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1. 发明专利

JPH01282101A HEATER FOR FUEL REFORMER 失效
公开(公告)号：JPH01282101A
公开(公告)日：1989-11-14
申请号：JP11150388
申请日：1988-05-10
申请人： TOKYO GAS CO LTD , HITACHI LTD , HITACHI TECHNO ENG
发明人： UCHIDA HIROSHI , OOTA HIROKUNI , OOYANAI HIDEO , AMANO YOSHIAKI , HANZAWA AKIO
IPC分类号： F23K5/00 , C01B3/38
摘要： PURPOSE:To obtain stabilized combustion performance even when a load is changed or partially changed by arranging an annular combustion catalyst communicating with an annular fuel-air header over the whole periphery on the inside of the header. CONSTITUTION:The annular header 30a for a hydrogen-contg. gas of the fuel consisting essentially of hydrocarbons and alcohols and steam is formed by header members 30b. The annular combustion catalyst 22 communicating with the header 30a over the whole periphery is arranged between an outer honeycomb 30c with the upper and lower ends supported by the members 30b and an inner honeycomb 30d. The fuel supply pipe 7A and air supply pipe 8A for supplying fuel and air to the catalyst 22 are connected to the header members 30b. The fuel and air are supplied from the outside, introduced into the header 30a through a vapor phase combustion part 40, passed through the honeycomb 30c over the whole periphery, and burned by the catalyst 22. The combustion gas is passed through the honeycomb 30d and then through the central part of a catalytic combustion part 30.

2. 发明专利

JPH0225613A STEAM MODIFYING DEVICE 失效
公开(公告)号：JPH0225613A
公开(公告)日：1990-01-29
申请号：JP17494588
申请日：1988-07-15
申请人： TOKYO GAS CO LTD , HITACHI LTD
发明人： OOTA HIROKUNI , UCHIDA HIROSHI , OBATA ISAO , AMANO YOSHIAKI , HANZAWA AKIO , KOYAMA KAZUHITO
IPC分类号： F23D14/18 , C01B3/38 , F23K5/00
摘要： PURPOSE:To provide a stable combustion characteristic and enable a uniform heating to be carried out by a method wherein a nozzle of a combustion unit is divided into a nozzle for air, a nozzle for hydrocarbon and a nozzle for cell discharged gas and then the nozzle for hydrocarbon is filled with a modifying catalyst. CONSTITUTION:During operation, fuel and air preheated at 400 deg.C to 500 deg.C. Cell discharged gas passes through a cell discharged gas flow passage, and air passes through an air flow passage 6, respectively and then injected out of nozzles. Methane active as auxiliary fuel is mixed with steam and passes through a hydrocarbon flow passage 4, and is brought into contact with a modifying catalyst 7 so as to start a reaction. The gas is improved to generate hydrogen having a better combustion characteristic, so that its combustion characteristic is remarkably improved. Then, in case of starting operation, the fuel is not preheated and no steam is generated, so that a combustion is carried out only with methane. Since the nozzle 1 for hydrocarbon and the nozzle 3 for air are arranged with the nozzle 2 for discharged gas being held therebetween, so that the fuel is preheated, and the combustion is gradually carried out at the same time as that of operation.

3. 发明专利

JPH0225616A BURNER 失效
公开(公告)号：JPH0225616A
公开(公告)日：1990-01-29
申请号：JP17494488
申请日：1988-07-15
申请人： TOKYO GAS CO LTD , HITACHI LTD
发明人： OOTA HIROKUNI , UCHIDA HIROSHI , KOYAMA KAZUHITO , SUGITA NARIHISA , UCHIYAMA YOSHIHIRO , HANZAWA AKIO
IPC分类号： F23D17/00
摘要： PURPOSE:To enable combustion gas providing a stable combustion and even in case of different type of fuel and having less difference in temperature distribution to be generated by a method wherein natural gas flows in a central port, anode discharged gas flows in a port around it and air flows in the outer- most circumference for a structure having triple ports. CONSTITUTION:Air 22 flows into an air manihold 12 and is injected from an air inlet 15 into furnace and at the same time natural gas 23 flows into a natural gas manihold 14, the gas is injected from a natural gas port 17 into the furnace so as to perform a combustion therein. Heated item is heated and its temperature is increased. Quality of water vapor is improved and generated hydrogen is supplied to an anode of a cell anode discharged gas 24 including unreacted hydrogen is discharged from the anode and a flow rate of natural gas 23 is throttled in place of supply of the anode discharge gas to the burner 1, and then a combustion at the burner 1 is transferred from a combustion of natural gas 23 to a combustion of the anode discharged gas 24. The anode discharged gas 24 is injected from an anode discharged gas port 16 into the furnace. Simultaneously, a flow rate if air 22 is also controlled and an adjustment is carried out so as to prevent a flame length from being too elongated.

