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1. 发明专利

JP2008285767A Highly heat-resistant fiber material for reinforcing rubber and method for producing the same 审中-公开
标题翻译：用于增强橡胶的高耐热纤维材料及其制造方法
公开(公告)号：JP2008285767A
公开(公告)日：2008-11-27
申请号：JP2007129074
申请日：2007-05-15
申请人： Toyobo Co Ltd , 東洋紡績株式会社
发明人： YOSHINO KENJI , NAGAHARA SHIGENORI , AIKAWA YASUSHI , TOTSUKA MORITO , KOBASHI MASANAO , IIZUKA NORIHISA
IPC分类号： D06M10/00 , D01F6/90 , D02G3/48 , D06M14/34 , D06M15/356
摘要： PROBLEM TO BE SOLVED: To provide a highly heat-resistant polyamide fiber material for a tire cord capable of retaining the shape of fibers composing reinforcing cords of a belt or a carcass of a tire at a high temperature, particularly a temperature of not lower than the melting point of the polyamide, and to provide a method for producing the fiber material. SOLUTION: The highly heat-resistant fiber material for reinforcing rubber which is a fiber material for reinforcing the rubber including the polyamide as a principal component has a cross-linked structure in at least a part of the polyamide molecular chain without causing hot-melt flow at a temperature of the melting point of the polyamide which is the principal component+20°C. The method for producing the highly heat-resistant fiber material for reinforcing the rubber includes irradiating the fiber material selected from an undrawn yarn prepared by melt-spinning a resin including the polyamide as the principal component, a drawn yarn obtained by hot-drawing the undrawn yarn, a twisted yarn cord prepared by twisting one or more drawn yarns together and a tire fabric prepared by weaving the twisted yarn cord, with ionizing radiation. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：为了提供一种用于轮胎帘线的高耐热性聚酰胺纤维材料，其能够在高温下，特别是在高温下，特别是高温下保持构成轮胎的带或胎体的增强帘线的纤维的形状不低于聚酰胺的熔点，并提供纤维材料的制造方法。解决方案：作为用于增强包含聚酰胺作为主要成分的橡胶的纤维材料的增强橡胶的高耐热性纤维材料在聚酰胺分子链的至少一部分具有交联结构而不引起热在作为主成分+ 20℃的聚酰胺的熔点温度下的熔融流动。制造用于增强橡胶的高耐热纤维材料的方法包括：将从通过熔融纺丝包含聚酰胺的树脂作为主要成分的未拉伸丝中选择的纤维材料照射通过热拉伸未拉伸而得到的拉伸丝纱线，通过将一根或多根拉伸丝捻合在一起而制成的加捻纱线和通过用电离辐射编织加捻纱线而制备的轮胎织物。版权所有（C）2009，JPO＆INPIT

