mannich condensate obtained from 2-hydroxynaphthalene which may or may not possess 1 or 2 further .beta.-OH groups, formaldehyde and a primary or secondary amine, (d) a compound of the formula K(-NH-CONH-R).sub.2, where K is 1,5-naphthylene or 4,4'-diphenylenemethane and R is C.sub.12 -C.sub.18 -alkyl, C.sub.12 -C.sub.18 -alkenyl, C.sub.8 -C.sub.18 -alkoxypropyl or C.sub.2 -C.sub.8 -alkoxyethyleneoxypropyl, (e) a C.sub.6 -C.sub.18 -alkylbenzenesulfonic acid and (f) a mixture of (e) with a basic copper phthalocyanine and/or a salt obtained by reacting (e) with the basic copper phthalocyanine.The finishes and printing inks produced using the formulations have tinctorial properties and performance characteristics which are superior to those of finishes and inks obtained by mixing individually milled or dispersed components.
摘要翻译：通过对（a）和（b）的混合物进行彻底研磨，得到包含（a）细分铜酞菁和（b）六氰基铁酸盐-III颜料的铁素体的易分散配方。包含（a）和（b）的制剂的性能特征和着色性能可以通过加入（c）由2-羟基萘得到的曼尼希缩合物来改善，其可以含有或不具有1或2个另外的β-OH基团，甲醛和伯胺或仲胺，（d）式K（-NH-CONH-R）2的化合物，其中K是1,5-亚萘基或4,4'-二苯基甲烷，R是C 12 -C 18烷基，C 12 C 18 - 烯基，C 8 -C 18烷氧基丙基或C 2 -C 8 - 烷氧基亚乙基氧基丙基，（e）C 6 -C 18烷基苯磺酸和（f）（e）与碱性铜酞菁和/ （e）与碱性铜酞菁。使用该制剂生产的表面处理剂和印刷油墨具有优于通过混合单独研磨或分散组分获得的表面处理和油墨的着色性能和性能特征。

9. 发明授权

US4490176A Fluid, stable formulations 失效
标题翻译：流体，稳定配方
公开(公告)号：US4490176A
公开(公告)日：1984-12-25
申请号：US429232
申请日：1982-09-30
申请人： Wolf D. Fechner , Joachim Kranz , Rudolf Polster
发明人： Wolf D. Fechner , Joachim Kranz , Rudolf Polster
IPC分类号： C09D17/00 , C09D11/00
CPC分类号： C09D17/002
摘要： Stable, fluid formulations contain (a) finely divided iron cyano complexes, iron-III oxides or iron-III oxide hydrates, (b) one or more C.sub.6 -C.sub.18 -alkylbenzenesulfonic acid, (c) one or more compounds which are obtained by Mannich condensation from 2-hydroxynaphthalene, which may or may not contain 1 or 2 additional .beta.-hydroxyl groups, formaldehyde and primary or secondary aliphatic, cycloaliphatic or aromatic monoamines, diamines, triamines or polyamines or 5- or 6-membered heterocyclic compounds, and which contain from 1 to 6 .beta.-hydroxynaphthyl groups, and (d) one or more organic liquids, the ratio of (b):(c) being from 1:8 to 2:1 and the amount of (c) being from 10 to 20% by weight, based on (a).The formulations are fluid or pourable at pigment concentrations of from 20 to 55% by weight and give very deeply colored, very glossy finishes.
摘要翻译：稳定的流体配方含有（a）细分铁氰基配合物，铁-III氧化物或铁-III氧化物水合物，（b）一种或多种C 6 -C 18烷基苯磺酸，（c）一种或多种由Mannich获得的化合物 2-羟基萘的缩合，其可以含有或不含有1或2个另外的β-羟基，甲醛和伯或仲脂族，脂环族或芳族单胺，二胺，三胺或多胺或5-或6-元杂环化合物，其中含有1至6个β-羟基萘基，和（d）一种或多种有机液体，（b）：（c）的比例为1:8至2:1，（c）的量为10至 20重量％，基于（a）。制剂在20至55重量％的颜料浓度下是流体或可倾倒的，并且产生非常深色的非常光泽的表面。

10. 发明授权

US4239549A Easily water-dispersed formulations of finely divided phthalocyanines 失效
标题翻译：易分散的酞菁的水分散配方
公开(公告)号：US4239549A
公开(公告)日：1980-12-16
申请号：US815986
申请日：1977-07-15
申请人： Wolfgang Fabian , Joachim Kranz , Guenter Stoeckelmann
发明人： Wolfgang Fabian , Joachim Kranz , Guenter Stoeckelmann
IPC分类号： C09B67/00 , C09B67/46 , C09B47/04 , D06P3/14 , D06P3/60
CPC分类号： C09B67/0086 , C09B67/0032
摘要： Easily water-dispersed formulations of a phthalocyanine pigment which contain--based on the formulation--(a) from 70 to 95% by weight of finely divided phthalocyanine pigment of which the mean primary particle size is less than 0.5 .mu.m, and (b) from 30 to 5% by weight of one or more alkylarylsulfonic acids, where alkyl is of 4 to 20 carbon atoms, but the sum of the alkyl carbon atoms is not less than 8, which alkylarylsulfonic acids may be in the form of water-soluble salts. A fine dispersion of the formulations is obtainable by sprinkling the formulations into water and shaking. The dispersions obtained are stable and can be filtered through a paper filter without leaving a residue. The finely dispersed pigment is absorbed quantitatively on wool, cotton or paper pulp.
摘要翻译：含有 - （a）70-95％重量的平均一次粒径小于0.5μm的细碎酞菁颜料的酞菁颜料的易水分散配方，和（b） 30至5重量％的一种或多种烷基芳基磺酸，其中烷基为4至20个碳原子，但烷基碳原子数之和不小于8，该烷基芳基磺酸可以是水溶性形式盐。制剂的精细分散体可以通过将制剂喷洒到水中并摇动来获得。获得的分散体是稳定的，可以通过纸过滤器过滤而不留下残余物。细分散的颜料在羊毛，棉花或纸浆上定量吸收。

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