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1. 发明专利

JPH05178929A HIGH-REFRACTIVE-INDEX TRANSPARENT RESIN AND ITS PRODUCTION 失效
公开(公告)号：JPH05178929A
公开(公告)日：1993-07-20
申请号：JP1767992
申请日：1992-02-03
申请人： MITSUBISHI HEAVY IND LTD , OIKAWA EIZO
发明人： SHIMOMURA MASAHITO , TSURUMAKI SHIGERU , OIKAWA EIZO
IPC分类号： C08F26/06 , C08F26/00 , C08G75/04 , C08G75/045 , G02B1/04 , G02C7/00
摘要： PURPOSE:To obtain a resin improved in refractive index, transparency and strength by subjecting a specified pyridine derivative and a dithiol to hydrogen transfer polymerization. CONSTITUTION:A diaminopyridine of formula I (wherein R and R are each H, an aliphatic group or an aromatic group) is reacted with an (alpha-substituted) acryloyl halide of formula II (wherein R is R ; and X is halogen) in the presence of an acid binder in a solvent to obtain a pyridine derivative of formula III. This derivative and an equimolar amount of a dithiol of formula IV (wherein R is an aliphatic group or an aromatic group) are subjected to hydrogen transfer polymerization at 50-100 deg.C for 10min to 100hr in an aprotic solvent to obtain a high-refractive-index resin comprising a polyaddition product comprising repeating units of formula V (wherein n is 500-5000).

2. 发明专利

JPS63171618A SEPARATION OF GASEOUS HYDROGEN 失效
公开(公告)号：JPS63171618A
公开(公告)日：1988-07-15
申请号：JP100087
申请日：1987-01-08
申请人： MITSUBISHI HEAVY IND LTD , OIKAWA EIZO
发明人： TSURUMAKI SHIGERU , SHIMOMURA MASAHITO , TSUNEYOSHI KIKUJI , OIKAWA EIZO
IPC分类号： B01D53/22 , B01D71/62
摘要： PURPOSE:To enhance the separation efficiency of gaseous H2 by using a separation membrane which is produced by adding diisocyanate to a polycondensation product of both pyridine-dicarboxylic acid or its derivative and dibasic acid dihydrazide. CONSTITUTION:Diisocyanate such as hexamethylene diisocyanate is added as a cross-linking agent to a polycondensation product of both pyridinedicarboxylic acid and/or its derivative and dibasic acid dihydrazide such as malonyldihydrazide, and the mixture is cast on a glass plate and dried, and thereby a membrane is formed. Since the membrane obtained by such a way is excellent in permselectivity of H2 and high in strength, separation of CO2 and H2 can be efficiently performed.

3. 发明专利

JPH04363123A SELECTIVELY PERMEABLE REVERSE OSMOSIS MEMBRANE AND ITS PRODUCTION 失效
公开(公告)号：JPH04363123A
公开(公告)日：1992-12-16
申请号：JP13755591
申请日：1991-06-10
申请人： OIKAWA EIZO , MITSUBISHI HEAVY IND LTD
发明人： OIKAWA EIZO , SHIMOMURA MASAHITO , TSURUMAKI SHIGERU
IPC分类号： B01D71/44 , B01D71/56 , B01D71/62
摘要： PURPOSE:To produce the selectively permeable membrane having high membrane strength and high permeation flow velocity and to assure the excellent selective permeability of expelling the transition metal salt solute in an aq. soln. and to allow the permeation of the rest by using a polycondensed high polymer having a pyridine ring and hydrazine in the main chain and polyvinyl pyridine. CONSTITUTION:The reverse osmosis membrane obtd. by dissolving a mixture composed of the polycondensation product of pyridine carboxylic acid and/or its deriv. and hydrazine with poly-4-vinyl pyridine in a soln., dissolving an inorg. salt at need therein and casting the soln. to a film, then drying the film and the process for production of this membrane.

