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1. 发明专利

JPS6187717A Polymer emulsion 失效
标题翻译：聚合物乳液
公开(公告)号：JPS6187717A
公开(公告)日：1986-05-06
申请号：JP18738385
申请日：1985-08-28
申请人： Mitsui Toatsu Chem Inc
发明人： ITO HIROSHI , NITTA ATSUHIKO , TANAKA TOMIO , KAMIO HIDEO
IPC分类号： C08F220/00 , C08F20/52 , C08F220/54
摘要： PURPOSE: A temperature-sensitive polymer emulsion which comprises polymer particles each consisting of a core composed of an oleophilic monomer and a surface composed of a specified monomer, has a surface to which specified functions can be easily imparted and is useful as a processing agent for paper, fiber, etc., prepared by copolymerizing a specified monomer with an oleophilic monomer.
CONSTITUTION: At least 0.05wt% N-alkyl- or N-alkylene-substituted (meth) acrylamide monomer (A) of formula I or II [wherein R
2 is R
1 or ethyl, R
1 is H or methyl, R
3 is methyl or ethyl, A is formula III (wherein n is 4W6), or formula IV] is copolymerized with an oleophilic monomer (B) (e.g., styrene) and, optionally, a hydrophilic monomer and an ionic monomer (C) at 0W100°C in the presence of a polymerization initiator by using water as a reaction medium and a surfactant to obtain a polymer emulsion containing 5W60% polymer in which the core is composed of component B and the surface is composed of component A. This polymer emulsion has a temperature-sensitive polymer which can undergo changes in hydrophilicity and hydrophobicity with temperature on the surface of the particle, and adsorption and desorption of various substances can be performed on this surface.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：包含由亲油性单体构成的核心和由特定单体构成的表面的聚合物粒子的温度敏感性聚合物乳液具有可以容易地赋予特定功能的表面，并且可用作加工剂纸，纤维等，通过使特定单体与亲油性单体共聚制备。组成：式I或II的至少0.05wt％的N-烷基 - 或N-亚烷基取代的（甲基）丙烯酰胺单体（A）[其中R 2是R 1或乙基，R 1是H或甲基，R 3是甲基或乙基， A是式III（其中n为4-6）或式IV]与亲油单体（B）（例如苯乙烯）和任选的亲水性单体和离子单体（C）在0-100℃下共聚在聚合引发剂的存在下，通过使用水作为反应介质和表面活性剂，得到含有5-60％聚合物的聚合物乳液，其中芯由组分B组成，表面由组分A组成。该聚合物乳液具有可以在颗粒表面上随着温度而亲水性和疏水性变化的温度敏感性聚合物，并且可以对该表面进行各种物质的吸附和解吸。

2. 发明专利

JPS60193955A Cyclic unsaturated amide-substituted ether compound and its preparation 失效
标题翻译：循环不饱和酰胺取代的醚化合物及其制备
公开(公告)号：JPS60193955A
公开(公告)日：1985-10-02
申请号：JP4653284
申请日：1984-03-13
申请人： Mitsui Toatsu Chem Inc
发明人： ITOU HIROSHI , NITSUTA ATSUHIKO , TANAKA TOMIO , KAMIO HIDEO
IPC分类号： C07C319/20 , C07C67/00 , C07C231/08 , C07C233/20 , C07C233/67 , C07C241/00 , C07C245/04 , C07C245/06 , C07C313/00 , C07C317/20 , C07C317/22 , C07C323/12 , C07C323/19 , C07D295/088 , C07D307/42 , C07D309/38
CPC分类号： C07D295/088 , C07D307/42 , C07D309/38
摘要： NEW MATERIAL:The compound of formula I (R
1 is cyclic group, i.e. carbon ring group or heterocyclic group; Z is alkylene, alkenylene, oxyalkylene, etc.; A is halogen, alkyl, alkenyl, etc.; B is O, carbonyl, thio, sulfonyl, etc.; R
2 is H or methyl; l is 0W5; when l is ≥2, plural A may be different; m is 4W20; α and β are 0W4; α+β is ≥1; p is 1 or 2; q is 0 or 1; q=0 when p=1, and q is 0 or 1 when p=2; in the latter case, the R
1 , A, l, α, and β at the right and left hands may be different).
EXAMPLE: N-(4-Phenoxybutyl)acrylamide.
USE: Useful as an adhesive, coating, etc.
PREPARATION: The compound of formula I can be prepared by reacting the cyclic halogen-substituted ether compound of formula II (A' is alkyl, etc.; X is halogen) with the unsaturated amide compound of formula III in an aprotic polar solvent in the presence of a strong basic substance.
COPYRIGHT: (C)1985,JPO&Japio
摘要翻译：新物质：式I化合物（R1为环状基团，即碳环基或杂环基; Z为亚烷基，亚烯基，氧化烯等）; A为卤素，烷基，烯基等; B为O，羰基，硫代，磺酰基等; R2是H或甲基; l是0-5;当l = 2时，多个A可以是不同的; m是4-20;α和β是0-4;α+β是 > = 1; p为1或2; q为0或1;当p = 1时q = 0，p = 2时q为0;在后一种情况下，q为1，R1，A，l，右手和左手的beta可能不同）。实施例：N-（4-苯氧基丁基）丙烯酰胺。用途：用作粘合剂，涂层等。制备：式I化合物可以通过使式II的环状卤素取代的醚化合物（A'是烷基等; X是卤素）与不饱和酰胺在非质子极性溶剂中，在强碱性物质存在下，式III化合物。

