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    • 5. 发明专利
    • Manufacture of glass fiber strand having superior workability and hydrophilic property
    • 玻璃纤维条的制造具有优越的工作性能和亲水性
    • JPS5950054A
    • 1984-03-22
    • JP16177982
    • 1982-09-17
    • Nippon Valqua Ind Ltd
    • OOZEKI TAKAOKOMAZAWA TOSHIKIYO
    • C08K9/00C03C25/10C04B14/44C08F26/00C08F226/04C08G73/00C08G73/02C08G75/00C08K9/04
    • PURPOSE: To obtain a glass fiber strand having superior workability and hydrophilic property, by treating glass fibers with a composition contg. polyethylene oxide and a polymer of an N-contg. compound having a specified structure as essential components.
      CONSTITUTION: Glass fibers are treated with a composition contg. polyethylene oxide represented by formula I such as polyethylene glycol and ≥1 kind of hydrophilic compound represented by formula II (where each of R
      1 and R
      2 is H, alkyl, aralkyl or the like, X is Cl or Br, and M is the residue of a vinyl monomer), e.g., diallyldimethyl-ammonium chloride as essential components. The compounds I and II are used in 95:5W5:95 weight ratio. The amount of the hydrophilic property providing agent to be stuck is about 0.01W10wt% of the amount of the glass fibers. By the treatment the workability, bundlability and hydrophilic property of a strand can be improved.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:为了获得具有优异的可加工性和亲水性的玻璃纤维束,通过处理具有组成的玻璃纤维 聚环氧乙烷和N-contg的聚合物。 具有特定结构的化合物作为必需组分。 构成:玻璃纤维用组合物处理 由式I表示的聚环氧乙烷如聚乙二醇和> = 1种由式II表示的亲水性化合物(其中R 1和R 2各自为H,烷基,芳烷基等,X为Cl或Br,M为残基 的乙烯基单体),例如二烯丙基二甲基氯化铵作为必需组分。 化合物I和II以95:5-5:95的重量比使用。 待粘合的亲水性赋予剂的量为玻璃纤维量的约0.01〜10重量%。 通过处理,可以提高线的可加工性,捆扎性和亲水性。
    • 6. 发明专利
    • Method for providing hydrophilic property to glass and glass fiber
    • 向玻璃和玻璃纤维提供氢化物性的方法
    • JPS5950052A
    • 1984-03-22
    • JP16177782
    • 1982-09-17
    • Nippon Valqua Ind Ltd
    • OOZEKI TAKAOKOMAZAWA TOSHIKIYO
    • C08K9/00C03C25/10C04B14/44C08F26/00C08F26/02C08F226/04C08G73/00C08G73/02C08G73/06C08G75/20C08K9/04
    • PURPOSE: To obtain glass fibers having superior hydrophilic property and water retentivity, by treating glass and glass fibers with a system contg. a polymer of an N-contg. compound having a specified structure to make the glass wettable with water.
      CONSTITUTION: Glass and glass fibers are treated with an aqueous soln. of a hydrophilic property providing agent contg. ≥1 kind of compound represented by the general formula (where each of R
      1 and R
      2 is H, alkyl, alkyl contg. a functional group or aralkyl, X is Cl or Br, and M is the residue of a vinyl monomer), e.g., diallyldimethyl-ammonium chloride. Air drying and drying under heating are then carried out. The amount of the agent to be stuck is about 0.01W10wt% of the amount of the glass fibers. Since the agent has positive charges, it bonds firmly to the surfaces of the glass fibers by ionic bond, so the hydrophilic property, dispersibility and water retentivity of the glass fibers can be improved.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:获得具有优良亲水性和保水性的玻璃纤维,通过用系统处理玻璃纤维和玻璃纤维。 N-contg的聚合物 具有特定结构以使玻璃可用水润湿的化合物。 构成:玻璃纤维和玻璃纤维用水溶液处理。 的亲水性质提供剂 > = 1种通式(其中R1和R2各自为H,烷基,烷基官能团或芳烷基,X为Cl或Br,M为乙烯基单体的残基)的化合物,例如 二烯丙基二甲基氯化铵。 然后进行空气干燥和加热干燥。 待粘合剂的量为玻璃纤维量的约0.01-10重量%。 由于该试剂具有正电荷,所以它通过离子键牢固地粘合到玻璃纤维的表面上,因此可提高玻璃纤维的亲水性,分散性和保水性。
    • 7. 发明专利
    • Preparation of glass fiber having alkali resistance
    • 具有碱性电阻的玻璃纤维的制备
    • JPS59217648A
    • 1984-12-07
    • JP8913583
    • 1983-05-23
    • Nippon Valqua Ind LtdNitto Chem Ind Co Ltd
    • OOZEKI TAKAOKOMAZAWA TOSHIKIYOHASHIGUCHI TAKASHITAKAHASHI TERUOISHIDA HIDEO
    • C04B14/44C03C25/10C03C25/02
    • PURPOSE: To prepare glass fiber having alkali resistance, by using a sizing agent for glass fiber containing a specific improver for alkali resistance as an essential component of the sizing agent.
