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    • 1. 发明授权
    • 태양전지 전해질 보호용 경화성 실리콘계 실링재 조성물의 제조방법
    • 生产用于太阳能电池电解质保护的可固化硅酮密封胶组合物的方法
    • KR101792677B1
    • 2017-11-02
    • KR1020160030048
    • 2016-03-14
    • 한경덕
    • 한경덕김정식이상문이상군
    • C09K3/10C08F283/12C08J3/24C08L83/10
    • 본발명은태양전지전해질보호용경화성실리콘계실링재조성물의제조방법에관한것으로, 더욱상세하게는 a) 사이클릭실록산모노머를중합하여폴리디메틸실록산올리고머를제조하는폴리디메틸실록산올리고머제조단계, b) 제조된폴리디메틸실록산올리고머에관능기를갖는제1모노머를중합하여관능성올리고머를제조하는관능성올리고머제조단계, c) 제조된관능성올리고머를감압증류하여미반응모노머를제거하는미반응모노머제거단계, d) 미반응모노머가제거된올리고머에비휘발성올리고머, 관능기를갖는제2모노머및 반응촉매를혼합하고중합하여프레폴리머를제조하는프레폴리머제조단계, e) 상기프레폴리머에비닐계모노머및 중합개시제를혼합하고공중합하는공중합단계, f) 제조된공중합물에가교제를혼합하여가교된중합물을제조하는가교단계및 g) 상기가교된중합물에경화제를혼합하는경화단계로이루어진다. 상기의과정을통해제조되는태양전지전해질보호용경화성실리콘계실링재조성물은실리콘계모노머가사용되어투명성, 신율, 내열성, 내구성, 내화학성및 밀폐성이우수하다.
    • 更具体地说,本发明涉及通过聚合a)环状硅氧烷单体以制备聚二甲基硅氧烷低聚物来生产聚二甲基硅氧烷低聚物的方法,b) 具有在低聚物官能低聚物的生产步骤的官能团用于生产官能低聚物的第一单体的二甲基硅氧烷和,c)中通过在减压下蒸馏,将制备的官能低聚物,除去未反应的单体的未反应的单体除去工序,d) 未反应的单体,其中除去低聚物,预聚物生产阶段进行期间组合的非挥发性低聚物的第二单体混合和具有官能团用于生产预聚物,E)混合在预聚物中的乙烯基类单体和聚合引发剂的催化剂 F)将生产的共聚物与交联剂混合以制备交联聚合物的交联步骤,以及g)交联步骤 它包括固化剂混合以交联聚合物的固化步骤。 即通过上述步骤制造的太阳能保护电解质固化的有机硅密封剂组合物所使用的硅系单体是yiwoosu透明度,断裂伸长率,耐热性,耐久性,耐化学性和气密性。
    • 2. 发明授权
    • 터치패널 인쇄잉크에 적용되는 저온경화형 바인더의 제조방법
    • 用于触摸面板打印墨水的低温固化型粘合剂的制造方法
    • KR101381719B1
    • 2014-04-07
    • KR1020130040543
    • 2013-04-12
    • 한경덕주식회사 엘 앤 에프
    • 정영철강해욱이상문이상군김군용우가영한경덕
    • C09D11/10C08F2/50C08F2/38H01L31/042
    • Y02E10/50C09D11/10C08F2/38C08F2/50H01L31/042
    • The present invention relates to a method for manufacturing a low-temperature cure type binder applied to a touch panel printing ink, and more specifically, to a method comprising: a functional oligomer manufacturing step for manufacturing a functional oligomer; a copolymerization step for copolymerizing by mixing a polymerization initiator into the functional oligomer manufactured through the functional oligomer manufacturing step; a reaction stopping step for inserting a reaction stopping agent into a reaction solution having undergone the copolymerization step; a monomer removal step for removing unreacted monomers included in the reaction solution wherein the copolymerization step is stopped through the reaction stopping step. The low-temperature cure type binder manufactured by the steps provides a print layer displaying excellent adhesiveness, low electric resistance, a print film in uniform thickness, uniform print width, print effectiveness when performing continuous printing, and excellent durability after printing. [Reference numerals] (AA) Start; (BB) End; (S101) Functional oligomer manufacturing step; (S103) Copolymerization step; (S105) Reaction stopping step; (S107) Monomer removal step
    • 本发明涉及一种应用于触摸面板印刷油墨的低温固化型粘合剂的制造方法,更具体地说,涉及一种制造功能性低聚物的功能低聚物的制造工序。 通过将聚合引发剂与通过功能性低聚物制造工序制造的功能性低聚物混合而共聚的共聚工序; 反应停止步骤,用于将反应停止剂插入已经进行共聚步骤的反应溶液中; 用于除去反应溶液中所含的未反应单体的单体除去步骤,其中通过反应停止步骤停止共聚步骤。 通过这些步骤制造的低温固化型粘合剂提供了显示出优异的粘附性,低电阻,均匀厚度的印刷膜,均匀的印刷宽度,进行连续印刷时的印刷效果和印刷后的优异的耐久性的印刷层。 (附图标记)(AA)开始; (BB)结束; (S101)功能性低聚物制造工序; (S103)共聚步骤; (S105)反应停止步骤; (S107)单体除去步骤
    • 3. 发明公开
    • 시알티용 디스플레이 패널의 내면복합코팅막의 박리세정용조성물
    • CRT显示面板的洗涤剂组合物
    • KR1020080000264A
    • 2008-01-02
    • KR1020060057918
    • 2006-06-27
    • 한경덕
    • 한경덕이상문오상헌
    • C11D1/40C11D7/10C11D3/43C11D11/00C11D11/04
    • C11D1/40C11D3/43C11D7/10C11D11/0047C11D11/0064C11D11/04
    • A stripping composition for an inner composite coating layer of a display panel for cathode ray tubes is provided to realize excellent cleaning capability to a composite coating layer, and to reduce environmental pollution. A stripping composition for an inner composite coating layer of a display panel for cathode ray tubes is obtained by the method comprising the steps of: introducing 0.1-2 mol/l of an amine-based surfactant, 0.1-2 mol/l of polyoxyethylene octylamine ether and 0.1-2 mol/l of a catalyst into a reactor with teflon lining and agitating the reaction mixture; introducing 1-3 mol/l of an inorganic salt having a fluoride ion into the reactor; heating the reaction mixture to 60-80 deg.C; and cooling the reaction mixture after an acid fluoride salt is obtained through an ammonium substitution reaction.
