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    • 2. 发明专利
    • Electrolyte film and manufacturing method of the same
    • 电解胶膜及其制造方法
    • JP2005285451A
    • 2005-10-13
    • JP2004095594
    • 2004-03-29
    • Sumitomo Electric Ind Ltd住友電気工業株式会社
    • MURANAKA KOJI
    • C23C14/06H01B1/06H01M8/02H01M8/12
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide an electrolyte film capable of conducting power generation with high efficiency, and a manufacturing method of the same. SOLUTION: The electrolyte film 1 used for a fuel cell comprises a base 2 and a convex-structured part 3. The convex-structured part 3 formed on the base 2 has columnar crystals 4 as columnar bodies slanted against the surface 5 of the base 2. In this way, as the convex-structured part 3 is formed of the columnar crystals 4, the surface area of the electrolyte film 1 at a convex-structured part side can be enlarged in comparison with an electrolyte film without the columnar crystals 4. By this, for example, by forming a fuel electrode on the convex-structured part 3, and forming an air electrode on a face located at the opposite side of the electrolyte film 1 on which the convex-structured part 3 is formed, the area (active area) of the air electrode forming area can be enlarged, and a fuel cell having high power generation efficiency can be obtained. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供能够高效率地进行发电的电解质膜及其制造方法。 解决方案:用于燃料电池的电解质膜1包括基底2和凸起的构造部分3.形成在基底2上的凸形结构部分3具有柱状晶体4,作为柱形体,其倾斜于表面5的 以这种方式,由于凸形结构部分3由柱状晶体4形成,与没有柱状的电解质膜相比,凸形结构部分侧的电解质膜1的表面积可以增大 晶体4.例如,通过在凸形结构部3上形成燃料电极,在形成有凸状结构部3的电解质膜1的相对侧的面上形成空气电极 ,可以扩大空气电极形成区域的面积(有效面积),并且可以获得具有高发电效率的燃料电池。 版权所有(C)2006,JPO&NCIPI
    • 4. 发明专利
    • Hydrogen permeable structure, and fuel cell using it
    • 氢气渗透性结构和燃料电池使用它
    • JP2008171775A
    • 2008-07-24
    • JP2007006163
    • 2007-01-15
    • Sumitomo Electric Ind LtdToyota Motor Corpトヨタ自動車株式会社住友電気工業株式会社
    • MIZUNO OSAMUKAMIMURA TAKUMURANAKA KOJIITO NAOKI
    • H01M8/02B01D69/12B01D71/02C01B3/56H01M4/94
    • Y02E60/50
    • PROBLEM TO BE SOLVED: To provide a hydrogen permeable structure containing an oxide proton conductive membrane and used for fuel cells capable of attaining high cell output when used for a fuel cell without being deteriorated by carbon dioxide, and to provide a fuel cell using this hydrogen permeable structure. SOLUTION: The invention provides a hydrogen permeable structure and a fuel cell using the same. The hydrogen permeable structure comprises a metal substrate having a hydrogen permeating function and a multi-layered oxide proton conductive membrane formed on the substrate.The oxide proton conductive membrane is made of a proton conductive oxide expressed by chemical formula A: (Zr 1 -xMx)O 3 (where, A is an alkali earth metal; M is Nd, Y, In, Yb, Sc, Gd, Sm or Pr; and 0.1≤x COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供含有氧化物质子传导膜的氢可渗透结构,并且用于能够在用于燃料电池的情况下获得高电池输出而不被二氧化碳劣化的燃料电池,并且提供燃料电池 使用这种氢可渗透结构。 解决方案:本发明提供氢可渗透结构和使用其的燃料电池。 氢可渗透结构包括具有氢渗透功能的金属基底和形成在基底上的多层氧化物质子传导膜。氧化物质子传导膜由化学式A表示的质子传导氧化物制成:(Zr 3其中,A为碱土金属; M为Nd,Y,In,Yb,Sc,Gd,Sm或Pr;0.1≤x< 0.8),并且包括厚度为0.01至2μm的顶层和基本上不含Zr的另一层。 版权所有(C)2008,JPO&INPIT
    • 5. 发明专利
    • Method of manufacturing hydrogen permeable structure, hydrogen permeable structure, and fuel cell
    • 氢化渗透性结构,氢化渗透性结构和燃料电池的制造方法
    • JP2007103273A
    • 2007-04-19
    • JP2005294411
    • 2005-10-07
    • Sumitomo Electric Ind LtdToyota Motor Corpトヨタ自動車株式会社住友電気工業株式会社
    • MIZUNO OSAMUKAMIMURA TAKUMURANAKA KOJIITO NAOKI
    • H01M8/02
    • Y02E60/50
    • PROBLEM TO BE SOLVED: To provide a method of manufacturing a hydrogen permeable structure having an oxide proton conductive film composed of oxide on a metal base material having a hydrogen permeable performance, the method enabling to form the oxide proton conductive film composed of the oxide of high crystallinity without oxidizing the metal base material, and to provide the hydrogen permeable structure manufactured by this method, and a fuel cell using the hydrogen permeable structure.
      SOLUTION: This is the method of manufacturing the hydrogen permeable structure having a process of forming an oxide film by vapor-depositing the oxide containing an alkaline earth group metal as well as a metal selected from Zr and Ce on the metal base material having the hydrogen permeable performance in an oxidizing atmosphere of 400°C or less, and a process of heating this oxide film at 450°C or more in a non-oxidizing atmosphere. This is the hydrogen permeable structure manufactured by the method, and the fuel cell using the hydrogen permeable structure.
      COPYRIGHT: (C)2007,JPO&INPIT
    • 解决问题的方法:提供一种制造具有氧化物质子传导膜的氢可渗透结构的方法,该氧化物质子传导膜由具有氢可渗透性能的金属基材上由氧化物构成,该方法能够形成由 不会氧化金属基材的高结晶度的氧化物,提供通过该方法制造的氢可渗透结构,以及使用氢可渗透结构的燃料电池。 解决方案:这是制造氢可渗透结构的方法,其具有通过在金属基材上气相沉积含有碱土金属的氧化物以及选自Zr和Ce的金属来形成氧化膜的方法 在400℃以下的氧化气氛中具有氢可渗透性,以及在非氧化性气氛中将该氧化膜加热至450℃以上的工序。 这是通过该方法制造的氢可渗透结构,以及使用氢可渗透结构的燃料电池。 版权所有(C)2007,JPO&INPIT