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    • 3. 发明公开
    • 유전체 세라믹 및 그 제조방법, 적층 세라믹 콘덴서
    • 包含PEROVSKITE复合颗粒和晶体氧化物颗粒的电介质陶瓷作为晶体颗粒,其制造方法和多层陶瓷电容器
    • KR1020040078565A
    • 2004-09-10
    • KR1020040013984
    • 2004-03-02
    • 가부시키가이샤 무라타 세이사쿠쇼
    • 나카무라도모유키가토아키라무토가즈오사노하루노부
    • H01G4/12
    • H01G4/30H01G4/1227Y10T29/43
    • PURPOSE: A dielectric ceramic, a manufacturing method thereof, and a multilayer ceramic capacitor are provided to achieve improved reliability even in case where a dielectric ceramic layer has a reduced thickness. CONSTITUTION: A dielectric ceramic comprises crystal grains, and crystal boundary and triple points arranged between the crystal grains. The crystal grains includes Perovskite compound grains(21) which are consisted of a Perovskite compound expressed as ABO3(wherein, A is Ba and Ca, Ba, or Ca and Sr, and B is Ti, or at least one of Zr and Hf), and crystal oxide grains(22) which are consisted of a crystal oxide containing at least Ba, Ti and Si. From among the triple points, 80% or higher of the number of the triple points have cross section areas of 8nm¬2 or lower.
    • 目的:提供电介质陶瓷及其制造方法和多层陶瓷电容器,以便即使在电介质陶瓷层具有减小的厚度的情况下也可实现提高的可靠性。 构成:电介质陶瓷包括晶粒,并且晶体边界和三重点排列在晶粒之间。 晶粒包括由以ABO3表示的钙钛矿化合物(其中A为Ba和Ca,Ba或Ca和Sr,B为Ti或Zr和Hf中的至少一种)的钙钛矿化合物晶粒(21) ,和由至少包含Ba,Ti和Si的结晶氧化物构成的晶体氧化物晶粒(22)。 在三重点中,三重点数的80%以上的截面积为8nm2以下。
    • 4. 发明授权
    • 유전체 세라믹 조성물 및 적층 세라믹 캐패시터
    • 유전체세라믹조성물및적층세라믹캐패시터
    • KR100443231B1
    • 2004-08-04
    • KR1020010073044
    • 2001-11-22
    • 가부시키가이샤 무라타 세이사쿠쇼
    • 나카무라도모유키하타고타로사노하루노부
    • C04B35/468H01B3/12H01G4/12
    • B32B18/00C04B35/468C04B2235/768C04B2237/066C04B2237/068C04B2237/123C04B2237/346C04B2237/348C04B2237/68
    • Provided is a dielectric ceramic composition suitably used for forming dielectric ceramic layers which constitute a laminated ceramic capacitor obtained by firing in a reducing atmosphere. Even when the dielectric ceramic composition is formed into thin dielectric ceramic layers, a highly reliable laminated ceramic capacitor having a small temperature coefficient of capacitance, a long lifetime under high temperature and high pressure conditions, and a small change in electrostatic capacitance with time under a DC voltage application can be realized. The dielectric ceramic composition contains a primary component, an additive component, and an auxiliary sintering agent, wherein the primary component and the additive component are represented by the formula 100BaTiO3+a{(1-b)R+bV}+cM, and 1.25 1.1 are satisfied. R is a compound containing at least one element selected from the group consisting of La, Ce, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb and Lu; V is a compound containing vanadium; and M is a compound containing at least one element selected from the group consisting of Mn, Ni, Mg, Fe and Zn.
