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    • 3. 发明授权
    • 마이크로파 조사에 의한 칼코파이라이트형 화합물의제조방법
    • 具有微波辐射的氯仿型化合物的制备方法
    • KR100867665B1
    • 2008-11-10
    • KR1020070108908
    • 2007-10-29
    • 한국화학연구원
    • 황영규장종산정성화황진수이혜영
    • C01G3/00C01B17/00C01B19/00C01G15/00
    • C01B19/002B82Y30/00C01P2002/72C01P2004/64Y10S977/777Y10S977/813
    • A manufacturing method of chalcopyrite type compound by radiating a microwave is provided to supply the chalcopyrite type compound in which non-interactant or oxide is not mixed by improving solubilities of the VI family elemental powder Cu salt which is generated reactant when manufacturing the chalcopyrite type compound consisting of III family element and VI family element, III family element and VI family elemental powder, and to mass-produce efficiently a high purity of chalcopyrite compound because a reaction time is short and a non-interactant does not remain. A mixed solution is manufactured by mixing a Cu salt, a III group element salt and a Vl family elemental powder into a mixture of a chelating agent, and an ionic liquid or the chelating agent and the ionic liquid. The mixed solution is injected in a reactor and heat by irradiating a microwave. The Chalcopyrite type compound is expressed by chemical formula 1 of CuM^1M^22. In the chemical formula 1, M is one or more selected from the III group element. M is one or more selected from the Vl group element.
    • 提供通过辐射微波的黄铜矿型化合物的制造方法,通过提高在制造黄铜矿型化合物时产生的反应物的VI族元素粉末Cu盐的溶解度来提供不混合不相互作用剂或氧化物的黄铜矿型化合物 由III族元素和VI族元素,III族元素和VI族元素粉末组成,并且由于反应时间短并且不残留非相互作用剂,因此有效地大量生产高纯度的黄铜矿化合物。 通过将Cu盐,III族元素盐和Vl族元素粉末混合到螯合剂和离子液体或螯合剂和离子液体的混合物中来制备混合溶液。 将混合溶液注入反应器中并通过照射微波加热。 黄铜矿型化合物由CuM ^ 1M ^ 22的化学式1表示。 在化学式1中,M是选自III族元素中的一种或多种。 M是从Vl组元素中选择的一个或多个。