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    • 4. 发明专利
    • AROMATIC POLYCARBOXYLIC ACID DERIVATIVE
    • JPH11140027A
    • 1999-05-25
    • JP30520997
    • 1997-11-07
    • NOF CORP
    • SATO HIROSHIISHIDOYA MASAHIRO
    • C07C69/80C08K5/12
    • PROBLEM TO BE SOLVED: To obtain a new aromatic polycarboxylic acid derivative which has excellent solubility to organic solvent(s) and compatibility to various resins, and is useful as a curing agent which is a heat curing composition which is suitable for coating material, ink, adhesive, molded article, and so on, having excellent chemical and physical properties. SOLUTION: The derivative shown by formula I (R is a 1-8C alkyl: (n) is 1-3) (e.g. bis(methylethoxymethyl) terephthalate) is obtained by the reaction of an aromatic polycarboxylic acid, for example, shown by formula II (e.g. orthophthalic acid, isophthalic acid, terephthalic acid) with a vinyl ether shown, for example, by formula III (e.g. methyl vinyl ether, ethyl vinyl ether), preferably, at room temperature to 150 deg.C in the presence of an acid catalyst, for example, an acidic phosphate ester shown by formula IV (R is a 3-10 alkyl, a cycloalkyl, and so on; (m) is 1 car 2) (e.g. phosphoric acid monoester or diester of n-propanol or n-butanol).