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    • 3. 发明专利
    • Method for producing crystalline microporous body
    • 生产晶体微孔体的方法
    • JP2009067638A
    • 2009-04-02
    • JP2007238755
    • 2007-09-14
    • Maruzen Petrochem Co LtdNational Institute Of Advanced Industrial & Technology丸善石油化学株式会社独立行政法人産業技術総合研究所
    • INOUE TOMOYASUGIYAMA HIROKIKIYOZUMI YOSHIMICHIHAMAKAWA SATOSHIMIZUKAMI FUJIO
    • C01B33/26C01B39/38
    • PROBLEM TO BE SOLVED: To provide: a method for producing a crystalline aluminum silicate microporous body having grain diameters of ≤2 μm, by which aluminum can be efficiently introduced under a mild condition, to provide the crystalline microporous body being industrially usable, a crystalline microporous molded article, and to provide a crystalline microporous body which exhibits high performances in applications such as a catalyst. SOLUTION: The method for producing the crystalline aluminum silicate microporous body is characterized by including following processes (1) to (4): (1) a mixing process for preparing an alkaline mixed liquid containing kanemite, an alumina precursor, and at least one kind of crystallization adjusting agent selected from ammonium compounds, phosphonium compounds or amines and agitating the mixed liquid for six hours or over; (2) a neutralization process for neutralizing the mixed liquid obtained in the process (1) so that the pH of the mixed liquid becomes 7.6 to 8.4; (3) a solid-liquid separation process for separating fine particles deposited in the mixed liquid neutralized in the process (2) from the mixed liquid; and (4) a crystallization process for crystallizing the fine particles separated from the liquid by heating them. The crystalline aluminum silicate microporous body is produced by the method. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种晶体直径≤2μm的结晶硅酸铝微孔体的制造方法,在温和条件下可以有效地引入铝,提供工业上可利用的结晶微孔体 ,结晶微孔成型制品,并提供在诸如催化剂的应用中表现出高性能的结晶微孔体。 结晶硅酸铝微孔体的制造方法的特征在于包括以下工序(1)〜(4):(1)制备含有卡米质,氧化铝前体的碱性混合液的混合工序, 选自铵化合物,鏻化合物或胺的至少一种结晶调节剂,并搅拌混合液体6小时以上; (2)中和工序(1)中得到的混合液的中和工序,使混合液的pH变为7.6〜8.4; (3)一种固溶分离方法,用于将在方法(2)中和的混合液中沉积的细颗粒与混合液分离; 和(4)通过加热使从液体中分离出的微粒结晶的结晶方法。 通过该方法制造结晶硅酸铝微孔体。 版权所有(C)2009,JPO&INPIT
    • 7. 发明专利
    • Hydrogen gas separation material with elevated temperature resistance which does not deteriorate under elevated temperature hyperbaric pressure-humid environment for a long term
    • 具有高温耐温性的氢气分离材料,不会在高温高温压力 - 湿度环境中长期存在
    • JP2010036080A
    • 2010-02-18
    • JP2008200303
    • 2008-08-03
    • National Institute Of Advanced Industrial & Technology独立行政法人産業技術総合研究所
    • IKEDA TAKUSHIOKAZAKI JUNYAWAKUI YOSHITOMIZUKAMI FUJIO
    • B01D71/02B01D69/10B01D69/12C01B3/56
    • PROBLEM TO BE SOLVED: To provide a hydrogen gas separation material with elevated temperature resistance where the hydrogen permeation performance of a permeation membrane does not deteriorate under elevated temperature hyperbaric pressure-humid environment which exceeds a temperature of 650°C even if used for a long term exceeding 46 hours.
