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    • 3. 发明专利
    • Water-based metallic coating and method for forming multi-layered coating film
    • 基于水的金属涂层和形成多层涂膜的方法
    • JP2007056161A
    • 2007-03-08
    • JP2005244292
    • 2005-08-25
    • Nippon Paint Co Ltd日本ペイント株式会社
    • OGAWA HIDEAKIHAYASHI HIROKIOBARA KOICHIANDO HIROYOSHIHIBI SUSUMU
    • C09D151/00B05D1/36B05D5/06C09D5/02C09D5/29C09D7/12C09D161/28
    • PROBLEM TO BE SOLVED: To provide a water-based coating composition which maintains the excellent characteristics of a water-based metallic coating and can simultaneously give coating films capable of holding an excellent flip-flop property by a two-coat, one base coating method. SOLUTION: This water-based coating composition comprising a coating film-forming resin, a curing agent and a bright pigment is characterized in that the coating film-forming resin comprises an acrylic resin emulsion obtained by a two step emulsion polymerization method using a monomer mixture containing a two or more unsaturated double bond-having unsaturated monomer in an amount of 0.05 to 30.0 mass% based on the solid content of the coating film-forming resin, and having an acid value of 1 to 30 mgKOH/g, a hydroxyl group value of 10 to 150, and a particle diameter of 20 to 140 nm; the curing agent is a hydrophobic melamine resin aqueous dispersion having a particle diameter of 20 to 140 nm; and a specific urethane-based compound is contained in an amount of 0.01 to 20 mass% based on a resin content in the coating composition. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种保持水性金属涂层的优异特性的水性涂料组合物,并且可以同时得到能够通过双层涂料保持优异的触发性能的涂膜 底涂法。 解决方案:这种包含涂膜形成树脂,固化剂和光亮颜料的水性涂料组合物的特征在于,涂膜形成树脂包括通过两步乳液聚合方法获得的丙烯酸树脂乳液,其使用 含有相对于涂膜树脂的固体成分为0.05〜30.0质量%的两种以上不饱和双键的不饱和单体,酸值为1〜30mgKOH / g的单体混合物, 羟基值为10〜150,粒径为20〜140nm; 固化剂是粒径为20〜140nm的疏水性三聚氰胺树脂水分散体, 相对于涂料组合物中的树脂含量,含有0.01〜20质量%的特定的氨基甲酸酯类化合物。 版权所有(C)2007,JPO&INPIT
    • 6. 发明专利
    • Water-base coating material and multilayer coating film forming method using the same
    • 水基涂层材料和多层涂膜成型方法
    • JP2012007113A
    • 2012-01-12
    • JP2010145719
    • 2010-06-28
    • Nippon Paint Co Ltd日本ペイント株式会社
    • KOIZUMI ATSUSHIOYAMA TAKESHIKAWABATA TAKAYUKIHIBI SUSUMU
    • C09D133/00B05D1/36B05D7/14C09D5/00C09D5/02C09D7/12C09D167/00
    • PROBLEM TO BE SOLVED: To provide a technology for preventing the occurrence of so-called clusters, which is a coating film defect of water-base coating material used for coating film forming for an automobile.SOLUTION: This water-base coating material contains, in 100 mass% of resin solid content, (a) 10-60 mass% of solid content of acrylic resin emulsion, (b) 5-40 mass% of solid content of water-soluble acrylic resin, (c) 20-40 mass% of solid content of melamine resin, and (d) 0.1-5 mass% of nonion-modified olefine resin that is obtained by making 8-22C polyethylene glycol monochrome alkyl ether (iii) of HLB 10-20 react with a copolymer of 10-16C α-olefin compound (i) and carboxylic acid anhydride (ii) having unsaturated double bond, and has a solid content acid value of 20-60 mgKOH/g and a weight-average molecular weight of 10,000-100,000.
    • 要解决的问题:提供防止作为用于汽车涂膜成膜的水性涂料的涂膜缺陷所谓的簇的发生的技术。 解决方案:该水性涂料含有100质量%的树脂固体成分,(a)10-60质量%的丙烯酸树脂乳液的固体成分,(b)5-40质量%的固体成分 水溶性丙烯酸树脂,(c)20-40质量%的三聚氰胺树脂的固体成分,和(d)通过制造8-22℃聚乙二醇单烯基烷基醚(d)得到的非离子改性烯烃树脂的0.1-5质量% iii)HLB 10-20与10-16Cα-烯烃化合物(i)和具有不饱和双键的羧酸酐(ii)的共聚物反应,其固含量酸值为20-60mgKOH / g,和 重均分子量为10,000-100,000。 版权所有(C)2012,JPO&INPIT