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    • 1. 发明专利
    • Thiol compound, production method therefor and polymerizable composition
    • THIOL化合物,其生产方法和可聚合组合物
    • JP2012122011A
    • 2012-06-28
    • JP2010274558
    • 2010-12-09
    • Showa Denko Kk昭和電工株式会社
    • SATO AKIKOYAMAGAMI ISAOMUROFUSHI KATSUMI
    • C08G75/02C07C323/12
    • PROBLEM TO BE SOLVED: To provide a photopolymerization initiator composition having high sensitivity, free from oxygen inhibition and excellent in water-resistance, alkali-resistance and heat-resistance, and to provide a new thiol compound containing the photopolymerization initiator composition and suitable for a photosensitive composition.SOLUTION: There are provided a polymerizable composition comprising a new aromatic ether-based polyfunctional primary thiol compound represented by general formula (1), a polymerizable composition comprising the aromatic ether-based polyfunctional primary thiol compound and a compound having an ethylenic unsaturated double bond, and cured products obtained by the photopolymerization of the composition. (In the formula, Rrepresents a single bond or a 1C-10C linear or branched alkylene; Rrepresents H or 1C-3C alkyl; Rrepresents H or 1C-3C alkyl; Rrepresents 1C-4C alkyl or alkoxy; (a) is 0 or 1; b is 3 or 4; c is an integer of 0-4; and a+b is 4).
    • 解决问题:提供一种无氧抑制性高,耐水性,耐碱性和耐热性优异的高灵敏度的光聚合引发剂组合物,提供含有光聚合引发剂组合物的新型硫醇化合物, 适用于感光组合物。 解决方案:提供一种可聚合组合物,其包含由通式(1)表示的新的芳族醚类多官能伯硫醇化合物,包含芳族醚系多官能伯主要硫醇化合物和具有烯属不饱和化合物的化合物 双键和通过组合物的光聚合获得的固化产物。 (式中,R 1 表示单键或1C-10C直链或支链亚烷基; R 2表示H或 1C-3C烷基; R 3表示H或C 1 -C 3烷基; R 4表示1 -C 4烷基或烷氧基;( a)为0或1; b为3或4; c为0-4的整数,a + b为4)。 版权所有(C)2012,JPO&INPIT
    • 2. 发明专利
    • Curable composition containing urethane compound, and cured product thereof
    • 含有URETHANE化合物的可固化组合物及其固化产物
    • JP2009209256A
    • 2009-09-17
    • JP2008053325
    • 2008-03-04
    • Showa Denko Kk昭和電工株式会社
    • OI HIROKOISHII NOBUAKIURAKAWA KEISHIMUROFUSHI KATSUMI
    • C08F20/36C08F2/44C09D4/02C09D5/00C09D175/16C09J4/02C09J175/16
    • PROBLEM TO BE SOLVED: To provide a curable composition capable of forming a cured film having both strength and flexibility which is excellent in surface hardness and abrasion resistance and has good flexibility and bendability, and to provide a cured product (film) thereof.
      SOLUTION: The curable composition comprises (A) a urethane compound represented by general formula (1) and (B) a polymerization initiator, wherein R
      1 represents a divalent aliphatic group having a linear, branched, or cyclic structure having 1-12 carbons, a divalent organic group having an aromatic ring, or [-(CH
      2 )
      a -O-(CH
      2 )
      b -]
      c (wherein a and b independently represent an integer of 1-10, and c represents an integer of 1-5); R
      2 represents -(CH
      2 )
      2 -O-[(CH
      2 )
      d -O-(CH
      2 )
      e -]
      f (wherein d and e independently represent an integer of 1-10, and f represents an integer of 1-5); and R
      3 represents a hydrogen atom or a methyl group.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 解决问题的方案:提供能够形成表面硬度和耐磨性优异的强度和柔韧性的固化膜的固化性组合物,并且具有良好的柔软性和弯曲性,并且提供其固化产物(膜) 。 < P>解决方案:可固化组合物包含(A)由通式(1)表示的氨基甲酸酯化合物和(B)聚合引发剂,其中R 1表示具有直链,支链 或具有1-12个碳的环状结构,具有芳环的二价有机基团,或[ - (CH 2)2 -S-(CH 2 SBR) (其中a和b独立地表示1-10的整数,c表示1-5的整数);其中a和b分别表示1-10的整数,c表示1〜5的整数。 R 2 表示 - (CH 2 )2 -O - [(CH 2 SB 2) (其中d和e独立地表示1-10的整数,和/或者 f表示1-5的整数); R 3表示氢原子或甲基。 版权所有(C)2009,JPO&INPIT