3. 发明专利

JPS58219158A Hydroxyalkanesulfonic acid, its derivative and its preparation 失效
标题翻译：羟基甘氨酸，其衍生物及其制备
公开(公告)号：JPS58219158A
公开(公告)日：1983-12-20
申请号：JP10207882
申请日：1982-06-16
申请人： Mitsui Toatsu Chem Inc
发明人： ITOU HIROSHI , NITSUTA ATSUHIKO , KAMIO HIDEO
IPC分类号： C07C309/24 , C07C67/00 , C07C301/00 , C07C303/02 , C07C303/14
摘要： NEW MATERIAL:The compound of formula (R is 1W10C alkyl) and its derivative.
EXAMPLE: 2-Phenyl-2-hydroxypropanesulfonic acid and its salt.
USE: Useful as a raw material of an amidoalkanesulfonic acid derivative which is useful as a lime soap dispersing agent, a modifier of fiber made of water-soluble polymer, etc.
PROCESS: The compound of formula can be prepared by reacting an α-alkylstyrene (e.g. α-methylstyrene, α-ethylstyrene, etc.) with bisulfite ion in a solvent such as water, alcohol, tetrahydrofuran, etc. in the presence of oxygen at -20W +70°C, preferably -10W+60°C for 20minW10hr. Addition of a phase transfer catalyst (e.g. tetramethylammonium chloride) to the reaction system promotes the reaction.
COPYRIGHT: (C)1983,JPO&Japio
摘要翻译：新材料：式（R为1-10C烷基）的化合物及其衍生物。实施例：2-苯基-2-羟基丙磺酸及其盐。用途：可用作酸性皂分散剂的酰胺基烷基磺酸衍生物的原料，由水溶性聚合物等制成的纤维改性剂。方法：该化合物可以通过使α-烷基苯乙烯（例如α-甲基苯乙烯，α-乙基苯乙烯等）与亚硫酸氢盐离子在溶剂如水，醇，四氢呋喃等中在-20-70℃，优选-10- + 60℃的存在下反应 ℃20分钟-10小时。向反应体系中加入相转移催化剂（例如四甲基氯化铵）促进反应。

4. 发明专利

JPS60193979A N-(omega-glycidoxyalkyl) substituted amide and its preparation 失效
标题翻译： N-（OMEGA-GLYCIDOXYALKYL）取代的酰胺及其制备
公开(公告)号：JPS60193979A
公开(公告)日：1985-10-02
申请号：JP4818584
申请日：1984-03-15
申请人： Mitsui Toatsu Chem Inc
发明人： ITOU HIROSHI , NITSUTA ATSUHIKO , TANAKA TOMIO , KAMIO HIDEO
IPC分类号： C07D303/18 , C07D303/22 , C07D303/24 , C07D303/27 , C07D303/46 , C08G59/28 , C08G59/32
CPC分类号： C07D303/22 , C07D303/24 , C08G59/28 , C08G59/3227
摘要： NEW MATERIAL:A compound of formula I (R is aliphatic hydrocarbon, aromatic hydrocarbon; X is H, ω-glycidoxyalkoxy; p is 0, 1; q, s are 1W4; m is 4W20; where, when Z is H, p is 0, 1).
EXAMPLE: N-(6-Glycidoxyhexyl)acrylamide.
USE: It is used as an adhesive, coating, paper finishing agent, fiber finishing agent, emulsion, urethane-curing agent, pigment dispersant, plastic additive and polymer coagulation agent.
PREPARATION: The reaction of an amide of formula II (Y is H, OH, amino) with a halogen-substituted glycidyl ether is carried out in an aprotonic polar solvent such as acetonitrile or N,N-dimethylformamide in the presence of a strong base such as NaOH or KOH to give the compound of formula I .
COPYRIGHT: (C)1985,JPO&Japio
摘要翻译：新物质：式Ⅰ化合物（R为脂族烃，芳烃; X为H，ω-缩水甘油氧基烷氧基; p为0,1; q，s为1-4; m为4-20; Z为 H，p为0,1）。实施例：N-（6-乙酰氧基己基）丙烯酰胺。用途：用作粘合剂，涂料，造纸剂，纤维整理剂，乳液，聚氨酯固化剂，颜料分散剂，塑料添加剂和聚合物凝结剂。制备：式II的酰胺（Y是H，OH，氨基）与卤素取代的缩水甘油醚的反应在非质子极性溶剂如乙腈或N，N-二甲基甲酰胺中在强碱的存在下进行例如NaOH或KOH，得到式I化合物。

