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    • 3. 发明专利
    • Heat-conducting elastomer and cross-linking agent
    • 导热弹性体和交联剂
    • JP2009040945A
    • 2009-02-26
    • JP2007209376
    • 2007-08-10
    • Kyushu Refract Co LtdTakechi:Kk九州耐火煉瓦株式会社株式会社タケチ
    • MATSUURA OSAMUYASUMOTO KOJITAKECHI YOSHIKAHORIUCHI KENTARO
    • C08L101/12C08K3/00C08K3/02C08K3/04C08K3/08
    • PROBLEM TO BE SOLVED: To provide a heat-conducting elastomer having high electrical resistance and high heat conductivity.
      SOLUTION: The heat-conducting elastomer is composed a polymer 10 having rubber elasticity, a cross-linking agent 12 comprising primary particles of graphite or primary particles of composite graphite containing graphite and a metal element, which particles mutually link and constitute aggregates when the agent 12 is added in the polymer 10, and a powdery heat-conducting filler 11 having thermal conductivity higher than that of the polymer 10 and electrical resistance higher than that of the primary particles. The average particle diameter of the heat-conducting filler 11 is larger than that of the aggregates, and the cross-linking agent 12 is stretched between mutually adjacent particles of the heat-conducting filler 11, and thereby, the thermal conductivity of the elastomer becomes higher than that of the elastomer free from the cross-linking agent 12.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供具有高电阻和高导热性的导热弹性体。 解决方案:导热弹性体由具有橡胶弹性的聚合物10构成,交联剂12包含一次石墨颗粒或含有石墨和金属元素的复合石墨的一次颗粒,该颗粒相互连接并构成聚集体 当将试剂12加入到聚合物10中时,以及导热性高于聚合物10的导热性的粉末状导热性填料11,并且电阻比初级粒子高。 导热性填料11的平均粒径大于聚集体的平均粒径,并且交联剂12在导热性填料11的相邻颗粒之间被拉伸,由此,弹性体的导热率变得 高于不含交联剂12的弹性体。版权所有(C)2009,JPO&INPIT
    • 4. 发明专利
    • Baking tool material, and method for manufacturing the same
    • 烘焙工具材料及其制造方法
    • JP2012017929A
    • 2012-01-26
    • JP2010156240
    • 2010-07-08
    • Kyushu Refract Co Ltd九州耐火煉瓦株式会社
    • TANAKA HIROAKINAKAMURA HIROSHIMATSUURA OSAMUKONO KOJI
    • F27D3/12C04B35/64C04B41/87
    • PROBLEM TO BE SOLVED: To provide a baking tool material having excellent mechanical strength and high adhesiveness of a base material to a thermal-sprayed layer.SOLUTION: The baking tool material includes a thermal-sprayed layer containing at least one to be selected from zirconia or a zirconate on a surface of an alumina-based or alumina-silica-based base material. The baking tool material satisfies the inequalities (1) dp≥750 and (2) vp≥0.007, and the base material thereof has the bending strength of ≥25 MPa, where dp denotes the peak pore diameter (nm) in the pore diameter distribution of the base material measured by the mercury penetration technique, and vp denotes the difference pore volume (ml/g) in the peak pore diameter dp, respectively.
    • 要解决的问题:提供一种具有优异的机械强度和基材对热喷涂层的高粘合性的烘烤工具材料。 解决方案:烘烤工具材料包括在氧化铝基或氧化铝 - 二氧化硅基基材的表面上含有至少一种选自氧化锆或锆酸酯的热喷涂层。 烘焙工具材料满足不等式(1)dp≥750和(2)vp≥0.007,其基材的弯曲强度为≥25MPa,其中dp表示孔径分布中的峰值孔径(nm) 通过水银渗透技术测定的基材,vp分别表示峰值孔径dp的差孔容积(ml / g)。 版权所有(C)2012,JPO&INPIT
    • 6. 发明专利
    • STOPPER HEAD HAVING HIGH DURABILITY
    • JP2000042726A
    • 2000-02-15
    • JP20995198
    • 1998-07-24
    • KYUSHU REFRACTORIESNIPPON STEEL CORP
    • IMAGAWA HIROSHIMATSUO SABUROUCHIDA MINEOMATSUURA OSAMU
    • B22D11/10B22D41/18C04B41/89
    • PROBLEM TO BE SOLVED: To prolong the durable service life by forming a zirconia thermal spraying film on the surface of materials composed of a refractory material and a carbonaceous material and forming a zirconia coating film on the surface of the thermal spraying layer. SOLUTION: The thermal spraying layer having good stickiness is formed on the surface of a base material and on this surface, further thick coating layer is formed to form a stopper head having high durability. In this way, the oxidizing resistance and the wear resistance to molten metal as the weak points in the carbonaceous stopper head can be improved. Since the stickiness is weaked in the coating layer, there is a danger of peeling, but since the stickiness is strong in the thermal spraying layer, the peeling is difficult to develop. On the other hand, in the case of arranging the coating layer on the surface of the thermal spraying layer, since the stickiness is strong by using the same material or the similar material to the coating layer and the thermal spraying layer and there is no difference of the thermal expansion between both layers, a problem of the peeling as the whole body of the stopper head is eliminated. As the base material, an acidic material of silica, etc., a neutral material of alumina, etc., a basic material of magnesia, etc., and a non-oxidizing material of silicon carbide, silicon nitride, etc., are combined.