    • 本发明提供适合用于构成在还原气氛中烧成而成的层叠陶瓷电容器的电介质陶瓷层的电介质陶瓷组合物。 即使在将电介质陶瓷组合物形成为薄的电介质陶瓷层的情况下,也能够提供电容温度系数小,高温高压下的寿命长,静电电容随时间的变化小的可靠性高的层叠陶瓷电容器 直流电压应用可以实现。 介电陶瓷组合物含有主要组分,添加剂组分和辅助烧结剂,其中主要组分和添加剂组分由式100BaTiO3 + a {(1-b)R + bV} + cM表示,并且1.25 ≤a≤8.0,0≤b≤0.2,1.0≤c≤6.0和a /c≥1.1。 R是含有选自La,Ce,Pr,Nd,Sm,Eu,Gd,Th,Dy,Ho,Er,Tm,Yb和Lu中的至少一种元素的化合物; V是含有钒的化合物; M是含有选自Mn,Ni,Mg,Fe和Zn中的至少一种元素的化合物。
    • 8. 发明授权
    • 세라믹 커패시터 및 그 제조방법
    • 세라믹커패시터및그제조방법
    • KR100374470B1
    • 2003-03-04
    • KR1020000033214
    • 2000-06-16
    • 가부시키가이샤 무라타 세이사쿠쇼
    • 하타코타로오카마츠도시히로나카무라도모유키호리겐지사노하루노부
    • H01G4/30
    • H01G4/1245H01G4/1218H01G4/1236
    • A ceramic capacitor has a dielectric ceramic layer and at least one pair of electrodes. The dielectric ceramic layer has a primary phase and secondary phases, and the size of the secondary phases in the thickness direction of the dielectric ceramic layer is not more than about one-third of the thickness of the dielectric ceramic layer. A method for making the ceramic capacitor includes the steps of mixing compounds constituting secondary phases in a primary phase of a dielectric ceramic, annealing and then pulverizing the mixture to prepare a raw material for the secondary phases, mixing the raw material for the secondary phases with other materials for the dielectric ceramic shaping and sintering the mixture to form a dielectric ceramic, and forming electrodes on the dielectric ceramic. The ceramic capacitor has high insulation resistance, superior load characteristics at high temperatures or high humidity and high weather resistance, even when sintered in a reducing atmosphere.
    • 陶瓷电容器具有介电陶瓷层和至少一对电极。 介电陶瓷层具有第一相和第二相,并且介电陶瓷层的厚度方向上的第二相的尺寸不大于介电陶瓷层的厚度的约三分之一。 制造陶瓷电容器的方法包括以下步骤:在介电陶瓷的主相中混合构成第二相的化合物,退火然后粉碎混合物以制备用于第二相的原料,将用于第二相的原料与 用于介电陶瓷的其他材料成形并烧结该混合物以形成介电陶瓷,以及在介电陶瓷上形成电极。 陶瓷电容器即使在还原气氛中烧结,也具有高绝缘电阻,高温或高湿度下的优异负载特性和高耐候性。
    • 10. 发明公开
    • 세라믹 커패시터 및 그 제조방법
    • 陶瓷电容器及其制造
    • KR1020010029809A
    • 2001-04-16
    • KR1020000033214
    • 2000-06-16
    • 가부시키가이샤 무라타 세이사쿠쇼
    • 하타코타로오카마츠도시히로나카무라도모유키호리겐지사노하루노부
    • H01G4/30
    • H01G4/1245H01G4/1218H01G4/1236
    • PURPOSE: To obtain a ceramic capacitor having a high insulation resistance, a superior service life characteristic, and superior wheatherability, by forming the dielectric ceramic layer of the capacitor in such a way that secondary phases having sizes which are equal to a specific rate of the thickness of the ceramic layer or smaller in the thickness direction of the layer exist in the ceramic layer separately from main phases. CONSTITUTION: In the dielectric ceramic layer 2b of a laminated ceramic capacitor 1, secondary phases 3 exist separately from main phases and the sizes of the phases 3 are adjusted to
    • 目的:通过形成电容器的介电陶瓷层,获得具有高绝缘电阻,优异的使用寿命特性和优异的可磨性的陶瓷电容器,使得二次相的尺寸等于 陶瓷层的厚度或层的厚度方向上的厚度与主相分开存在于陶瓷层中。 构成:在层叠陶瓷电容器1的电介质陶瓷层2b中,次级相3与主相分开存在,相3的尺寸被调整为<=厚度方向的层2b的厚度的1/3 层2b。 构成层2b的电介质陶瓷具有由式ABO 3表示的组成(其中A和B分别表示从Ba,Sr,Ca和Mg中选出的至少一种元素,以及选择的至少一种元素的输出Ti ,Zr和Hf)。 优选在电介质陶瓷中添加主要由SiO 2或B 2 O 3组成的玻璃成分,以便即使陶瓷在中性或还原性气氛中烘烤,陶瓷也不会降低陶瓷的不可还原性。