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    • 6. 发明专利
    • Urethane (meth)acrylate having fluorene skeleton, and its cured material
    • 具有氟橡胶的URETHANE(METH)丙烯酸酯及其固化材料
    • JP2013108091A
    • 2013-06-06
    • JP2013029659
    • 2013-02-19
    • Osaka Gas Co Ltd大阪瓦斯株式会社
    • MIYAUCHI SHINSUKEYAMADA MASAHIROMURASE HIROAKIKAWASAKI SHINICHISAMURA TETSUYAMORI RIEHANASAKA FUMIHIRO
    • C08G18/67C08F299/06
    • PROBLEM TO BE SOLVED: To provide a novel (meth)acrylate excellent in flexibility and simultaneously satisfying both properties such as high refractive index and high heat resistance, and excellent flexibility.SOLUTION: A urethane (meth)acrylate is obtained by using as reaction components: a diol having a fluorene skeleton (for example, 9,9-bis(hydroxyl(poly)Calkoxyphenyl)fluorene and 9,9-bis(mono or diCalkyl-hydroxy(poly)Calkoxyphenyl)fluorene), a specific polyisocyanate compound having a polyol skeleton and terminal isocyanate groups (for example, a urethane prepolymer made by reacting a diol compound such as an alkanediol or a polyetheric diol with a diisocyanate compound, and having isocyanate groups on both terminals), and a (meth)acrylic compound having a reactive group with the isocyanate group (for example, a hydroxyalkyl (meth)acrylate).
    • 要解决的问题:提供一种柔软性优异的新型(甲基)丙烯酸酯,同时满足高折射率,高耐热性等优异的柔软性。 解决方案:通过使用作为反应成分的聚氨酯(甲基)丙烯酸酯:具有芴骨架的二醇(例如,9,9-双(羟基(聚)C 烷氧基苯基)芴),具有多元醇骨架和末端异氰酸酯基团的特定多异氰酸酯化合物(例如,通过使二醇化合物如烷二醇或聚醚二醇与二异氰酸酯化合物反应制备的氨基甲酸酯预聚物, 两端的异氰酸酯基)和具有与异氰酸酯基具有反应性基团的(甲基)丙烯酸化合物(例如,(甲基)丙烯酸羟烷基酯)。 版权所有(C)2013,JPO&INPIT
    • 7. 发明专利
    • Method for manufacturing metallic particle utilizing solvothermal reaction
    • 制造使用溶胶热反应的金属颗粒的方法
    • JP2013053365A
    • 2013-03-21
    • JP2012070745
    • 2012-03-27
    • Osaka Gas Co Ltd大阪瓦斯株式会社
    • KAWASAKI SHINICHITAKEMOTO TETSUYASAKAMOTO HIRONORIHANASAKA FUMIHIROONAKA JUNKO
    • B22F9/24B22F9/20C22B3/20C22B7/00C22B23/06
    • Y02P10/234
    • PROBLEM TO BE SOLVED: To manufacture metallic particles efficiently by a solvothermal reaction from a mixed solution including a plurality of metallic ions.SOLUTION: A method uses a mixed solution including ions of metal (a) and ions of metal (b) that is different from the metal (a). In the method, metallic particles (A) of the metal (a) are produced by reducing ions of the metal (a) by a following process (1) or a process (2). The process (1) includes steps of: separating ions of the metal (a) from the mixed solution; converting the metal (a) to a metal hydroxide; subjecting the metal hydroxide to solvothermal reaction under the presence of an organic solvent (C1) that can reduce ions of the metal (a); and producing the metallic particles (A). The process (2) includes steps of: subjecting the mixed solution to a solvothermal reaction under the presence of an organic solvent (C2) that can reduce ions of the metal (a) and does not reduce ions of the metal (b); and producing the metallic particles (A).