      CONSTITUTION: A sizing agent containing at least one improver for alkali resistance shown by the formula. In the formula, R
      1 is H, ethyl group, or carboxymethyl group; X
      1 and X
      2 are H, alkali metal, ammonium group, or organic ammonium group; M is vinyl monomer residue; m is arbitrary integer; n is 0 or arbitrary integer. When n is 0 in the formula, the improver shown by the formula is a polymer of fumaric acid, maleic acid, citraconic acid, or its derivative. When n is not 0, it is at least a binary copolymer of a carboxy group-containing monomer or its derivative and another vinyl monomer.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:为了制备具有耐碱性的玻璃纤维,通过使用含有耐碱性的特定改良剂的玻璃纤维的施胶剂作为上浆剂的必要成分。 构成:含有至少一种耐碱性改进剂的施胶剂,由式表示。 在该式中,R 1为H,乙基或羧甲基; X1和X2是H,碱金属,铵基或有机铵基; M是乙烯基单体残基; m是任意整数; n为0或任意整数。 当式中n为0时,由式表示的改进剂是富马酸,马来酸,柠康酸或其衍生物的聚合物。 当n不为0时,它至少是含羧基单体或其衍生物与另一种乙烯基单体的二元共聚物。
    • 8. 发明专利
    • Manufacture of glass fiber strand having superior workability and hydrophilic property
    • 玻璃纤维条的制造具有优越的工作性能和亲水性
    • JPS5950055A
    • 1984-03-22
    • JP16178082
    • 1982-09-17
    • Nippon Valqua Ind Ltd
    • OOZEKI TAKAOKOMAZAWA TOSHIKIYO
    • C08K9/00C03C25/10C04B14/44C08F20/00C08F20/34C08F220/36C08K9/04
    • PURPOSE: To obtain a glass fiber strand having superior workability and hydrophilic property, by treating glass fibers with a composition contg. a polymer of an N-contg. compound having a specified structure and glycerols as essential components.
      CONSTITUTION: Glass fibers are treated with a composition contg. ≥1 kind of hydrophilic compound represented by formula I (where R
      1 is H or methyl, R
      2 is -CH-, each of R
      3 WR
      5 is alkyl or aralkyl, X is Cl, Br or I, and M is the residue of a vinyl monomer), e.g., methacryloyloxyethyltrimethylammonium chloride and ≥1 kind of glycerol (adduct to ethylene oxide) represented by formula II as essential components. The compounds I and II are used in 95:5W5:95 weight ratio. The amount of the hydrophilic property providing agent to be stuck is about 0.01W10wt% of the amount of the glass fibers. By the treatment the workability, bundlability and hydrophilic property of a strand can be improved.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:为了获得具有优异的可加工性和亲水性的玻璃纤维束,通过处理具有组成的玻璃纤维 N-contg的聚合物 具有特定结构的化合物和甘油作为必需组分。 构成:玻璃纤维用组合物处理 > = 1种由式I表示的亲水性化合物(其中R 1为H或甲基,R 2为-CH-,R 3 -R 5各自为烷基或芳烷基,X为Cl,Br或I,M为 乙烯基单体),例如甲基丙烯酰氧基乙基三甲基氯化铵和> = 1种由式II表示的甘油(与环氧乙烷的加合物)作为必需组分。 化合物I和II以95:5-5:95的重量比使用。 待粘合的亲水性赋予剂的量为玻璃纤维量的约0.01〜10重量%。 通过处理,可以提高线的可加工性,捆扎性和亲水性。
    • 9. 发明专利
    • Manufacture of glass fiber strand having superior workability and hydrophilic property
    • 玻璃纤维条的制造具有优越的工作性能和亲水性
    • JPS5950053A
    • 1984-03-22
    • JP16177882
    • 1982-09-17
    • Nippon Valqua Ind Ltd
    • OOZEKI TAKAOKOMAZAWA TOSHIKIYO
    • C08K9/00C03C25/10C04B14/44C08F226/04C08G73/00C08G75/00C08G75/20C08K9/04C08L33/00C08L33/02C08L33/04
    • PURPOSE: To obtain a glass fiber strand having superior workability and hydrophilic property, by treating glass fibers with a composition contg. an org. silane compound having a specified structure and a polymer of an N-contg. compound having a specified structure as essential components.