2. 发明专利

JP2008045225A Pretreated polyester fiber for reinforcing rubber and method for producing the same 审中-公开
标题翻译：用于增强橡胶的预浸复合纤维及其制造方法
公开(公告)号：JP2008045225A
公开(公告)日：2008-02-28
申请号：JP2006219380
申请日：2006-08-11
申请人： Toyobo Co Ltd , 東洋紡績株式会社
发明人： HIRAO KOICHI , KOBASHI MASANAO , IMAOKA KATSUTOSHI
IPC分类号： D06M15/55 , D02G3/48 , D06M15/41 , D06M101/32
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a pretreated polyester fiber producible with good yarn manufacturing properties at high productivity and further suitable as a rubber reinforcing material having high dimensional stability and good adhesiveness to rubber after high-order processing without deteriorating operation efficiency of yarn manufacturing by formation of deposits of heat deteriorated materials such as an epoxy compound on the surface of a heated roller, plate, etc., during heat treatment and to provide the pretreated polyester fiber.
SOLUTION: The method for producing the pretreated polyester fiber for reinforcing the rubber includes applying a treating agent A containing the epoxy compound to a polyester fiber yarn melt spun and subjected to drawing and heat treatment with a heat-treating roller having the surface temperature set at 200-250°C. The pretreated polyester fiber for reinforcing the rubber is the pretreated polyester fiber to which the treating agent A containing the epoxy compound is applied. Furthermore, the pretreated polyester fiber has the maximum shrinkage stress point in a heat shrinkage stress curve present within the range of 200-250°C.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：解决问题的方案：提供一种生产能够以高生产率生产良好纱线制造性能的预处理聚酯纤维的方法，并且进一步适合作为高阶加工后具有高尺寸稳定性和良好粘合性的橡胶增强材料而没有在热处理期间，通过在加热辊，板等的表面上形成诸如环氧化合物的热劣化材料的沉积物，并且提供预处理的聚酯纤维，使纱线制造的操作效率降低。解决方案：用于增强橡胶的预处理聚酯纤维的制造方法包括将含有环氧化合物的处理剂A涂布在熔融纺丝的聚酯纤维纱中，并用具有表面的热处理辊进行拉伸和热处理温度设定在200-250℃。用于增强橡胶的预处理聚酯纤维是应用含有环氧化合物的处理剂A的预处理的聚酯纤维。此外，预处理的聚酯纤维在200-250℃的范围内的热收缩应力曲线中具有最大收缩应力点。版权所有（C）2008，JPO＆INPIT

3. 发明专利

JP2007303056A Polyester fiber material having high heat-resistance, tire cord, dip cord and method for producing polyester fiber material having high heat-resistance 审中-公开
标题翻译：具有高耐热性的聚酯纤维材料，轮辋，DIP烙铁和生产具有高耐热性的聚酯纤维材料的方法
公开(公告)号：JP2007303056A
公开(公告)日：2007-11-22
申请号：JP2006215440
申请日：2006-08-08
申请人： Toyobo Co Ltd , 東洋紡績株式会社
发明人： KOBASHI MASANAO , YOSHINO KENJI , NAGAHARA SHIGENORI , AIKAWA YASUSHI , NISHIMURA HIROKAZU , TOTSUKA MORITO , IIZUKA NORIHISA
IPC分类号： D01F6/62 , B60C9/00 , B60C17/00 , C08G63/685 , D01F6/92 , D02G3/28 , D02G3/48 , D03D1/00 , D03D15/00 , D06M10/00 , D06M15/41 , D06M15/693 , D06M101/32
CPC分类号： B60C9/0042 , D01F6/62 , D01F6/92 , D02G3/48
摘要： PROBLEM TO BE SOLVED: To provide a polyester fiber material, a tire cord, a dip cord and a method for producing the polyester fiber material having high heat-resistance, which provide high heat-resistance to keep the mechanical properties at a high temperature, especially above the melting point of the polyester and provide.
SOLUTION: The polyester fiber material having high heat-resistance is a polyester fiber having ethylene terephthalate unit as main repeating unit and satisfying the following properties (a) and (b) at the same time in dynamic viscoelasticity measurement. (a) The storage modulus (E') is ≥0.1 MPa at 275°C and (b) the main dispersion peak temperature of loss tangent (tanδ) is ≤148°C.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种聚酯纤维材料，轮胎帘线，浸渍帘线以及具有高耐热性的聚酯纤维材料的制造方法，其提供高耐热性以将机械性能保持在高温，特别是高于聚酯的熔点并提供。解决方案：具有高耐热性的聚酯纤维材料是具有对苯二甲酸乙二醇酯单元作为主要重复单元的聚酯纤维，并且在动态粘弹性测量中同时满足以下性能（a）和（b）。（a）275℃下的储能模量（E'）≥0.1MPa，（b）损耗角正切（tanδ）的主分散峰值温度≤148℃。版权所有（C）2008，JPO＆INPIT

