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    • 2. 发明专利
    • Method and device for pulling silicon single crystal
    • 用于拉伸硅单晶的方法和装置
    • JP2003002782A
    • 2003-01-08
    • JP2001181118
    • 2001-06-15
    • Toshiba Ceramics Co LtdToshiba Corp東芝セラミックス株式会社株式会社東芝
    • WATANABE MASAYUKINAKAGAWA YASUTADA
    • C30B29/06
    • PROBLEM TO BE SOLVED: To provide a method for puling a silicon single crystal which is based on a CZ method and by which a high quality silicon single crystal free from distortions or defects in the crystal can be easily and reliably pulled with a high speed even when the crystal has a large diameter, and to provide a pulling device suitably used for the same.
      SOLUTION: When the silicon single crystal is pulled by the Czochralski method in which a cusp field is applied, the silicon single crystal is pulled under conditions that the temperature at the inner wall contacting with silicon melt of the bottom par of a crucible is adjusted to be higher than that at the inner side wall of the crucible and the temperature distribution at the bottom of the crucible is such that the temperature at the bottom of the crucible becomes lower from the center of the crucible toward the radial direction. Further, a bottom heater 7 and a side heater 4 are arranged so as to independently heat the bottom part and the side part of the crucible, respectively, to realize the temperature distribution mentioned above, and a radiation cover 6 for suppressing the radiant heat dissipation from the free surface of a silicon melt L1 and the upper end part of the crucible is arranged above the crucible.
      COPYRIGHT: (C)2003,JPO
    • 要解决的问题:提供一种基于CZ方法制浆的单晶的方法,通过该方法可以容易且可靠地以高速甚至均匀地拉伸晶体中的失真或缺陷的高质量硅单晶 当晶体具有大直径时,并且提供适合用于其的拉制装置。 解决方案:当通过施加尖尖场的切克拉斯基法拉伸硅单晶时,在与坩埚底部的硅熔体接触的内壁处的温度被调节至 高于坩埚的内侧壁,并且坩埚底部的温度分布使得坩埚底部的温度从坩埚的中心朝向径向方向下降。 此外,底部加热器7和侧面加热器4分别设置成独立地加热坩埚的底部和侧部,以实现上述温度分布,以及用于抑制辐射散热的辐射盖6 从硅熔体L1的自由表面和坩埚的上端部分设置在坩埚的上方。
    • 5. 发明专利
    • DEVICE FOR PRODUCING SINGLE CRYSTAL
    • JPS62119189A
    • 1987-05-30
    • JP25943585
    • 1985-11-19
    • TOSHIBA CORP
    • NISHIO JOSHIYASHIRO SATAOTERAJIMA KAZUTAKAWASHITSUKA SHOICHIWATANABE MASAYUKI
    • C30B15/14C30B15/20H01L21/18H01L21/208
    • PURPOSE:To obtain a single crystal having controlled diameter and without any slip even in moderate environment while controlling the heating and cooling with the output of a temp. detector provided at the lower part of a crystal lifting shaft in the titled device by the Czochralski method wherein the shaft is cooled. CONSTITUTION:Ga and As, for example, are charged in a crucible 2, then a B2O3 capsuling material 5 is charged. The crucible is placed in a high-pressure vessel 1, and the inside of the vessel is pressurized with Ar and heated to form a GaAs melt 4. Then the pressure in the vessel 1 is reduced to a pressure at which a crystal is lifted. The thermal environment in the melt 4 and the material 5 is moderately set by the first and the second resistance heater 61 and 62 among the heaters 61 and 62 and the third heater 7. The oil 13 in an oil bath (cooling mechanism) 12 is circulated by a pump 15, the flow rate is regulated by a valve 16, and seeding is carried out. At this time, the regulation is performed so that the temp. distribution measured by a thermocouple (temp. detector) 11, namely the differential thermal pattern in the axial direction of a lifting shaft 10, is specified. Then lifting is started, the valve 16 is regulated, the power supply to the heaters 61, 62, and 7 is controlled while monitoring the output of the thermocouple 11 to form the specified differential thermal pattern.
    • 6. 发明专利
    • APPARATUS FOR PRODUCING SINGLE CRYSTAL
    • JPS61251594A
    • 1986-11-08
    • JP8883485
    • 1985-04-26
    • TOSHIBA CORP
    • WASHITSUKA SHOICHITERAJIMA KAZUTAKAWATANABE MASAYUKI
    • C30B15/22H01L21/18H01L21/208
    • PURPOSE:To provide the titled apparatus capable of giving a single crystal having uniform round cross-section, high purity and high quality, by arranging a cylindrical magnet having magnetic poles along axial direction in a manner to effect the impression of radial magnetic field in the surface of molten material. CONSTITUTION:An electrically conductive substance is heated and melted, and a single crystal is produced from the molten material by Czochralski method under the radial DC magnetic field applied to the molten material. The magnetic field impression apparatus for the above process is composed of a cylindrical magnet 8 having magnetic poles along radial direction and a disk magnet 9 having magnetic poles along axial direction and arranged above and below a crucible 1 in a manner to effect the impression of radial magnetic field 7 in the surface of molten material. The symmetricity of the temperature distribution in the molten material 2 in the surface of the crucible can be maintained uniformly by the impression of the magnetic field 7 to the molten material 2, and accordingly, the generation of nonuniformity and defect of the crystal caused by the thermal convection can be suppressed to give a single crystal 3 having uniform round crosssection and high purity and quality.
