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1. 发明授权

KR101588052B1 발효액으로부터 부티르산을 추출하고 부티르산을 바이오연료로 화학적으로 전환하는 방법 有权
标题翻译：从肉汤中提取丁酸并化学转化为生物燃料的方法
公开(公告)号：KR101588052B1
公开(公告)日：2016-01-25
申请号：KR1020090020368
申请日：2009-03-10
申请人： 에스케이이노베이션 주식회사 , 한국과학기술연구원
发明人： 강신영 , 박철희 , 윤영식 , 조인호 , 안형웅 , 박삼룡 , 송종희 , 이성호 , 상병인 , 서영웅 , 엄영순 , 이선미
IPC分类号： C12P7/16 , C10G3/00 , C10L1/30
CPC分类号： C12P7/16 , C12P7/52 , Y02E50/17 , Y02E50/343 , Y02P30/20
摘要： 본발명은탄수화물발효액에포함된부티르산을바이오연료로전환하는방법에관한것으로서, 보다구체적으로는, 탄수화물의발효를통한부티르산생성과정에서발생되는가스로부터바이오수소를분리하고불용성용매를사용하여발효액중의부티르산을추출한다음, 에스테르화반응을통하여부티르산으로부터부틸부티레이트를생산하고, 생산된부틸부티레이트의전부또는일부를가수소분해하여부탄올을얻는과정을포함하는화학적전환방법에관한것이다. 본발명은바이오부탄올을효율적이고경제적으로생산할수 있으며, 기존의바이오디젤(지방산메틸에스테르)에비하여산화안정도가월등하여새로운바이오연료로서의가치를갖는부틸부티레이트를함께생산할수 있는효과를갖는다.

2. 发明公开

KR1020090103720A 발효액으로부터 부티르산을 추출하고 부티르산을 바이오연료로 화학적으로 전환하는 방법 有权
标题翻译：从肉汤中提取丁酸并化学转化为生物燃料的方法
公开(公告)号：KR1020090103720A
公开(公告)日：2009-10-01
申请号：KR1020090020368
申请日：2009-03-10
申请人： 에스케이이노베이션 주식회사 , 한국과학기술연구원
发明人： 강신영 , 박철희 , 윤영식 , 조인호 , 안형웅 , 박삼룡 , 송종희 , 이성호 , 상병인 , 서영웅 , 엄영순 , 이선미
IPC分类号： C12P7/16 , C10G3/00 , C10L1/30
CPC分类号： C12P7/16 , C12P7/52 , Y02E50/17 , Y02E50/343 , Y02P30/20
摘要： PURPOSE: A method for extracting butyric acid from fermented liquid and chemically converting the butyric acid to a bio fuel is provided to produce butyl butyrate as the bio fuel. CONSTITUTION: A method for producing bio fuel from fermented butyric acid comprises: a step of providing fermentation liquid containing butyric acid through fermentation of carbohydrate to liquid extracting tower; a step of using trialkylamine as extraction solvent to produce the butyric acid in the form of trialkylammonium butyrate; a step of adding the extracted trialkylammonium butyrate to isolate butyric acid and trialkylamine; a step of supplying trialkyl amine to the liquid extracting tower as a extraction solvent; and a step of reacting the butyric acid with butanol to convert to butyl butylate.
摘要翻译：目的：提供从发酵液中提取丁酸和将丁酸化学转化为生物燃料的方法，以生产丁酸丁酯作为生物燃料。构成：从发酵丁酸生产生物燃料的方法包括：通过将碳水化合物发酵至液体提取塔提供含有丁酸的发酵液的步骤; 使用三烷基胺作为提取溶剂来生产丁酸三烷基铵形式的丁酸的步骤; 加入提取的丁酸三烷基铵以分离丁酸和三烷基胺的步骤; 将三烷基胺作为萃取溶剂供给到液体萃取塔中的步骤; 以及使丁酸与丁醇反应以转化为丁基丁酸酯的步骤。