4. 发明专利

JPH092801A HYDROGEN MANUFACTURING APPARATUS 失效
公开(公告)号：JPH092801A
公开(公告)日：1997-01-07
申请号：JP15331995
申请日：1995-06-20
申请人： TOKYO GAS CO LTD , MITSUBISHI HEAVY IND LTD
发明人： OOTA HIROKUNI , SHIRASAKI YOSHINORI , INOUE KYOICHI , KURODA KENNOSUKE , KOBAYASHI KAZUTO , OTA SHINSUKE
IPC分类号： C01B3/38 , C01B3/50 , H01M8/06
摘要： PURPOSE: To provide a hydrogen manufacturing apparatus of so called membrane reactor-type having high practicability and capable of performing the reactions that are conventionally carried out in a reformer, a carbon monoxide transformer and a hydrogen purifier, at once in a group and producing hydrogen of high purity. CONSTITUTION: This hydrogen manufacturing apparatus is composed of a vertical burner 1, a cylindrical radiation board 2 surrounding the burner and forming a burning section in it, an outer cylinder 3 surrounding the outer periphery of the radiation board, having a closed ring-shaped ceiling board 10 and forming a reaction section 11 between the radiation board and itself, a canopy 6 closely covering above the outer cylinder 3, a raw material supplying tube 4 surrounding the radiation board 2 inside the reaction section 11, a vertical hydrogen permeating tube 5 placed in the reaction section, plural sweep gas tubes 7 vertically placed inside the hydrogen permeation tube 5 and plural smoke ducts 8 penetrating the hydrogen permeating tube 5 and vertically placed inside the reaction section 11. A reforming catalyst 9 is inserted into the surroundings of the hydrogen permeating tube in the reaction section 11.

5. 发明专利

JPH07109106A HYDROGEN-PRODUCTION APPARATUS 失效
公开(公告)号：JPH07109106A
公开(公告)日：1995-04-25
申请号：JP25270593
申请日：1993-10-08
申请人： TOKYO GAS CO LTD , MITSUBISHI HEAVY IND LTD
发明人： GONDAIRA MASAYUKI , OOTA HIROKUNI , UCHIDA HIROSHI , KURODA KENNOSUKE , MAKIHARA HIROSHI , KOBAYASHI KAZUTO
IPC分类号： B01D53/22 , B01J8/02 , B01J8/06 , C01B3/32 , C01B3/38 , C01B3/50 , C01B3/56 , H01M8/06
摘要： PURPOSE:To produce hydrogen on an industrial scale from a mixed gas of hydrocarbon or methanol and steam by a steam-reforming reaction. CONSTITUTION:This hydrogen production apparatus produces hydrogen by a steam-reforming reaction and separates and collects the hydrogen by permeating through a partition wall having selective hydrogen permeability. A raw material gas is introduced from the top of an inner layer annular space 30 into the reactor, lowered through a reforming catalyst layer and converted into hydrogen at a high temperature. The produced hydrogen is permeated through a hydrogen permeation pipe 32 to selectively separate and collect the hydrogen. The permeated hydrogen is accompanied with a sweep gas introduced from the bottom of an annular part formed between the hydrogen permeation pipe 32 and a sweep gas pipe 34, passed through the sweep gas pipe 34 and discharged from the lower part of the pipe together with the sweep gas.