4. 发明专利

JP2007284805A Radiation induced crosslinking polyester fiber 审中-公开
标题翻译：辐射诱导交联聚酯纤维
公开(公告)号：JP2007284805A
公开(公告)日：2007-11-01
申请号：JP2006110400
申请日：2006-04-13
申请人： Toyobo Co Ltd , 東洋紡績株式会社
发明人： TOTSUKA MORITO , YOSHINO KENJI , NAGAHARA SHIGENORI , KOBASHI MASANAO , NISHIMURA HIROKAZU , AIKAWA YASUSHI , IIZUKA NORIHISA
IPC分类号： D01F6/92 , C08G63/91 , D01F6/62 , D06M10/00
CPC分类号： C08G63/91
摘要： PROBLEM TO BE SOLVED: To provide a radiation induced crosslinking polyester fiber imparting heat resistance for maintaining a shape at high temperatures, particularly a temperature not lower than the melting point of the polyester by exposing the polyester fiber to ionizing radiation. SOLUTION: The radiation induced crosslinking polyester fiber is obtained as follows. When the molecular chain ends of a polyester having a high degree of polymerization are reacted with a compound having a specific structure, the amount of the polyester molecular chain ends and the amount of functional groups derived from the compound are regulated within suitable ranges. Melt spinning is then carried out. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供辐射诱导的交联聚酯纤维，其通过将聚酯纤维暴露于电离辐射而赋予耐热性，以保持高温下的形状，特别是不低于聚酯熔点的温度。解决方案：辐射诱导的交联聚酯纤维如下获得。当具有高聚合度的聚酯的分子链末端与具有特定结构的化合物反应时，聚酯分子链的末端数量和衍生自化合物的官能团的量被调节在合适的范围内。然后进行熔融纺丝。版权所有（C）2008，JPO＆INPIT

5. 发明专利

JP2008038295A High heat-resistant polyester dipped cord and method for producing the same 审中-公开
标题翻译：高耐热聚酯切割线及其制造方法
公开(公告)号：JP2008038295A
公开(公告)日：2008-02-21
申请号：JP2006215441
申请日：2006-08-08
申请人： Toyobo Co Ltd , 東洋紡績株式会社
发明人： KOBASHI MASANAO , YOSHINO KENJI , NAGAHARA SHIGENORI , AIKAWA YASUSHI , NISHIMURA HIROKAZU , TOTSUKA MORITO , IIZUKA NORIHISA
IPC分类号： D02G3/48 , B60C9/00 , D01F6/62 , D01F6/92 , D02G3/28 , D02G3/40 , D06M10/00 , D06M15/00 , D06M15/41 , D06M15/693
CPC分类号： B60C9/0042 , D01D5/12 , D01D10/00 , D01F6/62 , D01F6/92
摘要： PROBLEM TO BE SOLVED: To obtain a high heat-resistant polyester dipped cord for rubber reinforcement, which retains mechanical properties without melting and breaking at a high temperature, especially at the melting point of ordinary polyester or above and to provide a method for producing the same.
SOLUTION: The high heat-resistant polyester dipped cord is composed of a polyester fiber having an ethylene terephthalate unit as a main repeating unit and simultaneously satisfies properties of (a) the melting and breaking temperature in a thermal creep measurement is ≥275°C, (b) the strength is ≥4.0 cN/dtex, and (c) the elongation at 2.0 cN/dtex load is ≤5.0%.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：为了获得在高温下，特别是在普通聚酯或以上的熔点下保持机械性能而不熔化和断裂的高耐热聚酯浸渍帘线，并提供一种方法为了生产相同。
解决方案：高耐热涤纶浸渍帘线由具有对苯二甲酸乙二醇酯单元作为主要重复单元的聚酯纤维组成，同时满足（a）热蠕变测量中的熔融断裂温度≥275的性能 ℃，（b）强度≥4.0cN/ dtex，（c）2.0cN / dtex载荷下的伸长率≤5.0％。版权所有（C）2008，JPO＆INPIT