3. 发明公开

KR1020140147068A 저온 유동성을 개선한 경제적인 수첨 파라핀 형태의 디젤 탄화수소의 제조 방법 有权
标题翻译：经济地制造具有改进的冷流特性的加氢分离柴油碳氢化合物的方法
公开(公告)号：KR1020140147068A
公开(公告)日：2014-12-29
申请号：KR1020140153747
申请日：2014-11-06
申请人： 에스케이이노베이션 주식회사 , 에스케이에너지 주식회사
发明人： 주영환 , 김경록 , 유재욱 , 김도완 , 송종희 , 최선 , 황윤맹
IPC分类号： C10G3/00 , C10L1/08
CPC分类号： C10G3/52 , C10G3/50 , C10G45/32 , C10G45/58 , C10G65/043 , C10G65/06 , C10G65/08 , C10G2300/802 , C10G2400/04 , C10L1/026 , C10L1/08 , Y02E50/13 , Y02P30/20
摘要： The present invention relates to a method of manufacturing paraffinic diesel hydrocarbon by adding hydrogen to a feed stock containing triglyceride (TG) to remove oxygen in the form of water, CO, or CO_2, in which a portion of an output of a deoxygenation reaction undergoes an isodewaxing reaction and is then recycled to be diluted with fresh feed and simultaneously undergo a hydro-deoxygenation reaction.
摘要翻译：本发明涉及一种通过向含有甘油三酯（TG）的原料中加入氢以除去氧，CO或CO 2形式的氧的方法，其中一部分脱氧反应的产物经历进行异源脱蜡反应，然后再循环以用新鲜进料稀释，同时进行加氢脱氧反应。

4. 发明公开

KR1020120120625A 해조류로부터 혼합 카르복시산 제조 방법 无效
标题翻译：通过使用海草制备混合的羧酸盐
公开(公告)号：KR1020120120625A
公开(公告)日：2012-11-02
申请号：KR1020110038327
申请日：2011-04-25
申请人： 에스케이이노베이션 주식회사 , 에스케이에너지 주식회사
发明人： 박철희 , 조인호 , 김윤화 , 이승엽 , 윤영식 , 송종희
IPC分类号： C12P7/40 , C12N9/14 , C12R1/89
摘要： PURPOSE: A method for preparing carboxylic acid by fermenting marine algae under an anaerobic condition is provided to obtain carboxylic acid of high yield and to prevent pollution. CONSTITUTION: A method for preparing mixed carboxylic acid comprises hot water treatment, acid treatment, alkaline treatment, or enzyme treatment and from marine algae by anaerobic fermentation. The method further comprises a step of pulverizing the marine algae in a particle size of 20-300 um. The hot water treatment is performed by adding water to the marine algae in a ratio of 1:1-1:20 and treating at 60-200 Deg. C. for 5-120 minutes. The acid treatment is performed by adding 0.1-5%(w/w) of acidic solution and treating at 60-200 Deg. C. for 5-120 minutes. The alkaline treatment is performed by adding 0.1-5%(w/w) of an alkaline solution to the marine algae and treating at 60-200 Deg. C. for 5-120 minutes. Bio fuel is prepared through microorganism fermentation or chemical reaction using carboxylic acid. [Reference numerals] (AA) Marine Biomass(Gelidium amansii LAMOUROUX ); (BB) Kind of produced organic acid
摘要翻译：目的：提供在厌氧条件下发酵海藻制备羧酸的方法，以获得高产率的羧酸并防止污染。构成：制备混合羧酸的方法包括热水处理，酸处理，碱处理或酶处理，并通过厌氧发酵从海藻中提取。该方法还包括粉碎粒度为20-300μm的海藻的步骤。热水处理通过以1:1-1:20的比例向海藻中加水并以60-200度处理来进行。 C.为5-120分钟。酸处理通过加入0.1-5％（w / w）的酸性溶液并以60-200度处理。 C.为5-120分钟。通过向海藻中加入0.1-5％（w / w）的碱性溶液并以60-200度处理进行碱处理。 C.为5-120分钟。通过使用羧酸的微生物发酵或化学反应制备生物燃料。（附图标记）（AA）海洋生物质（Gelidium amansii LAMOUROUX）; （BB）生产的有机酸的种类