4. 发明专利

JPS6331508A PRODUCTION OF PERMSELECTIVE MEMBRANE 失效
公开(公告)号：JPS6331508A
公开(公告)日：1988-02-10
申请号：JP17384386
申请日：1986-07-25
申请人： MITSUBISHI HEAVY IND LTD , OIKAWA EIZO
发明人： SHIMOMURA MASAHITO , TSURUMAKI SHIGERU , OIKAWA EIZO
IPC分类号： B01D71/56 , B01D71/62 , B01D71/82
摘要： PURPOSE:To improve the strength and the permeating flow velocity of the title membrane by adding the specified reinforcing cross-linking agent and permeating flow velocity increasing agent in case of forming the permselective membrane especially suitable for the selection of separation of transition metallic salt from the polycondensate of pyridine-carbozxlic acid and dibasic acid dihydrazide. CONSTITUTION:Diisocyanate is dissolved in the proportion of 6-40wt% for a polycondensate of pyridimecarboxylic acid and/or its derivative and dibasic acid dihydrazide into the soln. (3-15wt% concn. of polymer) consisting of the polycondensate as a reinforcing cross-linking agent and inorganic salt not more than 6.5wt% for the solvent of the above-mentioned soln. is dissolved as a permeating flow velocity increasing agent and this polycondensate soln. is cast and dried to form a membrane. Further hexamethylene diisocyanate or the like is used as diisocyanate and lithium chloride or the like is used as inorganic salt.

5. 发明专利

JP2013171780A Secondary battery, battery pack using the same, and thermal history storage sheet for secondary battery 审中-公开
标题翻译：二次电池，使用该电池的电池组和二次电池的热历史存储表
公开(公告)号：JP2013171780A
公开(公告)日：2013-09-02
申请号：JP2012036251
申请日：2012-02-22
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： TSURUMAKI SHIGERU
IPC分类号： H01M10/48 , H01M2/02 , H01M2/04 , H01M2/10 , H01M10/052
CPC分类号： Y02E60/122 , Y02T10/7011
摘要： PROBLEM TO BE SOLVED: To store history of abnormal heating even if a battery control system fails or does not operate, by storing the history by non-electric means when abnormal heating occurs due to overcharge or overdischarge, to confirm the history of abnormal heating at anytime thereafter, and to prevent occurrence of such a situation that the history of abnormal heating cannot be confirmed due to outside environment or secular change.SOLUTION: A secondary battery includes a battery body constituted by housing a positive electrode and a negative electrode in a battery container, and a thermal history storage sheet produced by filling a sheet-like enclosed container which is at least partially translucent with a thermosetting resin precursor material which becomes a thermosetting resin by heating and the transparency of which changes. The thermal history storage sheet is applied tightly to at least a part of the outer surface of the battery container so that the translucent part faces the outside to the battery container.
摘要翻译：要解决的问题：即使电池控制系统故障或不工作，存储异常加热的历史，通过由于过充电或过放电而发生异常加热时通过非电动方式存储历史，以确认异常加热的历史任何时候，并且防止由于外部环境或长期变化而无法确认异常加热的历史的情况的发生。解决方案：二次电池包括通过在电池中容纳正极和负极而构成的电池体容器和热历史记录纸，其通过用热成型为热固性树脂的热固性树脂前体材料填充至少部分半透明的片状封闭容器而制成，并且其透明度改变。热历史记录纸被紧密地施加到电池容器的外表面的至少一部分，使得半透明部分面向电池容器的外部。

6. 发明专利

JP2012133890A Antirust system for secondary battery 审中-公开
标题翻译：二次电池防爆系统
公开(公告)号：JP2012133890A
公开(公告)日：2012-07-12
申请号：JP2010282368
申请日：2010-12-17
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： TAGAMI NAOTO , TSURUMAKI SHIGERU , SAO TOSHIO , SAKANISHI AKIHIRO
IPC分类号： H01M10/60 , H01M10/613 , H01M10/615 , H01M10/617 , H01M10/625 , H01M10/633 , H01M10/635 , H01M10/6563 , H01M10/657
CPC分类号： Y02E60/12
摘要： PROBLEM TO BE SOLVED: To provide an antirust system for a secondary battery, which prevents the occurrence of dew condensation in a secondary battery and thus can reliably prevent the secondary battery from rusting.SOLUTION: The antirust system for a secondary battery comprises: cell temperature measuring means 14 for measuring cell temperatures of secondary cells 1 housed in a housing 10; a cooling mechanism 13 for supplying an outside air G to the peripheries of the secondary cells 1 in the housing 10 to cool the secondary cells 1; atmospheric temperature measuring means 15 for measuring atmospheric temperatures on the peripheries of the secondary cells 1, through which the outside air G passes; and control means 16 for performing control so that the atmospheric temperatures are equal to or lower than the cell temperatures.
摘要翻译：要解决的问题：为了提供二次电池的防锈系统，防止在二次电池中发生结露，从而可以可靠地防止二次电池生锈。解决方案：二次电池的防锈系统包括：用于测量容纳在壳体10中的二次电池1的电池温度的电池温度测量装置14; 用于将外部空气G供应到壳体10中的二次电池1的周边以冷却二次电池1的冷却机构13; 大气温度测量装置15，用于测量外部空气G通过的二次电池1的周边的大气温度; 以及用于进行控制使得大气温度等于或低于单元温度的控制装置16。版权所有（C）2012，JPO＆INPIT