    • 要解决的问题:通过包含多种金属离子的混合溶液的溶剂热反应有效地制造金属颗粒。 解决方案:一种方法使用包含金属(a)的离子和金属(b)的不同于金属(a)的离子的混合溶液。 在该方法中,金属(a)的金属颗粒(A)通过以下方法(1)或方法(2)还原金属(a)的离子来制备。 方法(1)包括以下步骤:将金属(a)的离子与混合溶液分离; 将金属(a)转化为金属氢氧化物; 在可以还原金属(a)的离子的有机溶剂(C1)的存在下使金属氢氧化物进行溶剂热反应; 并生成金属颗粒(A)。 方法(2)包括以下步骤:在可以减少金属离子(a)的有机溶剂(C2)存在下使混合溶液进行溶剂热反应,并且不会减少金属(b)的离子。 并生成金属颗粒(A)。 版权所有(C)2013,JPO&INPIT
    • 8. 发明专利
    • Fluorene based composition and molded product of the same
    • 基于氟的组合物及其成型产品
    • JP2013010971A
    • 2013-01-17
    • JP2012229505
    • 2012-10-17
    • Osaka Gas Co Ltd大阪瓦斯株式会社
    • YAMADA MASAHIROKAWASAKI SHINICHIMURASE HIROAKIFUJIKI TAKESHISAKAMOTO HIRONORISAKAMOTO KANATANAKA MASASHIHIGASHIYAMA MASARUYAMADA MITSUAKISUDA YASUHIRO
    • C08L67/00C08G63/197C08K3/04
    • PROBLEM TO BE SOLVED: To obtain a fluorene based composition having excellent dispersibility of an additive and capable of making the additive exhibit the function of the additive by mixing of a small amount of the additive, and the molded product of the same.SOLUTION: The fluorene based composition containing a compound expressed by formula (1) or its derivative and the additive is prepared, and the molded product is formed by using the composition. [In the formula, Xand Xare identical to or different from each other and are each a hydroxyl group, -O(AO)H group (in the formula, A is a 2-3C alkylene group and (p) is an integers of ≥1), amino group or N-monosubstituted amino group, R-Rare identical to or different from each other and are each a non-reactive group, and m1 and m2 are identical to or different from each other and are each 0 or an integer of 1-3, and (m1+m2) is an integer of 1-6, n1-n4 are identical to or different from each other and are each an integer of 0-4, where, (m1+n1) and (m2+n2) are each an integer of 0-5].
    • 要解决的问题:为了获得具有优异的添加剂分散性并能够通过混合少量添加剂及其模塑产品而使添加剂显示出添加剂功能的芴基组合物。 解决方案:制备含有由式(1)表示的化合物或其衍生物和添加剂的基于芴的组合物,并使用该组合物形成模塑产品。 [在该式中,X 1 和X 2 彼此相同或不同,并且各自为羟基, O(AO) p H基(式中,A为2-3C亚烷基,(p)为≥1的整数),氨基或N-单取代 氨基,R 1 -R 4 彼此相同或不同,各自为非反应性基团, m1和m2彼此相同或不同,分别为0或1-3的整数,(m1 + m2)为1-6的整数,n1-n4彼此相同或不同,为 每个为0-4的整数,其中,(m1 + n1)和(m2 + n2)均为0-5的整数]。 版权所有(C)2013,JPO&INPIT
    • 10. 发明专利
    • Cellulose-based resin composition
    • 基于纤维素的树脂组合物
    • JP2012211253A
    • 2012-11-01
    • JP2011077447
    • 2011-03-31
    • Osaka Gas Co Ltd大阪瓦斯株式会社
    • YAMADA MASAHIROKAWASAKI SHINICHISOJO DAISAKUWAKABAYASHI KANJILIN LIANZHEN
    • C08L1/00C08K5/13C08L1/12C08L69/00C08L101/00
    • PROBLEM TO BE SOLVED: To provide a resin composition obtained by plasticizing a cellulose-based resin having poor meltability or solvent solubility and compounding the same with a non-cellulose-based thermoplastic resin.SOLUTION: The resin composition is composed of a cellulose-based resin (especially a cellulose ester, such as cellulose triacetate), a non-cellulose-based thermoplastic resin, and a fluorene compound having a 9,9-bisarylfluorene skeleton. In such a composition, the ratio of the cellulose-based resin to the non-cellulose-based thermoplastic resin may be approximately, for example, the former/the latter=97/3 to 50/50 (weight ratio), and the ratio of the fluorene compound may be approximately, for example, 1-25 pts.wt. relative to 100 pts.wt. of the cellulose-based resin.
    • 要解决的问题:提供通过使具有差的熔融性或溶剂溶解性的纤维素类树脂增塑而得到的树脂组合物,并与非纤维素类热塑性树脂混合。 解决方案:树脂组合物由纤维素类树脂(特别是纤维素酯,如三乙酸纤维素),非纤维素类热塑性树脂和具有9,9-双芳基芴骨架的芴化合物组成。 在这种组合物中,纤维素系树脂与非纤维素类热塑性树脂的比例可以为例如前者/后者= 97/3〜50/50(重量比),比例 的芴化合物可以约为例如1-25重量份。 相对于100 pts.wt 的纤维素类树脂。 版权所有(C)2013,JPO&INPIT