5. 发明公开

KR1020150137601A 고점도 수용성 폴리머 및 이를 포함하는 고점도 수용액의 제조방법 审中-实审
标题翻译：高粘度水溶性聚合物及其高粘度溶液的制造方法
公开(公告)号：KR1020150137601A
公开(公告)日：2015-12-09
申请号：KR1020140065722
申请日：2014-05-30
申请人： 에스케이이노베이션 주식회사
发明人： 가두연 , 정주은 , 구건효 , 송종희 , 정태문 , 최혁준
IPC分类号： C08J3/02 , C08F8/44 , C08F220/18 , C08F220/56 , C08F220/38 , C08F222/00 , C08L101/02
摘要： 본발명은고점도수용성폴리머를용매에용해한후 염기를가하여제조되는고점도수용액제조방법으로, 상기고점도수용액은점도비가하기식 1을만족하는것인고점도수용액제조방법에관한것이다. [식 1] 0.3 ≤ cps1/cps2 ≤ 0.7 (상기식 1에서 cps1은고점도수용성폴리머를 NaCl 3%용액에 0.5%농도로용해하고 18번스핀들, 25℃, 7.5rpm 조건에서측정된점도이며, cps2는상기 cps1 측정후 수용액에염기를가하여수용액의 pH를 7로조절한후 cps1과동일한조건에서측정된점도이다.) 본발명에따른고점도수용성폴리머및 이를포함하는고점도수용액의제조방법은아크릴산단량체에하나이상의수용성단량체를포함하는고점도공중합체제조시 pH를 7이하로낮춘조건에서중합하여고점도수용액제조시 불용분의생성을획기적으로낮출수 있으며, 이를통해수용액제조시 점도가매우높고, 불용분이거의발생하지않아여과공정에소요되는시간이단축되는장점이있다. 이를바탕으로본 발명에따라제조된고점도수용성폴리머는화학적석유회수증진(chemical flooding enhanced oil recovery)용고분자, 화장품등의수계증점제, 보습제, 유화제, 현택제등에널리사용될수 있다.
摘要翻译：本发明涉及通过在将高粘度水溶性聚合物溶解在溶剂中之后添加碱而制备高粘度溶液的方法。在高粘度溶液中，粘度比满足下式1.在式1中：cps1是在纺丝18的条件下测定的粘度，25℃的温度，以及溶解高粘度之后的转速为7.5rpm 在3％NaCl溶液中浓度为0.5％的水溶性聚合物; cps2是在将碱加入溶液后，在与cps1相同的条件下测量的粘度，在测量cps1后将溶液的pH调节至7。本发明的高粘度水溶性高分子和含有该高粘度水溶液的高粘度水溶液的制备方法，在通过使pH高的条件下进行聚合而制备高粘度溶液时，可以显着降低不溶物的产生， 7或更低，当制备其中一种或多种水溶性单体包括在丙烯酸单体中的高粘度共聚物时。因此，粘度非常高，在制备溶液时几乎不产生不溶物质，从而减少过滤过程所消耗的时间。因此，本发明制备的高粘度水溶性聚合物可广泛用于化学驱油强化油回收用聚合物，化妆品等水性增稠剂，保湿剂，乳化剂，悬浮剂等等

6. 发明授权

KR101746905B1 저온 유동성을 개선한 경제적인 수첨 파라핀 형태의 디젤 탄화수소의 제조 방법 有权
标题翻译：用于生产具有改进的低温流动性的经济的氢化石蜡型柴油烃的方法
公开(公告)号：KR101746905B1
公开(公告)日：2017-06-14
申请号：KR1020140153747
申请日：2014-11-06
申请人： 에스케이이노베이션 주식회사 , 에스케이에너지 주식회사
发明人： 주영환 , 김경록 , 유재욱 , 김도완 , 송종희 , 최선 , 황윤맹
IPC分类号： C10G3/00 , C10L1/08
CPC分类号： C10G3/52 , C10G3/50 , C10G45/32 , C10G45/58 , C10G65/043 , C10G65/06 , C10G65/08 , C10G2300/802 , C10G2400/04 , C10L1/026 , C10L1/08 , Y02E50/13 , Y02P30/20
摘要： 본발명은트리글리세리드(Triglyceride, TG)를함유하는공급원료에수소를첨가하여물, CO, CO형태로산소를제거하는데있어서, 탈산소반응의결과물중 일부를이성화반응시킨후 재순환하여신규공급원료(Fresh Feed)를희석한상태로다시수첨탈산소화반응을수행하여파라핀형태의디젤탄화수소를제조하는방법에관한것이다.
摘要翻译：本发明的甘油三酯（甘油三酯，TG）通过加入氢与含有在CO形式除去氧的水，CO，新原料中的原料，通过反应后的回收利用一些脱氧反应异构酶的产物（新鲜饲料）进行稀释，然后进行氢气脱氧反应以制备石蜡型柴油烃。