    • 9. 发明专利
    • Apparatus for producing compound semiconductor single crystal
    • 用于生产化合物半导体单晶的装置
    • JPS61132597A
    • 1986-06-20
    • JP25113084
    • 1984-11-28
    • Toshiba Corp
    • YASHIRO SATAOWASHITSUKA SHOICHIWATANABE MASAYUKINAGATA MITSUHIROSUGIURA YASUYUKI
    • C30B27/02H01L21/18H01L21/208
    • PURPOSE: To produce a semiconductor single crystal having high quality and low contamination with carbon and other impurities, in high reproducibility, by using specific multi-walled tube made of AlN as a heat-insulation cylinder of an apparatus for the production of a single crystal by LEC process, and growing a compound semiconductor single crystal with the apparatus.
      CONSTITUTION: A heat-insulation cylinder 20 is placed in the pressure vessel 11 (e.g. made of stainless steel) of an apparatus for the production of a compound semiconductor single crystal by LEC process. The cylinder 20 is free of carbonaceous materials and is composed of two cylinders 20a and 20b made of sintered AlN and a granular filler 20c made of sintered alN and having a size of 3W10mm. The GaAs raw material 14 and the B
      2 Oj
      3 encapsulation material 15 are charged in the crucible 12 made of e.g. PBN, the space in the vessel 11 is pressurized with Ar gas, the crucible 12 is heated with the heater 17 to melt the raw material 14 and the encapsulation material 15, the seed crystal 22 is made to contact with the molten raw material 14 via the encapsulation material 15, and is pulled up to effect the growth of the single crystal 23. A semiconductor single crystal 23 having extremely decreased carbon contamination can be produced by this process.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:通过使用由AlN制成的特定多壁管作为制造单晶的设备的隔热圆筒,以高重现性制造具有高质量和低碳污染和低污染的半导体单晶 通过LEC工艺,并用该装置生长化合物半导体单晶。 构成:通过LEC工艺制造化合物半导体单晶的装置,将绝热筒体20放置在压力容器11(例如,不锈钢制造)中。 气缸20不含碳质材料,由烧结AlN制成的两个气缸20a和20b和由烧结AlN制成的尺寸为3-10mm的颗粒填料20c组成。 将GaAs原料14和B 2 O 3 3封装材料15装入由例如硅化物制成的坩埚12中。 PBN中,用Ar气加压容器11中的空间,用加热器17加热坩埚12以熔化原料14和封装材料15,使晶种22与熔融原料14接触,经由 封装材料15,并被拉起以实现单晶23的生长。通过该方法可以制造具有极低碳含量的半导体单晶23。
    • 10. 发明专利
    • Installation for production of single crystal of compound semiconductor
    • 用于生产化合物半导体单晶的安装
    • JPS6163593A
    • 1986-04-01
    • JP18572684
    • 1984-09-05
    • Toshiba Corp
    • WASHITSUKA SHOICHINAKANISHI MASAEWATANABE MASAYUKIYASHIRO SATAO
    • C30B15/14C30B27/02H01L21/02H01L21/208
    • C30B15/14Y10S117/90Y10T117/1064
    • PURPOSE:The heat shield which has a round opening through which the single crystal can pass is made with separated blocks of sintered structure of a specific composition whereby the quality of single crystals is improved and the produc tion yield is increased. CONSTITUTION:The unit for production of single crystal of compound semicon ductor is composed of a high-pressure vessel 11, crucible 12, crucible supports 13, 14 heater 15, the starting melt 16, a liquid capsule layer 17, pressurized inert gas 18, pulling-up shaft 19, crucible shaft 22, heat-shielding bed 23, heat- shielding cylinder and heat-sheilding cover 25. By the way, 20 stands for seed crystal and 21, the single crystal. The heat-sheilding bed 23, the cylinder 24 and the plate 25 is formed by sintering AlN and the cover plate 25 is divided into at least 2 pieces. The AlN sintering products are made by, e.g., mixing AlN fine powder with about 1% of Y2O3 as a binder, granulating and forming them, and sintering under normal pressure, after defatting with heat.
    • 目的:具有单晶可以通过的圆形开口的隔热板由具有特定组成的烧结结构的分离块制成,从而提高了单晶的质量,并提高了生产率。 构成:复合半导体管的单晶的制造单元由高压容器11,坩埚12,坩埚13,14加热器15,起始熔体16,液体胶囊层17,加压惰性气体18, 上拉轴19,坩埚轴22,隔热床23,隔热筒和热封罩25.顺便提及,20代表晶种,21代表单晶。 散热床23,气缸24和板25通过烧结AlN形成,盖板25被分成至少2块。 AlN烧结产物通过例如混合约1%的Y 2 O 3作为粘合剂的AlN细粉末,将其造粒并成型,并在常压下烧结,然后加热脱脂。