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    • 4. 发明专利
    • ROLL
    • JPH03284780A
    • 1991-12-16
    • JP8511390
    • 1990-03-31
    • TOKAI RUBBER IND LTD
    • ISHIHARA KOMIYAHARA NAOTOSHI
    • G03G15/20C08L27/12C08L83/04C08L83/08F16C13/00
    • PURPOSE:To easily peel off fused toner stuck to a roll from the roll by forming an elastic member layer on the outer periphery of a core body along its circumference so as to be adhered to the outer periphery and forming the surface layer of the elastic member layer by fluoro-rubber having a prescribed composition. CONSTITUTION:The elastic member layer 2 is formed so as to be adhered to the outer periphery of the core body 1 along its circumference. At least the surface layer of the layer 2 is constituted of fluoro-rubber having coupling structure shown by structural formula I derived from a modified silicone oil in its molecular structure. In formula I, R1 to R4 are univalent organic groups and (y) is a positive integer. Since the coupling structure of -Si-O-Si- derived from modified silicone oil is introduced into the molecular structure of the fluoro-rubber constituting the elastic member layer 2 of the surface layer, the wettability of the elastic member layer itself with silicone oil can be sharply improved, so that fused toner stuck to the outer periphery of the roll can easily be peeled from the roll.
    • 7. 发明专利
    • ROLL
    • JPH01152485A
    • 1989-06-14
    • JP31168587
    • 1987-12-09
    • TOKAI RUBBER IND LTD
    • HASHIMOTO KAZUNOBUMIYAHARA NAOTOSHIEGUCHI HIROYUKITAGAMI HIROSHI
    • G03G15/20F16C13/00
    • PURPOSE:To obtain a roll which has a high release property to a toner and does not require maintenance by using a heat resistant rubber elastic layer which forms a surface layer on the outside circumference of an arbor to be constituted as a revolving shaft, inorg. filler particles which are dispersed into said rubber elastic layer and have a specific thermal conductivity and a coupling agent, etc. CONSTITUTION:This roll has the arbor to be constituted as the revolving shaft, the heat resistant rubber elastic layer which is fixed on the outside circumference thereof so as to form at least the surface layer thereon and the inorg. filler particles which are dispersed in this rubber elastic layer. The inorg. filler particles have >=5.00X10 cal/sec.cm.deg thermal conductivity and is surface- treated by at least one of the silane coupling agent, titanate coupling agent and aluminate coupling agent. Generation of surface staining films on the roll surface is thereby obviated even after long-term use and the sharp copied images are obtd. for a long period of time with substantial freedom from maintenance.
    • 8. 发明专利
    • RUBBER COMPOSITION
    • JPS63308045A
    • 1988-12-15
    • JP14369087
    • 1987-06-09
    • TOKAI RUBBER IND LTD
    • HASHIMOTO KAZUNOBUMIYAHARA NAOTOSHI
    • C08K5/47C08K5/45C08L15/00
    • PURPOSE:To obtain a rubber composition rapidly curable without foaming, by incorporating a rubber component consisting mainly of a partially hydrogenated acrylonitrile-butadiene rubber with a sulfur compound as the curing agent and dibenzothiazyl disulfide as the curing accelerator. CONSTITUTION:The objective rubber composition useful for various hoses and vibration-proof rubbers, can be obtained by incorporating (A) 100pts.wt. of a rubber component consisting mainly of a partially hydrogenated acrylonitrile- butadiene rubber pref. with hydrogenation rate of 50-98% and acrylonitrile content of 10-70wt.% with (B) 0-4pts.wt. of sulfur or sulfur supplier as the curing agent (e.g., N,N'-dithiobismorphorin) and (C) a dibenzothiazyl disulfide of formula (X is monovalent group selected from NO2, halogens, CHO, etc.) as the curing accelerator. The amount of the component C is 0.2-10pts.wt. when that of the component B is 0.5-10pts.wt. (pref. 0.1-7pts.wt., when that of the component B is 0.5-3pts.wt.).