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    • 4. 发明专利
    • PRODUCTION OF MOLYBDENUM ALLOY PLATE
    • JPS61204360A
    • 1986-09-10
    • JP4390985
    • 1985-03-06
    • TOSHIBA CORP
    • FUKAZAWA MIHARUMATSUMOTO TATSUHIKOKOIZUMI HIDEOTAKAHASHI TSUTAE
    • C22F1/18C22F1/00
    • PURPOSE:To obtain an Mo alloy plate which decreases the grain boundaries to be the cause for grain boundary cracking by subjecting a sintered body of an Mo alloy contg. K or/and Si at a prescribed ratio to area reduction at a specific reduction ratio or above then to a high-temp. heating treatment. CONSTITUTION:The sintered body of the Mo alloy contg. 0.003-0.05wt.%, more preferably 0.01-0.05wt.% K or/and Si is manufactured. The sintered body is then subjected to the area reduction by forging or rolling, etc. in a temp. region of a room temp. - primary recrystallization temp. in such a man ner that the direction for elongating the sintered body is >=2 directions crossing with the plane of the working plate. The reduction rate in this case is made >=60%, more preferably >=80%. At least one reduction rate of the above- mentioned orthogonal reduction rate is preferably >=20%, more particularly preferably >=40%. Such worked material is subjected to the 1st heating treat ment in a 1,200-1,500 deg.C range then to the 2nd heating treatment in a 1,700-2,000 deg.C range, by which the intended Mo alloy plate is obtd.
    • 5. 发明专利
    • Production of molybdenum jig for high-temperature heat treatment
    • 生产用于高温热处理的莫氏金刚石
    • JPS59150073A
    • 1984-08-28
    • JP1978283
    • 1983-02-10
    • Toshiba Corp
    • FUKAZAWA MIHARUKAWAI MITSUOKOIZUMI HIDEOSAITOU HIROYUKIUEDA SHIGERU
    • B22F3/24C22C1/05C22C27/04C22F1/00C22F1/18
    • PURPOSE: To obtain an Mo jig for a high-temp. heat treatment having excellent high temp. strength by subjecting a doped Mo material contg. prescribed components to reduction working at a specific reduction area or above, then the stress relief annealing at the crystallization temp. or below and forming the material and thereafter heat treating the formed material at the temp. higher than the recrystallization temp.
      CONSTITUTION: A doped Mo sintered material contg. 0.005W0.75% ≥1 kind among Al, Si and K, and 0.3W3wt% ≥1 kind among oxide, carbide, boride and nitride of La, Ce, Dy, etc. is prepd. Such Mo sintered body is hot-worked at a reduction rate of ≥85% and is formed into a jig for a high-temp. heat treatment directly after said hot working or after strees relief annealing at the recrystallization temp. or below. The jig is then heat treated in a temp. range from the temp. higher by 100°C than the recrystallization temp. up to 2,200°C, thereby obtaining the Mo jig for a high temp. heat treatment having improved resistance to thermal fatigue and creep strength.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:获得用于高温的Mo夹具。 高温高温热处理 通过使掺杂的Mo材料 规定的组分在特定还原面积或以上的还原加工,然后在结晶温度下进行应力消除退火。 或以下,形成材料,然后在温度下热处理成形材料。 高于再结晶温度。 构成:掺杂的Mo烧结材料 在Al,Si和K中为0.005-0.75%> = 1,在La,Ce,Dy等的氧化物,碳化物,硼化物和氮化物中为0.3〜3重量%> 1。 将这种Mo烧结体以> = 85%的还原率热加工,并形成高温夹具。 在热加工后直接进行热处理,或在再结晶温度下进行退火退火。 或以下。 然后将夹具在温度下进行热处理。 范围从温度 比再结晶温度高100℃。 达到2200℃,从而获得用于高温的Mo夹具。 具有改善的耐热疲劳和蠕变强度的热处理。
    • 7. 发明专利
    • Tungsten alloy for electrode of ignition plug
    • 用于点火电极的钨合金
    • JPS5925945A
    • 1984-02-10
    • JP13470282
    • 1982-08-03
    • Toshiba Corp
    • KOIZUMI HIDEOFUKUHARA YOSHIO
    • C22C27/04H01T13/20H01T13/39
    • PURPOSE: To improve the oxidation resistance of an electrode of an ignition plug by using tungsten contg. dopants as the material of the electrode.