      CONSTITUTION: Glass fibers are treated with an aqueous soln. of a hydrophilic property providing agent contg. a silane compound represented by formula I (where R
      1 is alkyl, and R
      2 is alkylene) and a compound represented by formula II(where each of R
      3 and R
      4 is H, alkyl, aralkyl or the like, X is Cl, and M is the residue of a vinyl monomer), e.g., γ-aminopropyltriethoxysilane as essential components. The compounds I and II are used in 95:5W5:95 weight ratio. The amount of the agent to be stuck is about 0.01W10wt% of the amount of the glass fibers. By the treatment the workability, bundlability and hydrophilic property of a strand can be improved.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:为了获得具有优异的可加工性和亲水性的玻璃纤维束,通过处理具有组成的玻璃纤维 一个组织 具有特定结构的硅烷化合物和N-contg的聚合物。 具有特定结构的化合物作为必需组分。 构成:玻璃纤维用水溶液处理。 的亲水性质提供剂 由式I表示的硅烷化合物(其中R 1是烷基,R 2是亚烷基)和由式II表示的化合物(其中R 3和R 4各自是H,烷基,芳烷基等,X是Cl,M是 乙烯基单体的残基),例如γ-氨基丙基三乙氧基硅烷作为必需组分。 化合物I和II以95:5-5:95的重量比使用。 待粘合剂的量为玻璃纤维量的约0.01-10重量%。 通过处理,可以提高线的可加工性,捆扎性和亲水性。
    • 10. 发明专利
    • Manufacture of glass fiber strand having excellent processability and hydrophilic property
    • 具有优异处理性和亲水性的玻璃纤维条的制造
    • JPS58204843A
    • 1983-11-29
    • JP8330882
    • 1982-05-19
    • Nippon Valqua Ind Ltd
    • OOZEKI TAKAOKOMAZAWA TOSHIKIYO
    • C04B14/44C03C25/10
    • PURPOSE: To manufacture a glass fiber strand having excellent collectability, processability and hydrophilic properties, by treating a glass fiber strand with a system containing specific two kinds of compounds.
      CONSTITUTION: A strand obtained by collecting glass filaments having diameter of 3W25μ is immersed in an aqueous solution containing 5W95wt% of the compound of formula I (R
      1 is alkyl; R
      2 is alkylene; m and n are integer, and 10≤m+ n≤100) and 95W5wt% of the compound of formula II (R
      3 is H or methyl; R
      4 W R
      6 are alkyl or aralkyl; X is Cl, Br or I; M is vinyl monomer residue; x is arbitrary integer; y is 0 or arbitrary integer; 10≤x+y≤5,000). The strand is taken out of the solution and dried to obtain the treated strand having 0.01W 10wt% of the above compounds attached thereto. The glass fiber treated by this process has excellent hydrophylic property, water-retainability and solid effluence preventing property comparable to those of asbestos.
      COPYRIGHT: (C)1983,JPO&Japio
    • 目的:通过用含有特定两种化合物的体系处理玻璃纤维束,制造具有优异的收集性,加工性和亲水性的玻璃纤维束。 构成:将通过收集直径为3-25mu的玻璃纤维所获得的线材浸入含有5-95wt%式I化合物的水溶液中(R1是烷基; R2是亚烷基; m和n是整数, = m + n <= 100)和95-5重量%的式II化合物(R3是H或甲基; R4-R6是烷基或芳烷基; X是Cl,Br或I; M是乙烯基单体残基; x是任意的 整数; y是0或任意整数; 10 <= x + y <= 5,000)。 将该链从溶液中取出并干燥,得到具有0.01-10重量%上述附着的化合物的经处理的链。 通过该方法处理的玻璃纤维具有与石棉相当的亲水性,保水性和固体流失防止性能。