6. 发明专利

JPH06345406A HYDROGEN PRODUCTION DEVICE 失效
公开(公告)号：JPH06345406A
公开(公告)日：1994-12-20
申请号：JP16635093
申请日：1993-06-11
申请人： TOKYO GAS CO LTD , MITSUBISHI HEAVY IND LTD
发明人： SHIRASAKI YOSHINORI , OOTA HIROKUNI , UCHIDA HIROSHI , KURODA KENNOSUKE , UCHIDA TOSHIYUKI , KOBAYASHI KAZUTO
IPC分类号： B01J8/02 , B01J8/06 , C01B3/32 , C01B3/38 , C01B3/50
摘要： PURPOSE:To provide a hydrogen production device capable of producing high-purity hydrogen by carrying out each reaction in a modifier, a carbon monoxide transformer and a hydrogen purifier collectively. CONSTITUTION:A device for producing hydrogen by steam modifying reaction from a hydrocarbon and/or an alcohol, the production device is equipped with an upright cylindrical burner 1, a cylindrical radiating plate 2 which covers the burner and has the open top, plural upright closed reaction tubes 3 which are arranged annularly at the outer periphery of the radiating plate at a specific interval from the radiating plate and have the lower end led to the an off-gas outlet 3a and a closed case 4 which covers the burner and the reaction tubes and has an exhaust vent 1a of an exhaust gas of combustion at the bottom. The reaction tubes have an upright feed pipe 10 of a raw material which has the top opening to the inside of the reaction tubes and the lower end led to a feed opening 10a of a raw material, an upright hydrogen taking out pipe 11 which covers the outer peripheral side of the feed pipe of the raw material, has the open top and the lower end led to a hydrogen outlet 11a and an upright closed hydrogen permeating pipe 12 which covers the outer periphery of the hydrogen taking out pipe, has the closed top and the lower end led to the a feed opening 12a of a sweeping gas. A reforming catalyst 5 is packed between the hydrogen permeating pipe and the reaction tubes.

7. 发明专利

JPH06345405A HYDROGEN PRODUCTION DEVICE 失效
公开(公告)号：JPH06345405A
公开(公告)日：1994-12-20
申请号：JP16634993
申请日：1993-06-11
申请人： TOKYO GAS CO LTD , MITSUBISHI HEAVY IND LTD
发明人： SHIRASAKI YOSHINORI , OOTA HIROKUNI , UCHIDA HIROSHI , KURODA KENNOSUKE , MAKIHARA HIROSHI , KOBAYASHI KAZUTO
IPC分类号： B01J8/02 , B01J8/06 , C01B3/32 , C01B3/38 , C01B3/50 , H01M8/06
摘要： PURPOSE:To provide a hydrogen production device capable of producing high- purity hydrogen by carrying out each reaction in a modifier, a carbon monoxide transformer and a hydrogen purifier collectively. CONSTITUTION:A hydrogen production device is equipped with an upright cylindrical burner 1, a radiating plate 2 covering the burner, a hollow double wall closed reactor 3 arranged annularly at the outer periphery of the radiating plate, plural upright hydrogen permeating pipes 4 which are annularly arranged between the double wall of the reactor, have an outlet of a sweeping gas at the top and are closed at the bottom, a closed inner tank 5 which covers the outer wall and the bottom of the reactor at a fixed interval and has an inlet of a raw material gas and steam, a closed outer tank 6 which covers the inner tank, takes in an exhaust gas of combustion in the burner from the top of the radiating plate, brings the exhaust gas into contact with the inner wall and the bottom of the reactor, raises the exhaust gas along the outside of the inner tank and discharges and a sweeping gas pipe 9 which is coaxially inserted into the hydrogen permeating pipe and is equipped with an exhaust vent 9a of hydrogen and the sweeping gas. A modifying catalyst 7 is packed into the hollow part of the reactor.

8. 发明专利

JPH06321503A APPARATUS FOR HYDROGEN PRODUCTION 失效
公开(公告)号：JPH06321503A
公开(公告)日：1994-11-22
申请号：JP11575893
申请日：1993-05-18
申请人： TOKYO GAS CO LTD , MITSUBISHI HEAVY IND LTD
发明人： GONDAIRA MASAYUKI , OOTA HIROKUNI , UCHIDA HIROSHI , SAOTOME TAKASHI , OTA SHINSUKE , KURODA KENNOSUKE
IPC分类号： B01J8/02 , B01D53/22 , B01J8/06 , C01B3/32 , C01B3/38 , C01B3/56 , H01M8/06
摘要： PURPOSE:To provide an industrial scale hydrogen-producing apparatus having a new constitution developed from a laboratory scale hydrogen-producing apparatus, wherein a product of steam reforming reaction is made to pass through a partition wall having selective hydrogen-permeability to separate the hydrogen formed in the reaction. CONSTITUTION:The hydrogen-producing apparatus 10 is composed of an outer cylinder 14 having a closed bottom 12, an medium cylinder placed inside of the outer cylinder 16 and an inner cylinder 18 placed further inside of the medium cylinder. All of the cylinders; the outer 14, the medium 16 and the inner 18; are in rectangular cylinder forms. The second circular space 26 between the medium cylinder and the inner cylinder is filled with a reforming catalyst A and this forms catalyst layer 26. Hydrogen-permeable rectangular parallelepipeds 34 having selective hydrogen-permeable metal membrane are placed in the catalyst layer 26 in a concentric manner with the second circular space 26. Many sweep-gas tubes are inserted in the third space 33 formed by the inner surfaces and the outer surfaces of the hydrogen-permeable rectangular parallelepipeds 34.