6. 发明专利

JP2007169833A Polyester tire cap ply cord and method for producing the same 审中-公开
标题翻译：聚酯轮胎皮带及其制造方法
公开(公告)号：JP2007169833A
公开(公告)日：2007-07-05
申请号：JP2005369750
申请日：2005-12-22
申请人： Toyobo Co Ltd , 東洋紡績株式会社
发明人： IMAOKA KATSUTOSHI , KOBASHI MASANAO
IPC分类号： D06M13/11 , B29D30/40 , B60C9/00 , D02G3/26 , D02G3/40 , D02G3/48 , D02J1/22 , D06M13/395 , D06M15/00 , D06M15/41 , D06M15/693 , D06M15/70 , D06M101/32
CPC分类号： B60C9/0042 , D06M13/11 , D06M13/395 , D06M15/55 , D06M15/693 , D06M2101/32 , D06M2200/50
摘要： PROBLEM TO BE SOLVED: To provide a polyester tire cap ply cord which has high elastic modulus and remarkably improved fatigue resistance and adhesiveness to rubbers, and to provide a method for producing the same.
SOLUTION: This method for producing the polyester tire cap ply cord includes treating a polyester fiber material in a first treating bath containing (A) a polyepoxide compound, (B) a blocked polyisocyanate compound and (C) a rubber latex and having a solid content weight ratio (A)/[(A)+(B)] of 0.05 to 0.9 and solid content weight ratio (C)/[(A)+(B)] of 0.5 to 15 as a treating liquid to impart adhesiveness to rubbers to the polyester fiber material, treating the polyester fiber material in the second treating bath containing a resorcinol-formalin-rubber latex, and then thermally treating the treated polyester fiber material under a normalizing tension adjusted to ≥0.2 cN/dtex.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种具有高弹性模量和显着提高的耐疲劳性和对橡胶的粘附性的聚酯轮胎胎冠帘布帘线，并提供其制造方法。聚酯轮胎胎冠帘线帘线的制造方法包括在含有（A）多环氧化合物，（B）封端多异氰酸酯化合物和（C）橡胶胶乳的第一处理浴中处理聚酯纤维材料，并且具有固体成分重量比（A）/ [（A）+（B）]为0.05〜0.9，固体成分重量比（C）/ [（A）+（B）]为0.5〜对聚酯纤维材料的橡胶的粘附性，在含有间苯二酚 - 甲醛 - 胶乳的第二处理槽中处理聚酯纤维材料，然后在调整至≥0.2cN/ dtex的归一化张力下热处理经处理的聚酯纤维材料。版权所有（C）2007，JPO＆INPIT

7. 发明专利

JP2006002327A Rubber-reinforcing polyester cord and method for producing the same 有权
标题翻译：橡胶增强聚酯线及其制造方法
公开(公告)号：JP2006002327A
公开(公告)日：2006-01-05
申请号：JP2005143962
申请日：2005-05-17
申请人： Toyobo Co Ltd , 東洋紡績株式会社
发明人： KOBASHI MASANAO , IMAOKA KATSUTOSHI
IPC分类号： D06M15/693 , D02G3/26 , D02G3/36 , D02G3/40 , D02G3/48 , D03D1/00 , D03D15/00 , D06M13/11 , D06M13/395 , D06M15/00 , D06M15/41 , D06M101/32
摘要： PROBLEM TO BE SOLVED: To provide a rubber-reinforcing polyester cord having a high modulus of elasticity, extremely improved in heat-resistant adhesion and retention of strength, when exposed to a high temperature for a long time in rubber, and suitable for a tire cap ply use, and to provide a method for producing the same.
SOLUTION: This method for producing the rubber-reinforcing polyester cord comprises treating a polyester fiber material through single-stage, double-stage, or multi-stage treatment, by combining four components of (A) a treating liquid containing a carrier, (B) an aqueous blocked isocyanate solution, (C) a dispersion of an epoxy compound, and (D) a resorcinol-formaldehyde-latex (RFL) mixed liquid as treating liquids, in case of furnishing the polyester fiber material with adhesion to the rubber, wherein the polyester fiber material is treated with a first treating liquid into which at least (A) the treating liquid containing the carrier is mixed, then treated with a second treating liquid into which at least (D) the RFL mixed liquid is mixed, and further heat-treated under a normalizing tension controlled to be 0.2 cN/dtex or more, after treated with the second treating liquid in a final stage.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：为了提供一种具有高弹性模量的橡胶增强聚酯帘线，在橡胶中长期暴露于高温下时，耐热粘合性和强度保持性极大地提高，并且适合并且提供其制造方法。解决方案：用于生产橡胶增强聚酯帘线的方法包括通过单级，双级或多级处理来处理聚酯纤维材料，通过组合（A）含有载体的处理液体的四种组分，（B）水性封端异氰酸酯溶液，（C）环氧化合物的分散体和（D）间苯二酚 - 甲醛胶乳（RFL）混合液体作为处理液体，在提供聚酯纤维材料粘附到橡胶，其中聚酯纤维材料用至少（A）含有载体的处理液体的第一处理液处理，然后用至少（D）RFL混合液体的第二处理液处理在最终阶段用第二处理液处理后，在归一化张力控制为0.2cN / dtex以上进一步进行热处理。版权所有（C）2006，JPO＆NCIPI