    • 提供用于阴极射线管的显示面板的内部复合涂层的剥离组合物,以实现对复合涂层的优异的清洁能力,并减少对环境的污染。 通过包括以下步骤的方法获得用于阴极射线管的显示面板的内复合涂层的剥离组合物:将0.1-2mol / l的胺类表面活性剂,0.1-2mol / l的聚氧乙烯辛胺 乙醚和0.1-2mol / l催化剂加入到具有聚四氟乙烯衬里和搅拌反应混合物的反应器中; 将1-3mol / l具有氟离子的无机盐引入反应器; 将反应混合物加热至60-80℃; 在通过铵取代反应得到酸式氟化物盐后,冷却反应混合物。
    • 4. 发明授权
    • 무기섬유 슬러리 성형용 수분산성 수지 조성물
    • 用于形成无机纤维污泥的水可溶性树脂组合物
    • KR1019950000990B1
    • 1995-02-06
    • KR1019900019385
    • 1990-11-28
    • 한경덕
    • 한경덕
    • C08L77/00C08L63/00
    • The water dispersible resin composition for the mfr. of the molded plate material is composed of 30-68 wt.% of a cationic polyacrylamide resin, 20-40 wt.% of an epoxy resin of formula (I), 1-2 wt.% of a cationic surfactant of formula (II) and 1-2 wt.% of a nonionic surfactant of formula (III). The mold plate material is produced by (a) mixing 0.1-1.0 wt.% of the resin composition, 20-30 wt.% of a rock wool or a glass wool, 10-15 wt.% of an inorganic filler i.e. alumina silicate, calcium silicate, zeolite, alumina hydrate, calcium carbonate or magnesium carbonate in water, (b) molding the mixture, and (c) heat drying it. The resin composition has a good water-repellency, coaggulance and reinforcing property, and is used in the mfr. of heat insulating and sound absorbing materials.
    • 水分散性树脂组合物 的模塑板材料由30-68重量%的阳离子聚丙烯酰胺树脂,20-40重量%的式(I)环氧树脂,1-2重量%的式(II)的阳离子表面活性剂 )和1-2重量%的式(III)的非离子表面活性剂。 模板材料通过以下方法制备:(a)混合0.1-1.0重量%的树脂组合物,20-30重量%的岩棉或玻璃棉,10-15重量%的无机填料,即硅酸铝 ,硅酸钙,沸石,水合氧化铝,碳酸钙或碳酸镁在水中,(b)成型混合物,和(c)加热干燥。 该树脂组合物具有良好的防水性,共聚性和增强性,并且以制造商使用。 的绝热和吸音材料。
    • 7. 发明授权
    • 시알티용 디스플레이 패널의 내면복합코팅막의 박리세정용조성물
    • 用于CRT显示面板的洗涤剂组合物
    • KR100810195B1
    • 2008-03-06
    • KR1020060057930
    • 2006-06-27
    • 한경덕
    • 한경덕이상문오상헌
    • C11D1/40C11D7/10C11D3/43C11D11/00C11D11/04
    • 본 발명은 산성불소염을 포함함을 특징으로 하는 CRT(Cathode Ray Tube)용 디스플레이 패널(Diplay panel)의 내면복합코팅막의 박리세정용 조성물 및 이의 제조방법에 관한 것으로서, 상세하게는 아민계 계면활성제 0.1-2 mol/ℓ, PEA 0.1-2 mol/ℓ및 촉매 0.1-2 mol/ℓ를 테플론 라이닝(Teflon lining) 반응기에 투입하여 교반하는 단계; 냉각수로 반응기를 냉각하면서 불산 1-3 mol/ℓ을 상기 반응기에 투입하는 단계; 산성불소염이 합성된 후 냉각하는 단계로 구성됨을 특징으로 한다.
