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1. 发明专利

JPH08238718A PRECOATED LAMINATE SUITABLE FOR PRESS MOLDING, ITS MANUFACTURE, AND PRESS-MOLDED CONTAINER WITH INTERNAL-SURFACE COATING 失效
公开(公告)号：JPH08238718A
公开(公告)日：1996-09-17
申请号：JP31457795
申请日：1995-12-01
申请人： KISHIMOTO AKIRA
发明人： AIZAWA MASANORI , SASAKI HIROSHI , MOCHIDA TAKAAKI , KOBAYASHI SEISHICHI , HIROTA KAZUSANE
IPC分类号： B65D1/00 , B05D7/14 , B32B15/08 , B32B15/082 , B65D1/09 , C08L63/00 , C08L79/08 , C09D5/00 , C09D127/12
摘要： PURPOSE: To obtain a laminate which is capable of being drawn in a high ratio of height/bore, with high heat resistance and impact proofness after molding by providing a primer layer containing a heat-resistant resin and a fluororesin, each having an imide bond in a molecular chain, on one surface of a metal substrate. CONSTITUTION: A laminate 1 is composed of a metal substrate 2, a primer layer 3 provided on the surface of the metal substrate and an overcoat layer 4 formed on the primer layer. The primer layer 3 is composed of a composition containing a heat-resistant resin and a fluororesin, each having an imide bond in a molecular chain, or, additionally an epoxy resin. A top coat layer 4 is formed of the fluororesin. An anchorage boundary 5 is present between the primer layer 3 and the top coat layer 4. A foundation layer and a top layer which is continuous to the former and an anchorage structure present between both are molded all at once by forming a film of fluororesin particles and curing a precursor polymer simultaneously.

2. 发明专利

JPH1176930A PRODUCTION OF PRINTING CAN 失效
公开(公告)号：JPH1176930A
公开(公告)日：1999-03-23
申请号：JP24435697
申请日：1997-09-09
申请人： KISHIMOTO AKIRA
发明人： GOTO HIROAKI , SASAKI HIROSHI , OTSUKA SHINYA
IPC分类号： B65D1/00 , B05D7/14 , B65D1/09 , B65D1/12
摘要： PROBLEM TO BE SOLVED: To provide a production method of a printing can hardly causing a scattering of mist even at a high speed printing, excellent in workability, and moreover excellent in brightness of a formed printing image, improved in product value, excellent in hardness and adhesion of a coating film, moreover excellent in workability such as neck-in processing. SOLUTION: In the printing method of a two-piece can, after the printing is executed by using a thermosetting ink on an outer surface of the two-piece can, a finishing vanish providing an ultraviolet curing property and a heat curing property is applied by a wet-on-wet system, then a partial curing of the finishing vanish is executed by UV ray irradiation, moreover, the ink and the finishing vanish are completely cured by a heat baking.

3. 发明专利

JPH1179174A PRINTED SEAMLESS CAN AND ITS MANUFACTURE 失效
公开(公告)号：JPH1179174A
公开(公告)日：1999-03-23
申请号：JP24435797
申请日：1997-09-09
申请人： KISHIMOTO AKIRA
发明人： GOTO HIROAKI , SASAKI HIROSHI , MOROFUJI AKIHIKO , OTSUKA SHINYA , YUGAWA YASUHIRO
IPC分类号： B65D8/00
摘要： PROBLEM TO BE SOLVED: To provide a printed seamless can and its manufacture, in which roughness at lap application parts and the distortion of printed images, or the deterioration of gloss, due to steps are eliminated, and which is excellent in the fine appearance of a printed part and in a commodity value in the printed seamless can having a printed ink layer provided on an outer surface thereof and a finish varnish layer provided on the printed ink layer, whose finish varnish layer contains an ultraviolet-curable resin and has, in the circumferential direction of a can body, a single application part and lap application parts at narrow intervals. SOLUTION: This printed seamless can has a printed ink layer 4 provided on an outer surface of the can and a finish varnish layer provided on the printed ink layer 4. The finish varnish layer contains an ultraviolet-curable resin and has, in the circumferential direction of a can body, a single application part and lap application parts at narrow intervals. The degree of surface roughness of the lap application parts of the finish varnish layer is at most 0.3 μm and moreover is controlled to a degree less than double of that of the single application part.