8. 发明专利

JP2005068635A Polyester fiber for rubber reinforcement and dipped cord 审中-公开
标题翻译：用于橡胶加固和DIPPED的聚酯纤维
公开(公告)号：JP2005068635A
公开(公告)日：2005-03-17
申请号：JP2004357536
申请日：2004-12-10
申请人： Toyobo Co Ltd , 東洋紡績株式会社
发明人： KOBASHI MASANAO , IMAOKA KATSUTOSHI , SAKUTA MITSUHIRO
IPC分类号： D01F6/62 , D02G3/36 , D02G3/48
摘要： PROBLEM TO BE SOLVED: To provide a polyester fiber for rubber reinforcement, which has high elastic modulus and low shrinkage and further has excellent strength utilization factor in dip treatment, and to provide a dip cord.
SOLUTION: The polyester fiber containing polyethylene terephthalate at 90 mol% or more of the whole repeating unit in the molecular chain thereof and having an intrinsic viscosity (IV) of ≥0.85 dl/g satisfies simultaneously the following characteristics: (a) strength≥6.0 cN/dtex; (b) strength×(breaking elongation)
0.5 ≥26.0 cN/dtex.%
0.5 ; (c) single filament fineness≤5.0 dtex; and (d) main dispersion peak temperature of loss tangent (tan δ) in the measurement of dynamic viscoelasticity at 110 Hz≤147.0°C.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供一种具有高弹性模量和低收缩率的橡胶增强聚酯纤维，并且在浸渍处理中还具有优异的强度利用系数，并提供浸渍帘线。解决方案：特性粘度（Ⅳ）≥0.85dl/ g的聚酯纤维含有分子链全部重复单元的90摩尔％以上的聚对苯二甲酸乙二醇酯同时满足以下特征：（a）强度≥6.0cN / dtex; （b）强度×（断裂伸长率） 0.5 ≥26.0cN/ dtex。％ 0.5 （c）单丝细度≤5.0分特; 和（d）在110Hz≤147.0℃下动态粘弹性测量中的主分散峰值温度损耗角正切（tanδ）。版权所有（C）2005，JPO＆NCIPI