      본 발명의 산성불소염은 휘발성이 강한 불산과 고비점 친수성 아민계 계면활성제를 반응시킨 것으로서, 흑연코팅, 형광체 코팅, 표면코팅, 알미늄 증착공정에서 제조된 디스플레이 패널 내면 복합코팅막을 박리세정할 경우 불산 사용에 따른 인체 및 환경오염을 축소하고 설비부식 및 폐수처리 등에서의 비용이 절감 등의 효과를 가지며, CRT용 디스플레이 패널의 회수, 재사용으로 인한 브라운관 재료비의 원가절감의 효과가 있어 CRT 제조 산업에 있어서 유용한 발명이다.
      CRT, 디스플레이 패널, 박리세정, 산성불소염
    • 8. 发明公开
    • 컬러브라운관의 형광체 표면 코팅용 코팅액 조성물
    • 彩色管状荧光物质涂层表面涂料溶液组合物
    • KR1020040008817A
    • 2004-01-31
    • KR1020020042528
    • 2002-07-19
    • 한경덕
    • 한경덕이재열
    • C09K11/02
    • C09K11/02C09K11/08H01J29/20H01J29/32
    • PURPOSE: A coating solution composition for coating the surface of a fluorescent substance of a color Braun tube is provided, to prevent the residue due to a coating solution composition from being left when an aluminum evaporation-deposition layer is formed on the coating solution and to improve the brightness of a fluorescent surface. CONSTITUTION: The coating solution composition comprises 2-10 wt% of a copolymer as a binder resin; a diluent; and an additive, wherein the copolymer is obtained by copolymerizing 10-50 wt% of vinyl toluene modified acrylate, 10-50 wt% of methyl methacrylate, 10-50 wt% of isobutyl methacrylate, and 5-50 wt% of at least one copolymeric monomer selected from acrylic acid, methacrylic acid, butyl acrylic acid, hydroxy methacrylate, maleic acrylate and t-butyl aminoacyl acrylate preferably in the presence of a catalyst by solution polymerization, and has a molecular weight of 5,000-50,000. Preferably the catalyst is at least one selected from the group consisting of benzyl peroxide, hydrogen peroxide, di-t-butyl peroxide, lauroyl peroxide, t-butyl hydroperoxide, cumene hydroperoxide and azoisobutyronitrile.
    • 目的:提供一种用于涂布彩色布朗管荧光物质表面的涂布溶液组合物,以防止在涂布溶液上形成铝蒸发沉积层时留下涂层溶液组合物残留物, 提高荧光表面的亮度。 构成:涂布液组合物含有2-10重量%的作为粘合剂树脂的共聚物; 稀释剂 和一种添加剂,其中共聚物通过共聚10-50重量%的乙烯基甲苯改性的丙烯酸酯,10-50重量%的甲基丙烯酸甲酯,10-50重量%的甲基丙烯酸异丁酯和5-50重量%的至少一种 共聚单体选自丙烯酸,甲基丙烯酸,丁基丙烯酸,羟基甲基丙烯酸酯,马来酸丙酯和叔丁基氨基酰基丙烯酸酯,优选在催化剂存在下通过溶液聚合,并且具有5,000-50,000的分子量。 优选地,催化剂是选自苄基过氧化物,过氧化氢,二叔丁基过氧化物,过氧化月桂酰,叔丁基过氧化氢,枯烯氢过氧化物和偶氮异丁腈中的至少一种。
    • 10. 发明公开
    • 친환경 위생분필
    • 友谊环保型卫生。。
    • KR1020090086837A
    • 2009-08-14
    • KR1020080012324
    • 2008-02-11
    • 한경덕이경애
    • 이상문오상헌한경덕이경애
    • C09D13/00
    • C09D13/00B43K19/003
    • An environment-friendly hygienic chalk is provided to be hygienic, to generate little dust generation and to prevent the chalk from being smeared on the skin by forming a coating layer on the external side of the chalk main body. An environment-friendly hygienic chalk comprises a chalk main body formed with filler 10-15 parts by weight, non-toxid pigment 40-60 parts by weight and binder 40-50 parts by weight; and a coating layer applied on the external side of the chalk main body. The filler is obtained by mixing titanium oxide 30-45 parts by weight, calcium carbonate 5-10 parts by weight, talc 3-5 parts by weight, fatty acid modified ester 30-45 parts by weight and fatty acid modified alcohol 5-10 parts by weight.
    • 提供环保卫生白垩是卫生的,通过在白垩主体的外侧形成涂层,产生少量的粉尘产生并防止白垩被污染在皮肤上。 一种环保卫生白垩包括由10-15重量份的填料形成的白垩主体,40-60重量份的无毒颜料和40-50重量份的粘合剂; 以及施加在白垩主体的外侧的涂层。 填充剂是将30-45重量份氧化钛,5-10重量份碳酸钙,滑石3-5重量份,30-45重量份脂肪酸改性酯和脂肪酸改性醇5-10 重量份。