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    • 2. 发明专利
    • Metal air secondary battery
    • 金属空气二次电池
    • JP2010287390A
    • 2010-12-24
    • JP2009139260
    • 2009-06-10
    • Toyota Motor Corpトヨタ自動車株式会社
    • MIZUNO FUMINORINAKANISHI SHINJI
    • H01M12/08H01M4/96
    • Y02E60/128
    • PROBLEM TO BE SOLVED: To provide a metal air secondary battery capable of suppressing capacity degradation due to charging and discharging.
      SOLUTION: The metal air secondary battery comprises an air electrode having an air electrode layer including a conductive material and an air electrode collector for performing current collection of the air electrode layer, an anode having an anode layer including an anode active material and an anode collector for performing current collection of the anode layer, and a nonaqueous electrolyte for performing conduction of metal ions between the air electrode layer and the anode layer. The conductive material is needlelike carbon of an average aspect ratio of 10 or more.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供能够抑制由于充放电引起的容量劣化的金属空气二次电池。 解决方案:金属空气二次电池包括具有包括导电材料的空气电极层的空气电极和用于进行空气电极层的电流收集的空气电极集电体,具有阳极层的阳极,阳极层包括阳极活性材料和 用于进行阳极层的集电的阳极集电体,以及用于在空气极层和阳极层之间进行金属离子传导的非水电解质。 导电材料是平均纵横比为10以上的针状碳。 版权所有(C)2011,JPO&INPIT
    • 4. 发明专利
    • Air battery system
    • 空气电池系统
    • JP2009032415A
    • 2009-02-12
    • JP2007192267
    • 2007-07-24
    • Toyota Motor Corpトヨタ自動車株式会社
    • NAKANISHI SHINJIMIZUNO FUMINORI
    • H01M12/08H01M10/44H01M10/48
    • Y02E60/128
    • PROBLEM TO BE SOLVED: To provide an air battery system having a favorable cycle characteristic.
      SOLUTION: The problem is solved by providing the air battery system including an air battery cell having: an air electrode having an air electrode layer containing a conductive material and an air electrode power collector for collecting electric power from the air electrode layer; a negative electrode having a negative electrode layer containing a negative electrode active material that adsorbs and releases Li ions and a negative electrode power collector for collecting electric power from the negative electrode layer; a separator provided between the air electrode layer and the negative electrode layer; and the fluorine-containing electrolyte with which at least the separator is impregnated, and also including a discharge controller that terminates the discharge of the air battery cell, wherein a discharge final voltage of the discharge controller is 2.3 V or higher based on an Li metal.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供具有良好循环特性的空气电池系统。 解决方案:通过提供一种包括空气电池单元的空气电池系统来解决问题,所述空气电池单元具有:具有包含导电材料的空气电极层的空气电极和用于从空气电极层收集电力的空气电极集电器; 具有含有负极活性物质的负极层的负极,负极活性物质吸附并释放Li离子,负极集电体用于从负极层收集电力; 设置在所述空气极层和所述负极层之间的隔膜; 以及至少含有隔膜的含氟电解质,并且还包括终止空气电池单元的放电的放电控制器,其中,放电控制器的放电最终电压基于Li金属为2.3V以上 。 版权所有(C)2009,JPO&INPIT
    • 5. 发明专利
    • Porous carbon and metal air battery
    • 多孔碳和金属气体电池
    • JP2014017230A
    • 2014-01-30
    • JP2012231029
    • 2012-10-18
    • Toyota Motor Corpトヨタ自動車株式会社Toyo Tanso Kk東洋炭素株式会社
    • MINAMI KEIICHIMIZUNO FUMINORIMORISHITA TAKAHIROHATSUSHIRO YOSHIO
    • H01M12/08H01M4/96H01M12/06
    • Y02E60/128
    • PROBLEM TO BE SOLVED: To provide porous carbon capable of providing a metal air battery improved in output characteristics while securing high capacity, and a metal air battery including the porous carbon in a positive electrode.SOLUTION: Porous carbon used for a positive electrode of a metal air battery includes a pore containing a meso pore and a micro pore having a pore size smaller than that of the meso pore. A carbonaceous wall configuring an outer shell of the meso pore forms a three dimensional network structure, and the micro pore is formed in the carbonaceous wall. The meso pore is an open pore, and pore portions are continuous to form a connection hole. A half-value width of a pore size distribution of the pore is 2 nm or less, and a half-value width of a connection hole size distributing of the connection hole is 50 nm or more.