      SOLUTION: The hydrogen gas separation material with elevated temperature resistance is a hydrogen gas separation membrane that is provided with a permeation membrane having selective permeability to selectively permeate the hydrogen gas on the outer surface of a single layer porous ceramic supporter which does not have a multilayer structure. The supporter does not contain any component to form an alloy with a metal included in the permeation membrane under elevated temperature conditions each other. The permeation membrane includes the hydrogen permeation performance of 3×10
      -6 mol/m
      2 /s/Pa or more at a temperature of 650°C and the hydrogen permeation performance of the permeation membrane does not deteriorate even if the hydrogen permeation test for a long term of at least 46 hours is conducted under the elevated temperature hyperbaric pressure-humid environment of the hydrogen-containing mixture gas exceeding 650°C. Thus, the hydrogen gas separation material with elevated temperature resistance has the selective permeability which permeates and separates only hydrogen with high quality efficiently.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供具有耐高温性的氢气分离材料,即使使用超过650℃的高温高压高湿环境下,渗透膜的氢渗透性能也不会劣化 长期超过46小时。 解决方案:具有耐高温性的氢气分离材料是氢气分离膜,其具有选择性渗透性的渗透膜,以选择性地渗透单层多孔陶瓷载体的外表面上的氢气 具有多层结构。 该支持体不含任何组分以在升高的温度条件下与渗透膜中包含的金属形成合金。 渗透膜在650℃的温度下具有3×10 -6 -6 /分钟/秒以上的透氢性能,并且氢渗透性能 即使在超过650℃的含氢混合气体的高温高压 - 潮湿环境下长时间进行至少46小时的氢渗透试验,渗透膜也不会劣化。 因此,具有耐高温性的氢气分离材料具有选择性渗透性,其有效地渗透并分离出高质量的氢。 版权所有(C)2010,JPO&INPIT
    • 8. 发明专利
    • Method for producing fuel gas from waste paper
    • 从废纸生产燃油的方法
    • JP2009197223A
    • 2009-09-03
    • JP2009010414
    • 2009-01-20
    • National Institute Of Advanced Industrial & Technology独立行政法人産業技術総合研究所
    • YAMAGUCHI ARITOMOHIYOSHI NORITOSATO OSAMUSHIRAI MASAYUKIIKEDA TAKUJIMIZUKAMI FUJIO
    • C10J3/00B01J23/46
    • Y02P20/52
    • PROBLEM TO BE SOLVED: To provide a method for producing a fuel gas such as hydrogen and methane from waste paper in high efficiency. SOLUTION: Provided is a method for producing a fuel gas by gasifying used waste paper with a supported metal catalyst and high-temperature water, the method comprising the reaction of the waste paper with water and the supported metal catalyst in a reaction vessel to convert the waste paper to a fuel gas and obtain the fuel gas containing hydrogen and methane from the waste paper, wherein the supported metal catalyst is a ruthenium catalyst supported on activated carbon and the waste paper is used PPC paper wasted from offices. An environment-conscious new technique for producing a fuel gas such as hydrogen and methane in high efficiency while saving energy is provided by gasifying waste paper in combination with a supported metal catalyst such as a supported ruthenium catalyst and high-temperature water of 200-450°C. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种用于从废纸高效率地生产诸如氢和甲烷的燃料气体的方法。 解决方案:提供一种通过用负载金属催化剂和高温水气化废旧废纸来生产燃料气体的方法,该方法包括废纸与水的反应和负载的金属催化剂在反应容器中的反应 将废纸转化为燃料气体,从废纸中获得含有氢和甲烷的燃料气体,其中负载金属催化剂是负载在活性炭上的钌催化剂,废纸用于从办公室浪费的PPC纸。 通过将废纸与负载的钌催化剂等负载金属催化剂和200-450℃的高温水相结合,提供了一种环保意识的新技术,可以高效率地生产氢气和甲烷等燃料气体,同时节约能源 C。 版权所有(C)2009,JPO&INPIT
    • 9. 发明专利
    • HYDROGEN SEPARATING THIN FILM BY SIMULTANEOUS PLATING OF Pd-Ag, AND ITS MANUFACTURING METHOD
    • 通过Pd-Ag同时镀层分离薄膜及其制造方法
    • JP2009185308A
    • 2009-08-20
    • JP2008023181
    • 2008-02-01
    • National Institute Of Advanced Industrial & TechnologyNgk Insulators Ltd日本碍子株式会社独立行政法人産業技術総合研究所
    • SUZUKI TOSHISHIGEALFRED PACHECO TANAKAWAKUI YOSHITOMIZUKAMI FUJIONODA KENICHI