5. 发明专利

JPS60190424A Unsaturated amide-substituted polyoxyalkylene and its production 失效
标题翻译：不饱和酰胺取代的聚氧乙烯及其生产
公开(公告)号：JPS60190424A
公开(公告)日：1985-09-27
申请号：JP4653184
申请日：1984-03-13
申请人： Mitsui Toatsu Chem Inc
发明人： ITOU HIROSHI , NITSUTA ATSUHIKO , TANAKA TOMIO , KAMIO HIDEO
IPC分类号： C08G65/32 , C07C233/20
摘要： PURPOSE: The titled compound that is prepared by reaction between a polyoxyalkylene and an unsaturated amide in an aprotonic polar solvent in the presence of a strong base, thus being capable of producing a variety of specifications through the same reaction process with the same reactor.
CONSTITUTION: The reaction between a polyoxyalkylene of formula I (B is H, alkyl, alkenyl, haloalkyl, acyloxy, aminoalkyl; X is halogen; is 2W10; is 3W50; m is 4W20) and an unsaturated amide of formula II (R is H, methyl) is effected in an aprotonic polar solvent in the presence of a strong base to produce an unsaturated amide-substituted polyoxyalkylene of formula III (A is H, alkyl, alkenyl, haloalkyl, ω-unsaturated amide-polymethylene as shown by formula IV, acyloxy, aminoalkyl).
COPYRIGHT: (C)1985,JPO&Japio
摘要翻译：目的：通过在强碱存在下在非质子极性溶剂中在聚氧化烯和不饱和酰胺之间反应制备的标题化合物，因此能够通过与相同反应器相同的反应方法产生各种规格。构型：式I的聚氧化烯（B为H，烷基，烯基，卤代烷基，酰氧基，氨基烷基; X为卤素;为2-10;为3-50; m为4-20）与不饱和酰胺式II（R为H，甲基）在非质子极性溶剂中，在强碱存在下进行，得到式III的不饱和酰胺取代的聚氧化烯（A为H，烷基，烯基，卤代烷基，ω-不饱和酰胺 - 聚亚甲基，如式IV所示，酰氧基，氨基烷基）。

6. 发明专利

JPS60190746A Aliphatic n-substituted unsaturated amide compound and preparation thereof 失效
标题翻译：二次N-取代的不饱和酰胺化合物及其制备方法
公开(公告)号：JPS60190746A
公开(公告)日：1985-09-28
申请号：JP4549384
申请日：1984-03-12
申请人： Mitsui Toatsu Chem Inc
发明人： ITOU HIROSHI , NITSUTA ATSUHIKO , TANAKA TOMIO , KAMIO HIDEO
IPC分类号： C07C323/12 , C07C67/00 , C07C233/20 , C07C241/00 , C07C245/04 , C07C313/00 , C07C317/18 , C07C317/28
摘要： NEW MATERIAL:A compound expressed by formula I (A is halogen, ω-unsaturated amide polymethylene, OH, etc.; B is O, carbonyl, thio, sulfonyl, etc,; R is H or methyl; l is an integer 0W5; m is an integer 4W20; n is an iteger 1W4; α is an integer 1W30; β
摘要翻译：新材料：由式I表示的化合物（A为卤素，ω-不饱和酰胺多亚甲基，OH等; B为O，羰基，硫代，磺酰基等; R为H或甲基; l为0〜 5; m是整数4-20; n是整数1-4;α是整数1-30;βα是整数0-3; p是1或2; q是0或1; 当p为1时，q为0，p为2时为2）。实施例：N-（4-正丁氧基丁基）丙烯酰胺。用途：用于粘合剂的主要或次要原料，涂布纸的加工剂，纺织品处理剂，乳液，氨基甲酸酯固化剂等以及交联剂。制备：式II（A'为卤素，OH，烷氧基等; X为卤素）表示的化合物与非质子传递极性溶剂例如式III表示的化合物反应。乙腈和强碱，例如。 NaOH，得到由式I表示的目标化合物。