7. 发明公开

KR1020120103499A 저온 유동성을 개선한 경제적인 수첨 바이오디젤의 제조 방법 无效
标题翻译：具有改进的冷流特性的经济生产氢化生物体的方法
公开(公告)号：KR1020120103499A
公开(公告)日：2012-09-19
申请号：KR1020120024181
申请日：2012-03-09
申请人： 에스케이이노베이션 주식회사 , 에스케이에너지 주식회사
发明人： 주영환 , 김경록 , 유재욱 , 김도완 , 송종희 , 황윤맹 , 최선
IPC分类号： C10G3/00 , C10L1/08
CPC分类号： C10G3/52 , C10G3/50 , C10G45/32 , C10G45/58 , C10G65/043 , C10G65/06 , C10G65/08 , C10G2300/802 , C10G2400/04 , C10L1/026 , C10L1/08 , Y02E50/13 , Y02P30/20
摘要： PURPOSE: A producing method of bio-hydrogenated diesel having improved low temperature fluidity is provided to prevent the excessive temperature rise of a reactant. CONSTITUTION: A producing method of bio-hydrogenated diesel comprises the following steps: hydro-deoxygenating supplied materials containing triglyceride(2, 4); separating the result into vapor compound and liquid compound; removing light components and impurities from the liquid compound(14); isomerizing 67-80% of the result from the previous step, and re-circulating the result to mix with the supplied materials(23, 27); and obtaining the remaining 20-33% of the result as a finished product(21). [Reference numerals] (AA) Low-temperature hydro-deoxygenating reaction block; (BB) High-temperature hydro-deoxygenating reaction block; (CC) Impurities; (DD) H2 purification facility; (EE) CHPS; (FF) HHPS; (GG) Water; (HH) Compressor; (II) Impurities and hard materials; (JJ) Isomerizing reaction; (KK) Stripper; (LL) Products
摘要翻译：目的：提供具有改善的低温流动性的生物氢化柴油的生产方法，以防止反应物过度升温。构成：生物氢化柴油的制备方法包括以下步骤：含有甘油三酯的加氢脱氧供料（2,4）; 将结果分离成蒸汽化合物和液体化合物; 从液体化合物（14）中除去轻质成分和杂质; 异构化上一步骤结果的67-80％，并将结果重新循环到与所提供的材料（23,27）混合; 并获得作为成品的剩余20-33％的结果（21）。（AA）低温加氢反应块; （BB）高温加氢脱氧反应块; （CC）杂质; （DD）H2净化设备; （EE）CHPS; （FF）HHPS; （GG）水; （HH）压缩机; （二）杂质和硬质材料; （JJ）异构化反应; （KK）剥线钳; （LL）产品

8. 发明公开

KR1020100096408A 해조류 추출물로부터 불균일계 촉매를 이용한 가수분해를 통해 바이오 연료를 제조하는 방법 无效
标题翻译：通过使用异源催化剂通过海藻提取物的水解生产生物油的方法
公开(公告)号：KR1020100096408A
公开(公告)日：2010-09-02
申请号：KR1020090015275
申请日：2009-02-24
申请人： 에스케이이노베이션 주식회사
发明人： 윤영식 , 고기호 , 송종희 , 오승훈 , 조인호 , 강신영 , 박철희 , 이성호
IPC分类号： C10G3/00 , C12P5/00 , C12P7/04 , B01J23/70
CPC分类号： C12P7/08 , B01J31/10 , C10G2300/1011 , C10L1/023 , C10L1/026 , C13K1/00 , C13K1/02 , C13K13/00 , Y02E50/13 , Y02P20/584 , Y02P30/20
摘要： PURPOSE: A method for manufacturing biofuels is provided to reduce by-product process costs and production costs through hydrolysis of seaweed extract using a heterogeneous catalyst, to enable a user to recycle the heterogeneous catalyst, and to remarkably improving productivity. CONSTITUTION: A method for manufacturing biofuels comprises a step of hydrolyzing seaweed extract, which is extracted from red algae, brown algae, and green algae, using a heterogeneous catalyst and a step of fermenting Hydrolysates using microorganisms or through chemical reactions. The red algae include laver, gelidium amansii, and gracilaria. The brown algae include sea mustard, kelp, sea weed fusiforme, gulfweed, Ecklonia stolonifera, and sea oak.
摘要翻译：目的：提供一种制造生物燃料的方法，以通过使用多相催化剂水解海藻提取物来减少副产物工艺成本和生产成本，使用户能够回收多相催化剂，并显着提高生产率。构成：制造生物燃料的方法包括使用多相催化剂水解从海藻，褐藻和绿藻中提取的海藻提取物的步骤，以及使用微生物或通过化学反应发酵水解产物的步骤。红藻类包括紫菜，，，和gr。。棕色藻类包括海芥，海藻，海草梭菌，海绵草，Ecklonia stolonifera和海栎。

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