4. 发明专利

JPH10230212A COATED STRUCTURE 失效
公开(公告)号：JPH10230212A
公开(公告)日：1998-09-02
申请号：JP3235997
申请日：1997-02-17
申请人： KISHIMOTO AKIRA
发明人： GOTO HIROAKI , SASAKI HIROSHI , MOROFUJI AKIHIKO , OTSUKA SHINYA
IPC分类号： B65D1/12 , B05D5/00 , B05D5/06 , B05D7/14 , B05D7/24
摘要： PROBLEM TO BE SOLVED: To prevent a coating film from a damage such as peeling by applying a coating material containing resin particulates in a specified wt.% so that a part of the particulates may be embedded in the coating film and remainder may be projected from a surface of the coating film, and curing the coating material by ultraviolet ray. SOLUTION: 2-10wt.% Resin particulates are incorporated in the ultraviolet curing type coating material. Then a part of the particulates is embedded in the coating film and remainder is allowed to protrude from the surface of the coating film and cured by the ultraviolet ray. An average grain size of the resin particulates is kept in 5-15μm, and a smooth part of the cured coating film is kept in 0.5-1 time thickness of the average grain size of the resin particulates. For example, a resin other than resin particulates, reactive diluent, oligomer and monomer are blended and dissolved. Moreover, lubricants, an initiator, sensitizer, titanium oxide and 2-10wt.% resin particulates are added to produce the ultraviolet curing type coating material. The coating film having a coefficient of dynamic friction of about 0.10 is obtained in the case when the coating material is applied and cured by ultraviolet ray and the peeling is prevented and a resistance to scuffing is improved.

5. 发明专利

JPH09103833A MANUFACTURE OF PRINTED CAN HAVING EXCELLENT DESIGN CHARACTERISTIC 失效
公开(公告)号：JPH09103833A
公开(公告)日：1997-04-22
申请号：JP26163495
申请日：1995-10-09
申请人： KISHIMOTO AKIRA
发明人： GOTO HIROAKI , SASAKI HIROSHI , KOBAYASHI SEISHICHI , OTSUKA SHINYA , YUGAWA YASUHIRO , WATANABE YOSHIKI
IPC分类号： B65D1/16 , B05D7/14 , B21D51/26 , B65D8/16 , B65D25/34
摘要： PROBLEM TO BE SOLVED: To make it possible to form printed layers satisfying all of workability, heat resistance, wear resistance, brightness, etc., by curing specific ink and coating materials by irradiation with UV rays, then executing various kinds of the moldings necessary for maintaining designs and strength, subjecting molded cans to a short time of heat treatment to thermally cure the UV curing films. SOLUTION: The ink and coating materials having a UV curing property and thermosetting property in combination or the ink and coating materials which has the UV curing property and is imparted with the thermosetting property by irradiation with UV rays is selectively used as the ink and coating material. Various kinds of the moldings, such as neck forming or bead forming of the printed cans, necessary for maintaining the designs and strength are then executed, but before such molding, the curing of the ink and the coating materials by the irradiation with the UV rays, is executed and, after such molding, the molded cans are subjected to the short time of the heat treatment to thermally cure the UV curing films. Then, the printed layers have the excellent heat resistance, wear resistance, etc., and withstand the retort sterilization and the collision and rubbing of the cans against each other.