7. 发明专利

JPS58225057A Preparation of hydroxyalkanesulfonic acid derivative 失效
标题翻译：羟基甘氨酸衍生物的制备
公开(公告)号：JPS58225057A
公开(公告)日：1983-12-27
申请号：JP10671182
申请日：1982-06-23
申请人： Mitsui Toatsu Chem Inc
发明人： ITOU HIROSHI , NITSUTA ATSUHIKO , KAMIO HIDEO
IPC分类号： C07C309/24 , C07C67/00 , C07C301/00 , C07C303/02 , C07C303/14
摘要： PURPOSE: To obtain the titled compound useful as a raw material for amidoalkanesulfonic acid derivatives in high purity and yield, by reacting an α-alkylstyrene with a hydrogenbisulfite of an alkaline earth metal as a hydrogensulfite ion supply source.
CONSTITUTION: An α-alkylstyrene is reacted with hydrogensulfite ions in the presence of oxygen in an aqueous medium at -20W+70°C to give the aimed substance of the formula (R is 1W10C lower alkyl). In the process, a hydrogensulfite of an alkaline earth metal, e.g. calcium or barium, is used as the hydrogensulfite ion supply source, and the reaction is carried out in the suspension of the sulfite of the alkaline earth metal. According to the method, the pH of the reaction solution is easily adjusted, and the dispersion of the α-alkylstyrene in the aqueous medium is kept in a good state. The amidoalkanesulfonic acid derivative is useful as a dispersant for calcium soaps, a raw material for water- soluble high polymers, etc.
COPYRIGHT: (C)1983,JPO&Japio
摘要翻译：目的：通过使α-烷基苯乙烯与碱土金属的氢化亚硫酸氢盐作为亚硫酸氢盐离子供给源反应，得到高纯度和高产率的用作酰胺基烷基磺酸衍生物的原料的标题化合物。构成：在-20- + 70℃的水性介质中，在氧存在下，α-烷基苯乙烯与亚硫酸氢盐离子反应，得到式（R为1-10C低级烷基）的目标物质。在此过程中，碱土金属的亚硫酸氢盐，例如钙或钡用作亚硫酸氢盐离子供应源，并且反应在碱土金属的亚硫酸盐的悬浮液中进行。根据该方法，可以容易地调整反应溶液的pH，并且将α-烷基苯乙烯在水性介质中的分散体保持在良好的状态。酰胺基磺酸衍生物可用作钙皂的分散剂，水溶性高聚物的原料等。

8. 发明专利

JPS58225056A Preparation of amidoalkanesulfonic acid derivative 失效
标题翻译：氨基磺酸衍生物的制备
公开(公告)号：JPS58225056A
公开(公告)日：1983-12-27
申请号：JP10753882
申请日：1982-06-24
申请人： Mitsui Toatsu Chem Inc
发明人： ITOU HIROSHI , NITSUTA ATSUHIKO , KAMIO HIDEO
IPC分类号： C07B61/00 , B01J27/00 , B01J27/02 , C07C67/00 , C07C301/00 , C07C303/22 , C07C309/15 , C07C309/24 , C08F2/22 , C08F2/44 , C08F220/58
CPC分类号： C08F220/58
摘要： PURPOSE: To obtain the titled compound useful as a dispersant for calcium soaps, raw material for water-soluble high polymers, and ion exchangers, etc. in high purity and yield, by reacting a nitrile compound with a hydroxyalkanesulfonic acid derivative in concentrated sulfuric acid.
CONSTITUTION: A nitrile compound of the formula R
1 -C≡N (R
1 is alkyl, alkenyl, phenylalkyl or aryl) is reacted with a β-hydroxyalkanesulfonic acid of formula I (R
2 and R
3 are H, lower alkyl or phenyl) or an alkali metallic salt or an alkaline earth metallic salt thereof in concentrated sulfuric acid at -30W +120°C, preferably -25W+100°C, to give the aimed compound of formula II. The amounts of the nitrile compound and sulfuric acid based on one mole compound of formula I are as follows: 1W40mol nitrile compound and 1W20mol sulfuric acid.
COPYRIGHT: (C)1983,JPO&Japio
摘要翻译：目的：通过使腈化合物与羟基链烷磺酸衍生物在浓硫酸中反应，得到高纯度和收率的用作钙皂分散剂，水溶性高分子聚合物原料，离子交换剂等的标题化合物。构成：将式R1-同价N（R1是烷基，烯基，苯基烷基或芳基）的腈化合物与式I的β-羟基链烷磺酸（R2和R3是H，低级烷基或苯基）或碱金属盐或其碱土金属盐在浓硫酸中在-30-120℃，优选-25- + 100℃下反应，得到目的化合物II。基于1摩尔式I化合物的腈化合物和硫酸的量如下：1-40摩尔腈化合物和1-20摩尔硫酸。

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