      CONSTITUTION: An electrode of an ignition plug is made of a W alloy contg. dopants. The dopants are 40W10
      3 ppm K
      2 O and 20W10
      3 ppm SiO
      2 , or 5W10
      3 ppm Al
      2 O
      3 is further contained. To the alloy may be added 10W30wt% Ag or Cu as a I b group element, 3W30wt% Pd, Rb, Rh, Pt or other VIII group element, 3W 30wt% Re, Ta or Re+Ta as high m.p. metals, or 2W5wt% ThO
      2 or ZrO
      2 as an electron emitting substance. Though an electrode of an ignition plug is heated to 2,400°C maximum temp. in arc discharge during working, it undergoes oxidation relatively scarcely and has a long endurance life when made of a W alloy having said composition.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:通过使用钨丝来提高火花塞电极的抗氧化性。 掺杂剂作为电极的材料。 构成:火花塞的电极由W合金制成。 掺杂剂。 掺杂剂是40-10ppm K2O和20-10ppm SiO2,还有5-10ppm Al2O3。 可以向合金中添加10-30重量%的Ag或Cu作为I b族元素,3-30重量%的Pd,Rb,Rh,Pt或其它VIII族元素,3-30重量%的Re,Ta或Re + Ta为高 熔点 金属或2-5wt%的ThO 2或ZrO 2作为电子发射物质。 尽管火花塞的电极被加热到最高温度为2,400摄氏度。 在加工时的电弧放电中,相对较少地进行氧化,并且由具有所述组成的W合金制成时具有长的耐久寿命。
    • 8. 发明专利
    • Element for vapor deposition
    • 蒸汽沉积元素
    • JPS58224168A
    • 1983-12-26
    • JP10619882
    • 1982-06-22
    • Toshiba Corp
    • YAMAZAKI OSAMUKOIZUMI HIDEOSHIMIZU TADASHI
    • C23C14/26C23C14/06
    • C23C14/0647C23C14/0641C23C14/0652
    • PURPOSE:To remarkably prolong the life of an element made of a W alloy for evaporation used as a heater for an evaporation source, by forming a thin nitride film of BN, AlN, Si3N4, TiN or VN on the surface of the element. CONSTITUTION:A thin layer of >=1 kind of nitride selected from BN, AlN, Si3N4, TiN and VN is formed on the surface of an element made of pure W or a W alloy. The thin layer is preferably formed by a vapor phase plating method, and the thickness is adjusted to 2-50mum. The most preferable composition of the element consists of >=99.95% W,
    • 目的:通过在元件的表面上形成BN,AlN,Si3N4,TiN或VN的氮化物薄膜,能够显着延长用作蒸发源的加热器的用于蒸发的W合金元素的寿命。 构成:在由纯W或W合金制成的元件的表面上形成选自BN,AlN,Si 3 N 4,TiN和VN的> = 1种类型的氮化物的薄层。 薄层优选通过气相镀覆法形成,厚度调整为2-50μm。 元素最优选的组成由> = 99.95%W,<= 0.01%Fe,<= 0.02%Mo,<= 0.01%不挥发物质,30-100ppm K,<= 20ppm Al和<= 20ppm Si组成。
    • 9. 发明专利
    • Preparation of tungsten sintered body
    • 钨钢烧结体的制备
    • JPS5770201A
    • 1982-04-30
    • JP14466680
    • 1980-10-16
    • Toshiba Corp
    • FUKUHARA YOSHIOKOIZUMI HIDEOSATOU SEIKI
    • B22F1/00B22F3/10
    • PURPOSE: To enhance sintering density, to prevent crack generation and to make processing property well by a method wherein a tungsten powder with a predetermined particle size and skeleton particles of a predetermined number or less is molded and the obtained molded object is sintered by indirect heating.
      CONSTITUTION: By using tungsten powder contg. ≤40 skeleton particles having 4W8μ particle size in 1mm
      3 , a powder molded object is formed by press molding. Next, the obtained molded object is sintered under vacuum by indirect heating such as high frequency heating or the like. The resultant sintered object has a high sintering density as well as can be degassed and does not generate defficiency such as crack or the like.
      COPYRIGHT: (C)1982,JPO&Japio
    • 目的:为了提高烧结密度,通过以下方法提高烧结密度,防止产生裂纹,并且通过将具有规定数量以下的骨架粒子的规定粒径的钨粉末和规定数量以下的骨架粒子成形而得到的成形体,通过间接加热 。 构成:通过使用钨粉 <= 40个骨架颗粒,其具有1mm的颗粒尺寸为4-8μm,通过压制成型形成粉末成型体。 接下来,通过诸如高频加热等的间接加热在所得到的成型体上进行真空烧结。 所得到的烧结体的烧结密度高,能够脱气,不产生裂纹等的不良效果。
    • 10. 发明专利
    • Rolling method for metallic sheet of high melting point
    • 高熔点金属片的轧制方法
    • JPS5747510A
    • 1982-03-18
    • JP12065780
    • 1980-09-02
    • Toshiba Corp
    • TAKAHASHI DENKOIZUMI HIDEOMORITA TADASHISAITOU HIROYUKI
    • B21B1/02B21B1/22B21B3/00B22F3/02B22F3/17
    • PURPOSE: To prevent the generation of cracks in the surface of a sheet product, by hot-forging a sintered blank comprising such a high melting point metal as W or Mo into to sheet blank, and then, by hot-for ging the edge of this sheet blank in order to deform it into a wedge shape, and by hot rolling this wedge shape blank.
      CONSTITUTION: A powder of such a high melting point metal as W or Mo is press- formed into a compressed powder blank which is then baked in a hydrogen atmosphere; an electric power is then conducted across this baked blank which then generates a resistance heat and is sintered thereby. This sintered blank is again heated in a hydrogen atmosphere and is subjected to a hot forging pass; hereby, the blank is deformed into a wedge shape with a taper angle of about 20 degrees after once passing a sheet shape. This wedge shape blank is heated in a hydrogen atmosphere and is hot rolled into a sheet shape. By the present constitution, any creack does not generate in the surface of the sheet product so that the rolling yield of the sheet product is improved.
      COPYRIGHT: (C)1982,JPO&Japio
    • 目的:为了防止在片材产品表面产生裂缝,通过将包含如W或Mo的高熔点金属的烧结坯料热锻成板坯,然后通过热轧将边缘 该板坯为了使其变形为楔形,并通过热轧该楔形坯料。 构成:将诸如W或Mo的高熔点金属的粉末压制成压缩粉末坯料,然后在氢气氛中烘烤; 然后在该烘烤的坯料上进行电力,然后产生电阻热并由此烧结。 该烧结坯料在氢气气氛中再次加热并进行热锻造, 因此,一旦通过片材形状,坯料变形成具有大约20度的锥角的楔形。 将该楔形坯料在氢气氛中加热并热轧成片状。 通过本构成,在片材制品的表面上不会产生任何起皱,从而提高片材产品的轧制率。