7. 发明专利

JP2009209379A Water electrolysis apparatus 有权
标题翻译：水电解器
公开(公告)号：JP2009209379A
公开(公告)日：2009-09-17
申请号：JP2008050308
申请日：2008-02-29
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： TSURUMAKI SHIGERU , SAKANISHI AKIHIRO , KOSAKA KENICHIRO , URAKA YASUTAKA , HASHIMOTO HIDEAKI , MORI YASUSHI , KOBAYASHI YOSHINORI , HIRAYAMA YUTAKA
IPC分类号： C25B9/00 , C25B9/10
摘要： PROBLEM TO BE SOLVED: To provide a water electrolysis apparatus which can reduce its cost and improve water electrolysis performance. SOLUTION: The first water electrolysis apparatus 10A includes a water electrolysis cell 15A which includes: a polymer solid electrolyte membrane 11; a hydrogen pole catalyst layer 12A and an oxygen pole catalyst layer 13A on both sides of the polymer solid electrolyte membrane 11; and power feeders 14A for feeding an electric power to the hydrogen pole catalyst layer 12A and the oxygen pole catalyst layer 13A, which are respectively arranged on the outside of the hydrogen pole catalyst layer 12A and the oxygen pole catalyst layer 13A. A cell stack is structured by stacking a plurality of water electrolysis cells 15A while sandwiching each cell with a plurality of separator plates 16 and 16. The hydrogen pole catalyst layer 12A is made by mixing a Pt-carrying carbon catalyst 17 which carries Pt particles thereon with Pt-black particles 19. Thereby, the water electrolysis apparatus can reduce the amount of the Pt-black particles 19 used in the hydrogen pole catalyst layer 12A, and has also a water electrolysis performance equal to or more excellent than a conventional one. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供可以降低成本并提高水电解性能的水电解装置。解决方案：第一水电解装置10A包括水电解槽15A，其包括：聚合物固体电解质膜11; 高分子固体电解质膜11两侧的氢极催化剂层12A和氧极催化剂层13A; 以及分别设置在氢极催化剂层12A和氧极催化剂层13A的外侧的氢极催化剂层12A和氧极催化剂层13A供给电力的供电线路14A。电池堆叠通过在多个隔板16,16间隔堆叠多个水电解槽15A而构成。氢极催化剂层12A通过在其上携带有Pt颗粒的携带Pt的碳催化剂17混合而制成由此，水电解装置可以减少在氢极催化剂层12A中使用的Pt黑色颗粒19的量，并且还具有等于或优于常规水电解性能的水电解性能。版权所有（C）2009，JPO＆INPIT

8. 发明专利

JP2009117158A Maintenance method of solid polymer fuel cell power generation system, and solid polymer fuel cell power generation system using the same 审中-公开
标题翻译：固体聚合物燃料电池发电系统的维护方法和使用其的固体聚合物燃料电池发电系统
公开(公告)号：JP2009117158A
公开(公告)日：2009-05-28
申请号：JP2007288406
申请日：2007-11-06
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： YAMADA AKIHIKO , MORIGA TAKUYA , SATO AKIO , YAMADA TAMOTSU , ITO EIKI , TSURUMAKI SHIGERU
IPC分类号： H01M8/04 , H01M8/10
CPC分类号： Y02E60/521
摘要： PROBLEM TO BE SOLVED: To maintain for a long time suppression of deterioration of a solid polymer electrolyte without causing deterioration of power generation performance in a solid polymer fuel cell power generation system.
SOLUTION: In order to immerse cells 111 of a stack of a fuel cell body 110 into metal ion solution 3 containing at least one kind of metals out of Ce, Tl, Mn, Ag and Yb, the power generation system is provided with opening and closing valves 125, 135, 142, a storage tank 141, a supply pump 143, and three-way valves 123, 124, 133, 134 or the like which supply the metal ion solution 3 into the stack of the fuel cell body 110 during shutdown of the power generation operation.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：解决的问题：长时间保持固体聚合物电解质的劣化而不会使固体聚合物燃料电池发电系统的发电性能下降。解决方案：为了将燃料电池体110的堆叠单元111浸入含有Ce，Tl，Mn，Ag和Yb中的至少一种金属的金属离子溶液3中，提供发电系统具有将金属离子溶液3供给到燃料电池的叠层中的开闭阀125,135,142，储罐141，供给泵143以及三通阀123,124,133,134等，在发电操作关闭期间，主体110。版权所有（C）2009，JPO＆INPIT