    • 4. 发明专利
    • Photosensitive composition for black matrix
    • 黑色矩阵的光敏组合物
    • JP2005331938A
    • 2005-12-02
    • JP2005124375
    • 2005-04-22
    • Showa Denko Kk昭和電工株式会社
    • ISHIGAKI SATOSHIOONISHI MINAMUROFUSHI KATSUMIMORINAKA KATSUTOSHI
    • G03F7/027C08F290/06C08F299/06G02B5/20G03F7/004
    • PROBLEM TO BE SOLVED: To provide a photosensitive composition for a black matrix of a color filter resin capable of easily forming a pattern having a thin film property and a high light-shielding property by a photolithography method, and having sufficient sensitivity, resolution, developability, durability, and curing rate. SOLUTION: The photosensitive composition comprises a binder resin (A) and a black-base pigment (B), wherein the binder resin (A) contains a urethane acrylate compound which is a reaction product of an isocyanate compound (a-1) shown by formula (1) (where R represents a 1-30C hydrocarbon group) with a polyhydroxy compound (a-2). The photosensitive composition preferably comprises the binder resin (A), the black-base pigment (B), an ethylenically unsaturated monomer (C), a photopolymerization initiator (D) and an organic solvent (E). The photosensitive composition is capable of easily forming a pattern having a thin film property and a high light-shielding property by a photolithography method, and has sufficient sensitivity, resolution, developability, durability, and curing rate. COPYRIGHT: (C)2006,JPO&NCIPI
    • 解决问题:为了提供能够通过光刻法容易地形成具有薄膜性能和高遮光性的图案的滤色器树脂的黑矩阵的感光组合物,并且具有足够的灵敏度, 分辨率,可开发性,耐久性和固化速率。 光敏组合物包含粘合剂树脂(A)和黑色基础颜料(B),其中粘合剂树脂(A)含有作为异氰酸酯化合物(a-1)的反应产物的氨基甲酸酯丙烯酸酯化合物 )(其中R表示1-30C烃基)与多羟基化合物(a-2)表示。 感光性组合物优选包含粘合剂树脂(A),黑色颜料(B),烯属不饱和单体(C),光聚合引发剂(D)和有机溶剂(E)。 光敏组合物能够通过光刻法容易地形成具有薄膜特性和高遮光性的图案,并且具有足够的灵敏度,分辨率,显影性,耐久性和固化速度。 版权所有(C)2006,JPO&NCIPI
    • 5. 发明专利
    • Curable polymer compound
    • 可固化聚合物化合物
    • JP2005163033A
    • 2005-06-23
    • JP2004328725
    • 2004-11-12
    • Showa Denko Kk昭和電工株式会社
    • OONISHI MINAKAMIJO MASANAOMUROFUSHI KATSUMI
    • G03F7/004C08F2/38C08F2/50C08F8/00C08F290/12G02B5/20G03F7/038
    • PROBLEM TO BE SOLVED: To obtain a novel curable polymer compound, a radical polymerizable/curable composition prepared from the curable polymer compound and a cured product prepared by photo-setting of the curable polymer composition, and a process for production of the curable polymer compound. SOLUTION: The novel curable polymer compound has a structure shown by formula (1) wherein R 1 represents hydrogen atom or methyl group, R 2 represents at least one or more organic residues independently selected from the group consisting of an alkylene, a branched alkylene, an alkenylene group, a cycloalkylene group, a cycloalkenylene group and an arylene group, and (n) represents an integer of 0 or 1. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题为了获得新的可固化聚合物化合物,由可固化聚合物化合物制备的自由基可聚合/固化组合物和通过光固化可固化聚合物组合物制备的固化产物,以及制备 固化性高分子化合物。 解决方案:新型可固化聚合物化合物具有式(1)所示的结构,其中R SP 1表示氢原子或甲基,R SP 2表示至少一个或 更多的有机残基独立地选自亚烷基,支链亚烷基,亚烯基,亚环烷基,亚环烯基和亚芳基,(n)表示0或1的整数。 (C)2005,JPO&NCIPI
    • 8. 发明专利
    • Metal oxide dispersion solution for dye-sensitized solar cell, photoactive electrode, and dye-sensitized solar cell
    • 用于透明的太阳能电池,光电极和透明的太阳能电池的金属氧化物分散溶液
    • JP2005203378A
    • 2005-07-28
    • JP2005048238
    • 2005-02-24
    • Showa Denko Kk昭和電工株式会社
    • MUROFUSHI KATSUMIKONDO KUNIOSATO RYUSUKE
    • H01L31/04H01M14/00
    • Y02E10/542