9. 发明专利

JP2007177360A Method for producing ply cord for polyester tire cap 审中-公开
标题翻译：用于生产聚酯轮胎胎圈的方法
公开(公告)号：JP2007177360A
公开(公告)日：2007-07-12
申请号：JP2005375784
申请日：2005-12-27
申请人： Toyobo Co Ltd , 東洋紡績株式会社
发明人： KOBASHI MASANAO , IMAOKA KATSUTOSHI
IPC分类号： D06M15/693 , B60C9/00 , C08J5/04 , D02G3/26 , D02G3/48 , D06M13/11 , D06M13/395 , D06M15/00 , D06M15/41 , D06M15/70 , D06M101/32
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a ply cord for a polyester tire cap, hardly causing deterioration of adhesion in a state embedded in rubber after a long time at high temperature, being embedded in the rubber, having reduced fatigue deterioration under repeated elongation and compression, being produced in excellent productivity, having excellent adhesion to the rubber and cord strength, and also having high modulus.
SOLUTION: The method for producing the ply cord for the polyester tire cap comprises treating a polyester fiber with an adhesive composition containing a terpolymer rubber latex comprising 40-60 wt.% conjugated diene-based monomer, 13-20 wt.% vinylpyridine-based monomer and 25-45 wt.% styrenic monomer, and subjecting the resultant fiber to heat treatment under a normalizing tension regulated to ≥0.2 cN/dtex.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：解决问题的方案为了提供一种聚酯轮胎胎冠帘布层的制造方法，在高温下长时间嵌入橡胶中的状态下，几乎不会在橡胶中嵌入的状态下的粘合性劣化，在重复伸长和压缩下的疲劳劣化，以优异的生产率生产，具有优异的橡胶密合性和帘线强度，并且还具有高模量。解决方案：聚酯轮胎帽的层帘线的制造方法包括用含有40-60重量％共轭二烯类单体的三元共聚物橡胶胶乳的粘合剂组合物处理聚酯纤维，13-20重量％乙烯基吡啶类单体和25-45％（重量）苯乙烯类单体，并使得到的纤维在调节至≥0.2cN/ dtex的标准化张力下进行热处理。版权所有（C）2007，JPO＆INPIT

10. 发明专利

JP2006274530A Polyester fiber material that has improved adhesion with rubber, and method for producing the same 审中-公开
标题翻译：用橡胶改善粘合剂的聚酯纤维材料及其制造方法
公开(公告)号：JP2006274530A
公开(公告)日：2006-10-12
申请号：JP2005196212
申请日：2005-07-05
申请人： Toyobo Co Ltd , 東洋紡績株式会社
发明人： IMAOKA KATSUTOSHI , KOBASHI MASANAO
IPC分类号： D06M13/11 , B60C9/00 , B60C9/20 , D06M15/00 , D06M15/41 , D06M15/55 , D06M15/564 , D06M15/693 , D06M101/32
摘要： PROBLEM TO BE SOLVED: To provide polyester fiber material for reinforcing rubber that has high elastic modulus, markedly improved heat-resistant adhesion in the case where the cords are buried in rubber compound and exposed to high temperature for a long time and in the high temperature atmosphere and further has a cord hardness softened to a practically acceptable level on the viewpoint of the fatigue resistance and of the fabrication of the rubber-reinforced products. SOLUTION: When an epoxy compound is previously applied in the yarn-making step or the cord-twisting step and the adhesion property to the rubber is given to the polyester fiber material, the polyester fiber material is treated with the treating solution including (A) blocked isocyanate aqueous solution, (B) epoxy resin dispersion and (C) resorcinol-formaldehyde-latex (RFL) through a one-step or two or more multiple step, thereby producing polyester fiber material for reinforcing rubber that has improved adhesion with the rubber for treating the polyester fiber material. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：为了提供具有高弹性模量的增强橡胶用聚酯纤维材料，在将帘线埋入橡胶混合物中并长时间暴露于高温的情况下，显着提高耐热粘合性高温气氛，并且在耐疲劳性和橡胶增强制品的制造的观点上，还具有软化到实用可接受水平的帘线硬度。解决方案：当在生丝步骤或捻线步骤中预先施加环氧化合物时，向聚酯纤维材料施加与橡胶的粘附性，则将聚酯纤维材料用包括（A）通过一步或两步以上的多步骤封闭的异氰酸酯水溶液，（B）环氧树脂分散体和（C）间苯二酚 - 甲醛胶乳（RFL），从而生产具有改善粘合力的增强橡胶的聚酯纤维材料与用于处理聚酯纤维材料的橡胶。版权所有（C）2007，JPO＆INPIT

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