6. 发明专利

JPH107122A SEAMLESS CAN AND MANUFACTURE THEREOF 失效
公开(公告)号：JPH107122A
公开(公告)日：1998-01-13
申请号：JP15828896
申请日：1996-06-19
申请人： KISHIMOTO AKIRA
发明人： AIZAWA MASANORI , GOTO HIROAKI , SASAKI HIROSHI , OTSUKA SHINYA
IPC分类号： B65D1/16 , B21D22/30 , B21D51/26 , B65D8/16
摘要： PROBLEM TO BE SOLVED: To improve the impact resistance and the corrosion resistance after a formed can for which a printing and a secondary process have been applied by a method wherein a plurality of oriented crystalization states being shown by specified endothermic peaks in a differential thermal analysis, are imparted to a polyester layer on the internal surface of the can, and a spontaneous stretching property is imparted to a polyester layer straight under the flange part. SOLUTION: A laminate plate 1 wherein at least on the internal surface of a metal plate 2, a biaxially oriented polyester film 3 is laminated by a condition to remain the biaxial orientation, is draw-iron-molded, and is formed into a can body wherein the polyester layer 3 is uniaxially oriented, and a heat treatment is performed by a temperature which is -60 to -5 deg.C of the melting point of the polyester. Then, a printing is applied on the external surface of the can body with an ultra-violet ray hardening type ink, and the ink is hardened by irradiating ultra-voilet rays. Then, the printed can body is secondarily molded, and a post-heat treatment is performed by a temperature which is +100 to 150 deg.C of the glass transition point of the polyester. By this method, three kinds of oriented-crystalization states corresponding with specified three endothermic peaks in a differential thermal analysis, and internally distorted state are realized on the polyester layer 3.

7. 发明专利

JPH0931144A ULTRAVIOLET-CURABLE RESIN COMPOSITION AND LAMINATE USING SAME 失效
公开(公告)号：JPH0931144A
公开(公告)日：1997-02-04
申请号：JP17782995
申请日：1995-07-13
申请人： KISHIMOTO AKIRA
发明人： GOTO HIROAKI , KOBAYASHI SEISHICHI , SASAKI HIROSHI
IPC分类号： B32B27/16 , C08F290/00 , C08F290/06 , C08G59/17
摘要： PROBLEM TO BE SOLVED: To obtain an ultraviolet-curable resin compsn. which is excellent in applicability and ultraviolet curability and gives a cured resin layer excellent in processibility, adhesive properties, and resistance to retort sterilization by using a specific acrylic epoxy resin. SOLUTION: This compsn. contains a monofunctional acrylic monomer and an acrylic epoxy resin mainly comprising a component represented by the formula (wherein R is H or methyl; ϕ and ϕ are each phenylene; and (n) is 2-9). In the acrylic epoxy resin, 20-50mol% of phenylene-methylene-phenylene (-ϕ -CH2 -ϕ ) bonds are pref. para-para bonds; esp. pref. 15-19mol% are ortho- ortho bonds, 48-52mol% ortho-para bonds, and 29-37mol% are para-para bonds. Pref. the wt. ratio of the acrylic epoxy resin to the monofunctional acrylic monomer in the compsn. is (80:20)-(20:80).

8. 发明专利

JPH10195281A ULTRAVIOLET-CURING TYPE RESIN COMPOSITION, EXTERIOR COATING MATERIAL FOR PACKAGING CONTAINER AND EXTERIOR-COATED CAN 失效
公开(公告)号：JPH10195281A
公开(公告)日：1998-07-28
申请号：JP242597
申请日：1997-01-09
申请人： KISHIMOTO AKIRA
发明人： GOTO HIROAKI , SASAKI HIROSHI , KOBAYASHI SEISHICHI
IPC分类号： C08L63/02 , C08F16/18 , C08G59/40 , C09D5/00 , C09D163/02
摘要： PROBLEM TO BE SOLVED: To obtain the subject composition useful, e.g. as a coating for packaging container exteriors, excellent in ultraviolet-curability, and processability, toughness and adhesion after being cured by incorporating an OH-containing ethylene-based unsaturated monomer and bisphenol F type epoxy resin. SOLUTION: This composition comprises (A) a photocationic polymerization initiator, e.g. sulfonium salt, (B) a photocationic polymerizable epoxy-based monomer, e.g. an alicyclic epoxy compound, (C) an organic silicone-based resin, (D) an OH-containing ethylene-based unsaturated monomer, e.g. a compound shown by formula I (R is H or a lower alkyl; Y is a 2-6C alkylene; and (n) >=1), and (E) a bisphenol F type epoxy resin having at least 3,000 epoxy equivalents, e.g. an epoxy resin composed of a repeating unit shown by formula II (Φ is phenylene; and (m) is a number that gives 3,000 to 5,000 epoxy equivalents). The composition preferably contains the components D and E each at 5 to 15wt.%.

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