    • PROBLEM TO BE SOLVED: To provide a dye-sensitized solar cell in which, as a sheet-like electrode substrate, a resin material having high transparency, of low cost and light-weighted, and having freedom in shape can be used, and to provide a metal oxide dispersion solution used for the manufacture of the cell electrode. SOLUTION: A photoactive electrode for a dye-sensitized solar cell can be manufactured by applying heat treatment under room temperature to 200°C after applying on a sheet-like electrode a metal oxide dispersion solution for solar cell that contains a metal oxide particulate, a binder containing no hydroxide group, nor amino group, and a solvent. Thereby, a material such as resin, which can not maintain its performance in a heat treatment under high temperature carried out in a conventional manufacturing process, can be used for the sheet-like electrode substrate. COPYRIGHT: (C)2005,JPO&NCIPI
    • 解决问题的方案:提供一种染料敏化太阳能电池,其中,作为片状电极基板,可以使用低成本且重量轻且具有自由形状的高透明度的树脂材料 ,并提供用于制造电池电极的金属氧化物分散液。 解决方案:用于染料敏化太阳能电池的光活性电极可以通过在片状电极上施加包含金属氧化物的太阳能电池用金属氧化物分散液之后,在室温至200℃下进行热处理来制造 颗粒,不含氢氧化物的粘合剂,也不含氨基和溶剂。 因此,片状电极基板可以使用在常规制造工艺中进行的在高温下的热处理中不能保持其性能的树脂等材料。 版权所有(C)2005,JPO&NCIPI
    • 9. 发明专利
    • Polymerizable composition
    • 可聚合组合物
    • JP2011032351A
    • 2011-02-17
    • JP2009179188
    • 2009-07-31
    • Showa Denko Kk昭和電工株式会社
    • YAMAGAMI ISAOUENO AKIKOMUROFUSHI KATSUMI
    • C08F2/50
    • PROBLEM TO BE SOLVED: To provide a polymerizable composition that includes a thiol compound and a compound having an ethylenically unsaturated double bond as components of a resin composition with good water resistance, alkali resistance, and heat resistance.
      SOLUTION: The polymerizable composition includes an aromatic ether-based multifunctional secondary thiol compound represented by general formula (1) and a compound having an ethylenically unsaturated double bond, wherein A is an n-functional aromatic group; R
      1 is a 1-3C alkyl group; m is an integer of 1-4; and n is an integer of 2-4. A cured product is obtained by performing photopolymerization of the composition.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 待解决的问题:提供包含硫醇化合物和具有烯属不饱和双键的化合物作为具有良好耐水性,耐碱性和耐热性的树脂组合物的组分的可聚合组合物。 解决方案:聚合性组合物包括由通式(1)表示的芳族醚系多官能仲硫醇化合物和具有烯属不饱和双键的化合物,其中A为正官能芳族基团; R 1是一个1-3C的烷基; m为1-4的整数; n为2-4的整数。 通过进行组合物的光聚合获得固化物。 版权所有(C)2011,JPO&INPIT
    • 10. 发明专利
    • Thiol compound
    • THIOL化合物
    • JP2011032201A
    • 2011-02-17
    • JP2009179186
    • 2009-07-31
    • Showa Denko Kk昭和電工株式会社
    • YAMAGAMI ISAOUENO AKIKOMUROFUSHI KATSUMI
    • C07C323/12
    • PROBLEM TO BE SOLVED: To provide a new thiol compound serving as a raw material for a resin composition having good water resistance, alkali resistance and heat resistance. SOLUTION: The aromatic ether-based polyfunctional secondary thiol compound is represented by general formula (1) [wherein, R 1 is 1C-3C alkyl; R 2 is hydrogen or 1C-3C alkyl which may have a substituent; R 3 is 1C-4C alkyl which may have a substituent, or 1C-4C alkoxy which may have a substituent; m is an integer of 1-2; (a) is 0 or an integer of 1-2; b is an integer of 2-4; c is 0 or an integer of 1-2; with the proviso that a+b is 4]. COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供用作具有良好的耐水性,耐碱性和耐热性的树脂组合物的原料的新的硫醇化合物。 解决方案:芳族醚类多官能二级硫醇化合物由通式(1)表示[其中,R 1 SP 1是C 1 -C 3烷基; R 2是氢或可具有取代基的C 1 -C 3烷基; R 3是可以具有取代基的1C-4C烷基或可以具有取代基的1C-4C烷氧基; m为1-2的整数; (a)为0或1-2的整数; b为2-4的整数; c为0或1-2的整数; 条件是a + b为4]。 版权所有(C)2011,JPO&INPIT