    • C23C18/44B01D69/10B01D69/12B01D71/02
    • PROBLEM TO BE SOLVED: To provide a hydrogen separating thin film, wherein palladium and silver are uniformly film-deposited so as to have a predetermined composition by the electroless plating on a surface of a non-conductive base material, and rapidly alloyed by heating at ≤600°C when manufacturing a dense palladium-silver alloy film which is used for the hydrogen separating thin film. SOLUTION: A method is provided for film-depositing palladium and silver at the predetermined composition ratio uniformly in the depth direction by controlling the deposition rate of both elements by continuously adding silver-containing aqueous solution at the predetermined flow rate in a process of performing the plating by immersing a porous base material with seed cores stuck thereto in a plating bath containing palladium and silver. The hydrogen separating thin film is manufactured by the method. A method is also provided for manufacturing the alloy film of palladium and silver to be used for the hydrogen separating film wherein palladium and silver are uniformly deposited on the surface of the non-conductive base material so as to have a predetermined composition by the electroless plating. The hydrogen separating thin film is manufactured by the method. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种氢分离薄膜,其中通过在非导电性基材的表面上进行化学镀,将钯和银均匀地膜沉积成具有预定组成,并且快速合金化 当制造用于氢分离薄膜的致密钯 - 银合金膜时,通过加热至≤600℃。 解决方案:提供了一种通过在工艺中以预定的流速连续加入含银水溶液来控制两种元素的沉积速率,以均匀的方式在深度方向上以预定组成比对钯和银进行膜沉积的方法 通过将含有种子芯的多孔基材浸渍在含有钯和银的镀浴中来进行电镀。 通过该方法制造氢分离薄膜。 还提供了用于制造用于氢分离膜的钯和银合金膜的方法,其中钯和银均匀地沉积在非导电基材的表面上,以便通过化学镀具有预定的组成 。 通过该方法制造氢分离薄膜。 版权所有(C)2009,JPO&INPIT
    • 10. 发明专利
    • Hydrolase complex of silica-based meso porous body-starch
    • 基于二氧化硅的MESO多孔体系的水解复合物
    • JP2009153448A
    • 2009-07-16
    • JP2007335229
    • 2007-12-26
    • National Institute Of Advanced Industrial & Technology独立行政法人産業技術総合研究所
    • TSUNODA TATSUROTOGASHI HIDEAKISEKIKAWA CHISATONARA TAKAYUKIHISAMATSU KANAKOSHIOMI TORUKAWAI AKIKOMIZUKAMI FUJIOSAKAGUCHI KENGO
    • C12N11/14C12P19/14
    • PROBLEM TO BE SOLVED: To provide a hydrolase complex of silica-based meso porous body-starch, which contributes to the realization of efficient starch hydrolysis for various starch materials, and enables the recovery, recycling and continuous use of the enzyme.
      SOLUTION: Provided is the hydrolase complex of silica-based meso porous body-starch, which is the complex of the silica-based meso porous body with the enzyme for hydrolyzing the starch, characterized in that the enzyme immobilized on the silica-based meso porous body has activity for catalyzing the hydrolysis of starch. Provided is a method for producing the hydrolase complex of silica-based meso porous body-starch, characterized by mixing the silica-based meso porous body with a solution containing the hydrolase to stably adsorb, hold and immobilize the hydrolase on the silica-based meso porous body and in the fine pores of the silica-based meso porous body. Further, provided is a method for producing a starch hydrolysis product, characterized by hydrolyzing starch with the hydrolase complex of silica-based meso porous body-starch.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供二氧化硅基中孔多孔体淀粉的水解酶复合物,其有助于实现各种淀粉材料的有效淀粉水解,并且能够回收,再循环和连续使用酶。 解决方案:提供二氧化硅基的内消旋多孔体 - 淀粉的水解酶复合物,其是二氧化硅基的内消旋多孔体与用于水解淀粉的酶的复合物,其特征在于固定在二氧化硅 - 基于meso多孔体具有催化淀粉水解的活性。 本发明提供一种二氧化硅系内消旋多孔体淀粉的水解酶配合物的制造方法,其特征在于,将二氧化硅系中孔多孔体与含有水解酶的溶液混合,使水解酶稳定地吸附, 多孔体和二氧化硅基中孔多孔体的细孔内。 此外,提供一种生产淀粉水解产物的方法,其特征在于用二氧化硅基的内消旋多孔体淀粉的水解酶复合物水解淀粉。 版权所有(C)2009,JPO&INPIT