    • 要解决的问题:提供能够提供在确保高容量的输出特性方面提高金属空气电池的多孔碳,以及在正极中包含多孔碳的金属空气电池。解决方案:用于正极的多孔碳 金属空气电池包括含有中孔的孔和孔径小于中孔的孔的微孔。 构成中孔的外壳的碳质壁形成三维网状结构,微孔形成在碳壁中。 中孔是开孔,孔部分连续形成连接孔。 孔的孔径分布的半值宽度为2nm以下,连接孔的连接孔尺寸的半值宽度为50nm以上。
    • 6. 发明专利
    • Metal-air battery
    • 金属电池
    • JP2013037999A
    • 2013-02-21
    • JP2011174979
    • 2011-08-10
    • Toyota Motor Corpトヨタ自動車株式会社
    • MIZUNO FUMINORI
    • H01M12/08H01M2/02H01M12/06
    • Y02E60/128
    • PROBLEM TO BE SOLVED: To provide a metal-air battery excellent in volumetric efficiency and an energy density.SOLUTION: The metal-air battery comprises: a power generation element in which an air electrode comprising an air electrode layer which uses oxygen as an active material, a negative electrode comprising a negative electrode layer which contains a negative electrode active material, and an electrolyte layer disposed between the air electrode layer and the negative electrode layer and conducting metallic ions, are layered; and a flexible outer casing accommodating the power generation element and made of a flexible film. The air electrode has a layered structure composed of the air electrode layer which is nearer to the electrolyte layer, and an air electrode collector having conductivity and a porous structure; the flexible outer casing comprises an oxygen inlet hole communicating with the air electrode collector; and a pressure equal to or higher than normal pressures is applied to the power generation element in the layering direction with an oxygen-containing gas for supplying oxygen to the oxygen inlet hole, from the outside of the flexible outer casing.
    • 要解决的问题:提供容积效率和能量密度优异的金属空气电池。 解决方案:金属空气电池包括:发电元件,其中空气电极包括使用氧作为活性材料的空气电极层,负极包括负极层,负极层含有负极活性材料, 并且层叠设置在空气极层和负极层之间并导电金属离子的电解质层; 以及容纳发电元件并由柔性膜制成的柔性外壳。 空气电极具有由更靠近电解质层的空气电极层构成的层状结构和具有导电性和多孔结构的空气电极集电体; 柔性外壳包括与空气电极收集器连通的氧气入口孔; 通过从柔性外壳的外部向氧气导入孔供给氧的含氧气体,在分层方向上向发电元件施加等于或高于常压的压力。 版权所有(C)2013,JPO&INPIT
    • 7. 发明专利
    • Battery
    • 电池
    • JP2012174341A
    • 2012-09-10
    • JP2011031871
    • 2011-02-17
    • Toyota Motor Corpトヨタ自動車株式会社
    • MIZUNO FUMINORIHAMA SHIGEKIAONO MASAMICHI
    • H01M2/10
    • Y02E60/12
    • PROBLEM TO BE SOLVED: To provide a battery whose performance can be improved and can be maintained over a long period of time.SOLUTION: The battery includes: a unit cell comprising a cathode, an anode, and an electrolyte layer disposed between the cathode and the anode; and a container housing the unit cell. The unit cell is housed in an exterior material, a first gas fills the inside of the exterior material, a second gas fills the outside of the exterior material and the inside of the container, and the unit cell is pressurized using at least the first gas.
    • 要解决的问题:提供能够提高性能并且可以长时间保持的电池。 电池包括:单元电池,包括阴极,阳极和设置在阴极和阳极之间的电解质层; 以及容纳该单电池的容器。 单元电池容纳在外部材料中,第一气体填充在外部材料的内部,第二气体填充外部材料的外部和容器的内部,并且使用至少第一气体来加压单元电池 。 版权所有(C)2012,JPO&INPIT
    • 10. 发明专利
    • Metal air cell system
    • 金属气囊系统
    • JP2011065816A
    • 2011-03-31
    • JP2009214532
    • 2009-09-16
    • Toyota Motor Corpトヨタ自動車株式会社
    • MIZUNO FUMINORI
    • H01M12/08H01M12/06
    • Y02E60/128
    • PROBLEM TO BE SOLVED: To provide a metal air cell system superior in discharge performance and long durability and having a low cost and capable of securing safety.
      SOLUTION: The metal air cell system includes a metal air cell having at least an air electrode, a negative electrode, and an electrolyte interposed between the air electrode and the negative electrode; and an oxygen generating part having an oxygen generating agent generating oxygen by reacting with a component other than oxygen in the air and supplying generated oxygen to the air electrode.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供一种排出性能优异且耐久性高,成本低且能够确保安全性的金属气囊系统。 解决方案:金属气囊系统包括至少具有空气电极,负极和置于空气极和负极之间的电解质的金属气泡; 氧发生部,其具有通过与空气中的氧以外的成分反应而产生氧并向空气电极供给生成氧的氧发生剂。 版权所有(C)2011,JPO&INPIT