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    • 1. 发明专利
    • SOOT BLOWING METHOD
    • JPS5676227A
    • 1981-06-23
    • JP15314179
    • 1979-11-27
    • MITSUBISHI HEAVY IND LTD
    • SHIRAISHI YOSHIHIROKUBO KIYOUJIHANEDA MICHIOSUZUMURA HIROSHI
    • B01D53/94B08B5/02F23J3/00F23J3/02
    • PURPOSE:To produce an effective removal effect in a subject method which removes solid adhered to a catalyst bed by the aid of air current flowing at a rapid speed into an exhaust gas denitrating device by providing a long slit nozzle throughout almost a full length of an injection pipe, and injecting a continuous air stream therefrom. CONSTITUTION:Denitration catalyst beds 1, 1' consist of catalyst blocks having a honeycomb-shaped perforation, and gas to be treated is exhausted through an outlet 9 after it passes through the catalyt bed 1, 1' successively. A part of solid, contained in the exhaust gas 3, adheres to the inlet edge surfaces and catalyst surfaces 2. A soot blow device, which is fitted into a guide material 13 and in which an injection pipe 10 can move in the direction of an arrow mark 8 parallel to the catalyst bed, is mounted in front of the catalyst bed. A pressurized air supplied from a feed pipe 6 is jetted to the catalyst surface through a slit nozzle 7 formed in the injection pipe 10 to remove extraneous matter. In this method, the pressurized air is injected uniformly, whereby the injection pipe can approach closer to the catalyst surface and the consumption amount of air can be reduced.
    • 4. 发明专利
    • CATALYST PACKAGED TO RECTANGULAR PARALLELEPIPED
    • JPS5684621A
    • 1981-07-10
    • JP16192279
    • 1979-12-13
    • MITSUBISHI HEAVY IND LTD
    • HONDA MICHIYASUSHIRAISHI YOSHIHIROSETO TOORU
    • B01D53/86B01J19/24B01J35/04F01N3/28F01N13/04
    • PURPOSE:To prevent the deviation of catalysts at the time of filling and removing and decrease their damages by mounting L-shaped heat-resistant packings to the side edge parts of the gas passage holes of the catalysts, fixing the same by means of retaining fittings from the outer side of the packing material of single catalysts. CONSTITUTION:Heat-resistant packings 2 of an L-shape formed by ''Kaowool '', asbestos, etc. are disposed on the upper stream side and lower stream side of the gas passage surfaces of single catalyst layers 1, and the catalysts 1 and heat-resistant packings 2 are alternately combined and stacked, whereby these are packaged into one body. Further, retaining fittings 4 are applied from the outer side of the packing materials 2 at said side edge parts on at least one side of the gas inlet side or outlet side of the gas passage surfaces of the single catalysts and the fittings 4 are fixed to a frame structural body 5. The packings 2 are used at about 2-3mm. thicknesses corresponding to the thickness of the outside wall part of the catalysts in order to provide protection to the end face parts of the catalysts 1 and prevent the deviation of the catalysts in the direction perpendicular to the gas flow 3.
    • 6. 发明专利
    • CLEARING OF DUST IN SOLIDDGAS CATALYTIC REACTOR
    • JPS5676238A
    • 1981-06-23
    • JP15268479
    • 1979-11-26
    • MITSUBISHI HEAVY IND LTD
    • HANEDA MICHIOSHIRAISHI YOSHIHIROHINO MASAOSETO TOORU
    • B01J8/02F23J3/00F28G1/16
    • PURPOSE:To economically and effectively remove deposition, accomulation and bridge formation in a packed layer by specifying the distance between gas jet nozzles and the packed layer to be from 0.2-10m and the gas flow velocity at the inlet section of packing material during the gas injection to 5-40m/sec. CONSTITUTION:The distance between the solid-gas catalytic packed layers 2 packed with a filling material having a plurality of gas passages extending in a gas flow direction and the nozzles 4 from which the gas introduced from outside of the system is jetted is regulated to 0.2-10m; the flow velocity of the gas when jetted at the injet section of the packing material is 5-40m/sec., and while the jetting position of the gas jet nozzles 4 is fixed or moved by directing toward the packed layer 2 and the packed layer surfaces at their inlet or outlet sides, the gas is jetted from the gas jet nozzles 4 to remove the dust deposition 6 or the like. Each of the packed layers 2 is made of a packing material having gas passages in the form of a lattice, honeycomb or the like, and a plurality of such packed layer 2 are package and arranged to be supported by the outside wall of the duct for the packing material.