9. 发明专利

JP2007115415A Solid polymer electrolyte membrane-electrode assembly and polymer electrolyte fuel cell using it 有权
标题翻译：固体聚合物电解质膜电极组件和聚合物电解质燃料电池
公开(公告)号：JP2007115415A
公开(公告)日：2007-05-10
申请号：JP2005302454
申请日：2005-10-18
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： ITO EIKI , TSURUMAKI SHIGERU , MORIGA TAKUYA , YAMADA AKIHIKO , YAMADA TAMOTSU , SATO AKIO
IPC分类号： H01M8/02 , H01B1/06 , H01M8/10
CPC分类号： Y02E60/521
摘要： PROBLEM TO BE SOLVED: To provide a solid polymer electrolyte membrane-electrode assembly capable of suppressing degradation of proton conductivity of a solid polymer electrolyte membrane while restraining damage of the solid polymer electrolyte membrane due to a radical. SOLUTION: This solid polymer electrolyte membrane-electrode assembly is provided with a base layer 14 arranged in the solid polymer electrolyte membrane 11 to partition the solid polymer electrolyte membrane 11 into the side of a fuel electrode layer 12 and the side of an oxidation electrode layer 13, containing at least one kind of ions out of Ce, Tl, Mn, Ag, Yb and W, comprising a porous body of at least one kind of material out of polytetrafluoroethylene (PTFE), p-phenylene-benzobisoxazole (PBO) and polyimide to have a plurality of communication holes 14a for making the fuel electrode layer 12 side and the oxidation electrode layer 13 side communicate with each other, and having a proton conducting material 14c filled in the communication holes 14a. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种能够抑制固体聚合物电解质膜的质子传导性降低的固体聚合物电解质膜 - 电极组件，同时抑制固体聚合物电解质膜由于自由基的损伤。解决方案：该固体聚合物电解质膜 - 电极组件设置有布置在固体聚合物电解质膜11中的基底层14，以将固体聚合物电解质膜11分隔成燃料电极层12的侧面包含Ce，Tl，Mn，Ag，Yb和W中的至少一种离子的氧化电极层13，其包含聚四氟乙烯（PTFE），对亚苯基 - 苯并二恶唑（PTFE）中的至少一种材料的多孔体， PBO）和聚酰亚胺，具有用于使燃料电极层12侧和氧化电极层13侧连通的多个连通孔14a，并且具有填充在连通孔14a中的质子传导材料14c。版权所有（C）2007，JPO＆INPIT

10. 发明专利

JP2006216285A Solid polymer electrolyte membrane, solid polymer electrolyte membrane electrode assembly, and solid polymer electrolyte fuel cell 有权
标题翻译：固体聚合物电解质膜，固体聚合物电解质膜电极组件和固体聚合物电解质燃料电池
公开(公告)号：JP2006216285A
公开(公告)日：2006-08-17
申请号：JP2005025888
申请日：2005-02-02
申请人： Mitsubishi Heavy Ind Ltd , 三菱重工業株式会社
发明人： WATANABE SATORU , YASHIMA YOSHIMI , TOYODA ICHIRO , KANEKO MASAHITO , TSURUMAKI SHIGERU , ITO EIKI , YAMADA AKIHIKO , SATO AKIO , HORI KEIICHI
IPC分类号： H01M8/02 , H01M8/10
CPC分类号： Y02E60/521
摘要： PROBLEM TO BE SOLVED: To provide a solid polymer electrolyte membrane high in durability to a hydroxy radical even in operation attendant on every day starting and stopping, operation attendant on load following operation, or low humidifying condition, to provide a solid polymer electrolyte membrane electrode assembly using this, and to provide a solid polymer electrolyte fuel cell. SOLUTION: In the solid polymer electrolyte membrane-electrode assembly 10 in which a fuel electrode membrane 12 is arranged on one surface of the solid polymer electrolyte membrane 11 and an oxidizing electrode membrane 13 is arranged on the other surface, a conductive material is included in the solid polymer electrolyte membrane 11 in the solid polymer electrolyte membrane electrode assembly 10. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：为了提供即使在每天启动和停止的操作中对羟基自由基的耐久性高的固体聚合物电解质膜，伴随操作的加载操作或低加湿条件的操作，以提供固体聚合物使用这种电解质膜电极组件，并提供固体聚合物电解质燃料电池。解决方案：在固体聚合物电解质膜11的一个表面上设置有燃料电极膜12和氧化电极膜13的固体高分子电解质膜 - 电极组件10中，在导电材料包含在固体高分子电解质膜电极组件10中的固体高分子电解质膜11中。（C）版权所有（C）2006，JPO＆NCIPI

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