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    • 3. 发明专利
    • REFORMING DEVICE FOR METHANOL
    • JPS60246201A
    • 1985-12-05
    • JP10321184
    • 1984-05-22
    • TOYO ENGINEERING CORP
    • YAMAGUCHI TOSHIOOOSAKI KOUZOUNISHIMURA YOSHINORIZANMA ATSUSHIHIDAKI MORIHISA
    • C01B3/32
    • PURPOSE:To make operation easy, and to raise energy efficiency, by making a mixed gas of methanol and steam flow through a catalytic layer of reaction tubes, circulating a combustion gas between an inner column and a group of reaction tubes. CONSTITUTION:The inner column 3 is set in the cylindrical container 1, tube sheets are laid at the upper and the lower parts of the container 1 and the inner column 3, and the tube sheets are provided with the sheath pipes 22. The reaction tubes 6 containing the catalytic layer 24 are inserted into the sheath pipes 22, and supported on the top of the sheath pipes 22. The heights at the tops of the reaction tubes 6 are stepwise varied by taking header attachment into account. The circulating fan 5 is set at the top of the inner column 3. Another cylindrical column 9 is laid in the inner column 3, and a combustion gas from a burner is introduced into the cylindrical column. The inlet regulator 11 for secondary air is set before an inlet of the combustion gas, and the heater 10 for a mixed gas of methanol and steam is set at the rear part of the flow. By this reforming device, methanol is efficiently decomposed to give hydrogen.
    • 4. 发明专利
    • IMPROVED REACTOR
    • JPS60150824A
    • 1985-08-08
    • JP682684
    • 1984-01-18
    • TOYO ENGINEERING CORP
    • ZANMA ATSUSHINISHIMURA YOSHINORISHIYOUJI KAZUOSHIMAGAKI MAKOTONAKAJIMA YOUICHI
    • B01J8/06B01J8/02B01J8/04
    • PURPOSE:To prevent rise of temperature for a pressure resistant vessel by making the produced gas which is flowed out ultimately from a catalytic layer to be exchanged thermally with a heat exchanger for gaseous starting material at low temp. which is flowed into the first catalyst layer and enabling gas to be cooled thereby. CONSTITUTION:A catalyst is packed in the space which is sandwiched between two cylindrical catalyst supporters 7, 8 having different diameter and gas permeability to form a catalyst layer 6, and the produced gas which is flowed out ultimately from the catqlyst layer 6 is exchanged thermally with a heat exchanger 4 for gaseous starting material at low temp. which is flowed into the first catalyst layer and thereby gas is cooled and passed along the inner surface of a pressure resistant outside shell 1. The cooling liquid is supplied through a supply path 22 penetrating an above cover 2 to the bottom end of a cooling pipe 15 from the outside of reactor and the vapor of cooling liquid or the mixture of vapor and liquid is conducted out through a conduction path 23 penetrating cover 2 to the outside of reactor from the above end of the cooling pipe 15. Thus, the rise of temp. for the pressure resistant vessel can be prevented efficiently.
    • 5. 发明专利
    • CATALYTIC REACTOR
    • JPS60110328A
    • 1985-06-15
    • JP21681983
    • 1983-11-17
    • TOYO ENGINEERING CORP
    • ZANMA ATSUSHINISHIMURA YOSHINORISHIMAGAKI MAKOTOHIROYA KUNIOUOZU HIROHISAHIDAKI MORIHISA
    • B01J8/04
    • PURPOSE:To effect a reaction at favorable efficiency with a relatively simple construction, by a method wherein a heat exchanger is provided at the center of a reaction vessel, and reactant gases are passed alternately through a plurality of catalyst beds provided in an annular space between the heat exchanger and the reaction vessel. CONSTITUTION:Raw material gases are introduced through a raw material gas inlet 12, are fed into the tube side of the heat exchanger 6 from a lower part thereof, and are passed to an upper part. Then, the raw material gases are fed into the first catalyst bed 5 from outside, are passed through the inside in substantially radial directions, and are fed into the first shell side of the heat exchanger 6, where the gases are cooled by the inlet raw material gases, and are fed into the second catalyst bed 5. Similarly, the gas is passed alternately through the catalyst layer 5 and the heat exchanger 6, and the reaction gas is discharged to the exterior of the reaction vessel 1 through a reaction gas outlet 13. Cooling gases are fed to reaction gas outlets of the heat exchanger 6 to finely adjust the gas temperature at the inlet to the catalyst bed 5, thereby maintaining the optimum temperature.
    • 8. 发明专利
    • HEAT EXCHANGER
    • JPS5677692A
    • 1981-06-26
    • JP15243279
    • 1979-11-27
    • TOYO ENGINEERING CORP
    • ZANMA ATSUSHINISHIMURA YOSHINORINAKASHIMA YOUICHISAKAI TADAAKI
    • F22B1/02F28D7/12F28F9/02
    • PURPOSE:To improve a material-selecting property and a planning property, by a method wherein, when a bayonet tube is used with a heat exchanger, the tube is inserted into a space provided at the inside of an outer pipe for being formed open thereat, and the other end is open to a seperation chamber for a high temperature gas provided in a current of a high-temperature gas fluid. CONSTITUTION:A high temperature gas is fed into a drum 11 through an inlet 12, and flows through between pipe bundles of outer pipes 15 for exhausting as it is controlled by barrier plates 16. In the meantime, a low temperature high-pressure gas flows into inner pipes 24 of bayonet tubes through an inlet 21 from a high temperature gas separating chamber 27, and flows down from the end thereof between an outer pipe 15 and the inner pipe 24 of the bayonet tube as it heat-exchanges with a high temperature gas. Then, it flows out from an outlet 20 after passing through a pressure-resisting drum 28 at a pipe side from an opening of a tube plate 13. As described above, the inner and the outer surface of the separation chamber 27 for high temperature gas are covered with the high temperature gas, and the inner and the outer pressure are reduced, whereby a thin sheet can be used, and a feed-in pipe 25 and an expansion joint 26 can be reduced in thickness. As a result, a material- selecting property and a planning property can be improved.
    • 10. 发明专利
    • HEAT EXCHANGER
    • JPS56108097A
    • 1981-08-27
    • JP874380
    • 1980-01-30
    • TOYO ENGINEERING CORP
    • NISHIMURA YOSHINORIKANEKO TAKAYUKIZANMA ATSUSHINAKASHIMA YOUICHI
    • F28D7/06F28D7/16F28F9/02
    • PURPOSE:To reduce the thermal stress of a tube plate by a method wherein the channel fixed at the lower part of a U-tube heat exchanger drum applied to high temperature and high pressure fluid is divided into an upper and a lower chamber, where the former is used for the output side of the 2nd fluid and the latter is for the input side and the inlet and the outlet of the U-conductive tube are opened to the respective chambers. CONSTITUTION:The 1st fluid comes from an inlet 12 to the drum 11 while the 2nd fluid is heated in the heat exchanger and discharged from the outlet 13. On the other hand, the 2nd fluid at a high temperature flows from an inlet 21 of the lower chamber 19 of the channel, a U-tube inlet 22a into a U-conductive tube 22, gives heat to the 1st fluid, enters the upper chamber 18 of the channel through an outlet 22b and is discharged from an outlet 20. Therefore, a tube plate 14 comes in contact with the 2nd fluid cooled by the heat-exchanger with the 1st fluid, comes in no direct contact with high temperature fluid and as a result the temperature distribution on the tube plate 14 can be equalized further than before. Thus, the thermal stress that appears on the tube plate 14 can be made smaller.