    • 7. 发明专利
    • CONTROLLING METHOD FOR AMMONIA INJECTION AT DRY PROCESS EXHAUST GAS DIEITRATION METHOD
    • JPS5499771A
    • 1979-08-06
    • JP583578
    • 1978-01-24
    • MITSUBISHI HEAVY IND LTD
    • SHIRAISHI YOSHIHIROUGAWA NAOHIKO
    • B01D53/56B01D53/74B01D53/86F23J15/00
    • PURPOSE:To seek for the most suitable injection quantity of NH3, by building in the operator preliminary memorized NOx quantity from the relation of the value showing combustion quantity of each flow etc., such as fuel or combustion air and generated NOx concentration and also, the operator memorized NH3/NOx ratio from the relation of exhaust gas temperature and denitration capacity. CONSTITUTION:The fuel A passed through the flowmeter 1, is burnt in the combustion apparatus B and generated exhaust gas containing NOx, is induced to the denitration apparatus D accompanying NH3 15. Radio of NH3/NOx is preliminary found by the relation of the temperature of exhaust gas C' and denitration capacity and is memorized in the operator II of the mark 4. On the one hand, signal of the flowmeter 1 or feeding quantity of water of the apparatus B or steam generating quantity signal 1-1, is transmitted to the multiplier 10 as the NOx quantity signal 2-1, by the operator of the mark 2 memorized by preliminary functioning the product of the fuel or air flowing amount for combustion and flowing amount of the exhaust gas and also, NOx concentration. The signal 3-1 of the exhaust gas temperature detector 3 is made the NH3/NOx specific signal 4-1 by the operator II (4) and the above signal is transmitted to the multiplier 10 directly or passing through the operator 5.
    • 9. 发明专利
    • Controlling method of ph
    • PH控制方法
    • JPS59102424A
    • 1984-06-13
    • JP21040282
    • 1982-11-30
    • Mitsubishi Heavy Ind Ltd
    • OKINO SUSUMUFUKUMOTO KATSUTOSHISHIRAISHI YOSHIHIROTAKEDA HIROSHIATSUMI TOSHIKAZU
    • B01D53/50B01D53/34B01D53/77C02F1/66C02F1/68
    • PURPOSE: To maintain stably the pH value of the liquid discharged from an oxidation column by controlling the amt. of the sulfuric acid to be introduced into the oxidation column in accordance with the control signal obtd. by arithmetic processing from the flow rate signal for the liquid to be oxidized, the pH signal of the liquid discharged from the oxidation column and an adjustment signal for the deviation of pH.
      CONSTITUTION: The amt. of the sulfuric acid to be introduced into an oxidation column 2 is controlled in accordance with the control signal ϕ for the amt. of the sulfuric acid to be supplied obtd. by the arithmetic processing using the equation by an arithmetic device 22 from the opening signal X of a control valve 16 for a flow rate controller for the liquid to be oxidized, the pH signal Y obtd. by measuring the liquid discharged from the oxidation column 2 with a pH meter 19, and the control signal Z of a controller 20 for the deviation of pH to which the pH value is inputted, in a wet type stack gas desulfurizer of a lime method which introduces waste gas contg. SO
      2 through a duct 6 into a desulfurization column 1, desulfurizes the same by spraying a circulating lime slurry therein, introduces part of said slurry as the liquid to be oxidized into the column 2 and produces gypsum by oxidizing the same with gas contg. sulfuric acid and oxygen contg. gas in said column. The pH of the liquid discharged from the column 2 is stably maintained even while load fluctuates and the recovery of gypsum having a high grade is made possible.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:通过控制amt来稳定从氧化柱排出的液体的pH值。 的根据控制信号被引入氧化柱的硫酸。 通过从待氧化液体的流量信号的算术处理,从氧化塔排出的液体的pH信号和pH偏差的调节信号。 规定: 根据amt的控制信号phi来控制要引入氧化柱2的硫酸。 的供应硫酸。 通过运算装置22根据用于待氧化液体的流量控制器的控制阀16的开启信号X的运算处理,得到pH信号Y。 通过用pH计19测量从氧化塔2排出的液体,以及控制器20的控制信号Z,用于输入pH值的pH的偏差,在酸式方法的湿式烟道气脱硫器中 引进废气 SO2通过管道6进入脱硫塔1,通过在其中喷洒循环的石灰浆料对其进行脱硫,将作为待氧化液体的所述浆料的一部分引入塔2中,并通过用气体保护剂氧化石膏来生产石膏。 硫酸和氧气不足 所述柱中的气体。 即使在负荷波动的情况下,也能稳定地保持从塔2排出的液体的pH,能够回收高等级的石膏。