9. 发明专利

JP2001031403A DEVICE FOR PRODUCING HYDROGEN 失效
公开(公告)号：JP2001031403A
公开(公告)日：2001-02-06
申请号：JP20699399
申请日：1999-07-22
申请人： MITSUBISHI HEAVY IND LTD , TOKYO GAS CO LTD
发明人： FUJIMOTO YOSHIMASA , KOBAYASHI KAZUTO , OOTA HIROKUNI , SHIRASAKI YOSHINORI
IPC分类号： C01B3/40
摘要： PROBLEM TO BE SOLVED: To provide a hydrogen-producing device whose hydrogen partition walls have improved durability and which can produce highly pure hydrogen, by using a molded plate-like reforming catalyst. SOLUTION: The molded plate-like reforming catalyst 126 is preferably formed by carrying a Ni-based catalyst or the like on a metal such as stainless steel. A hydrogen-penetrating rectangular member 34 is provided with an inside wall 28 near to the plate-like reforming catalyst 126 and with an outside wall 32 near to the adjacent unit. The inside wall 28 and the outside wall 32 are formed from hydrogen- penetrating metal membranes, respectively. The unit is provided with a spacer 127 which is fixed to the plate-like reforming catalyst 126 and a hydrogen-penetrating rectangular member 34 by a welding method or the like, and is extended in the longitudinal direction of the hydrogen-penetrating rectangular member 34. Thereby, the spacer 127 is disposed between the hydrogen-penetrating rectangular member 34 and the plate-like reforming catalyst 126 of each unit, and when the unit is assembled in the second space, the spacer 127 of the outside wall 32 is also disposed between the outside wall 32 and the adjacent plate-like reforming catalyst 126. Thus, the damage of the metal membrane due to the contact with the plate-like reforming catalyst 126 is not caused.

10. 发明专利

JPH08338260A POWER GENERATING METHOD 失效
公开(公告)号：JPH08338260A
公开(公告)日：1996-12-24
申请号：JP14198395
申请日：1995-06-08
申请人： TOKYO GAS CO LTD , MITSUBISHI HEAVY IND LTD
发明人： OOTA HIROKUNI , SHIRASAKI YOSHINORI , INOUE KYOICHI , KURODA KENNOSUKE , IIJIMA MASAKI , TAKEUCHI YOSHIYUKI , MAKIHARA HIROSHI , FUJIMOTO YOSHIMASA , OSADA ISAMU
IPC分类号： F02C3/28 , C01B3/38 , F02C6/00 , H01M8/06 , H02P9/04
摘要： PURPOSE: To improve the power generating efficiency by working steam and oxygen to coal to manufacture combustible gas and using it for gas turbine generation, or reforming hydrocarbon by a reforming device by use of combustible gas and high temperature combustion gas to manufacture high purity hydrogen, and supplying it to a fuel cell to generate electricity. CONSTITUTION: Coal, steam and oxygen are supplied to a gas making furnace 1 to gasify the coal, the resulting combustible gas is passed to and treated by a reforming device 3 and a desulfurizing device 5 through a line 2, and then supplied to a combustor 7 constituting a gas turbine generating device by a line 6. The combustible gas is burnt under supply of compressed air, and the generated high temperature and high pressure combustion gas is introduced to a gas turbine 9, which is then rotated to drive a generator 23. The combustion waste gas leaving the gas turbine 9 is sent to a waste heat recovering boiler 11, a natural gas 16 is reformed by a reforming device 12 in the boiler 11, high purity hydrogen is generated by the action of a hydrogen separating penetrating film, and the resulting hydrogen is supplied to a fuel cell 19 to generate electricity.

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