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    • 2. 发明专利
    • THINNED SEAMLESS CAN
    • JPH08119285A
    • 1996-05-14
    • JP26062894
    • 1994-10-25
    • KISHIMOTO AKIRA
    • GOTO HIROAKIKOBAYASHI SEISHICHIOTSUKA SHINYAWATANABE YOSHIKIYUGAWA YASUHIRO
    • B65D1/16B21D51/18B21D51/26B32B15/08B65D25/34C09D7/12C23C30/00
    • PURPOSE: To increase the anticorrosition property and external appearance, by providing an ultraviolet ray setting coating layer mixed with titanium oxide with a specified thickness on the external face film layer at the side wall of a metallic material and setting the total amount of titanium oxide per unit area of the side wall of external face at least in a specified value. CONSTITUTION: In a thinned seamless can 1, the metallic base material 11 is coated with a thermoplastic film at both inside and outside and an ultraviolet ray setting coating layer 16 mixed with titanium oxide having 3-20 micron millimeter in thickness is applied on the external face side film layer of the side wall 3. And the total amount of titanium oxide per unit area of the external face side wall is at least 0.5mg/cm . When the thickness of ultraviolet ray setting coating layer 16 mixed with titanium oxide is finer than 3μm, a sufficient whiteness degree cant not be obtained and also the hiding power is not enough. On the other hand, when the thickness is larger than 20μm, the coating layer can not follow at the neck-in process and hence, the coating layer is broken. Since the coating layer has been hardened by ultraviolet ray, it is lustrous and excellent in score-resistance and hence, the external appearance characteristics are increased.
    • 4. 发明专利
    • WATER-BASED PAINT FOR CAN
    • JPS6348361A
    • 1988-03-01
    • JP19057886
    • 1986-08-15
    • KISHIMOTO AKIRA
    • KOJIMA SHUNJIWATANABE YOSHIKI
    • C09D163/00
    • PURPOSE:To provide the title paint which has excellent dispersion stability and gives a coating film having excellent resistance to corrosion and hot water, adhesion and flavor retentivity consisting of a dispersed particle phase contg. a bisphenol A type epoxy resin and a curing agent composed of a resin having methylol groups and a specified aq. dispersion medium. CONSTITUTION:95-40wt% bisphenol a type epoxy resin (a) having a number- average MW of 900-30,000 and an epoxy equivalent of 450-40,000 is melt- mixed with 5-60wt% curing agent (h) composed of a resin having methylol groups at a concn. of 100-1,000mmol of the methylol group per 100g and a number-average MW 200-1,500 (e.g., a resol type phenol/formaldehyde resin) to obtain a resin compsn. (A). 0.05-15wt% (based on the amount of the component A) water-soluble org. high-molecular dispersant having hydroxyl group at a concn. of 900-2,270mmol of the hydroxyl group per 100g (e.g., PVA) and a catalyst (e.g., sulfuric acid) are dissolved in water to obtain an aq. dispersion medium (B) having a pH of 2.0-6.0. 20-75wt% component A is finely dispersed in the component B to obtain water based paint for can, which is composed of a dispersed particle phase having a medium diameter of 0.1-10mum and the component B.
    • 5. 发明专利
    • PAINT COMPOSITION FOR CAN
    • JPS636063A
    • 1988-01-12
    • JP14699486
    • 1986-06-25
    • KISHIMOTO AKIRA
    • WATANABE YOSHIKIKOJIMA SHUNJI
    • C09D161/06C09D161/04C09D163/00
    • PURPOSE:To provide the title compsn. which gives a coating film having excellent low-temperature curability, corrosion resistance, etc., by mixing an epoxy resin with a resol type phenol/formaldehyde resin and an acid catalyst in a ratio satisfying a specified relationship and dissolving or dispersing the mixture in an org. solvent. CONSTITUTION:An epihalohydrin is condensed with bisphenol A to obtain an epoxy resin (a) having an average MW of 800-5,500. Separately, a phenol is reacted with formaldehyde in the presence of an alkali or alkaline earth metal catalyst to obtain a resol type phenol/formaldehyde resin (b). The component (a) is blended with the component (b) in a weight ratio of a:b=95-50:5-50. The blend is blended with an acid catalyst (c) (e.g., phosphoric acid) in such an amount as to satisfy formulas I-IV [wherein X is chemical equivalent of the component (c) per 100pts.wt. paint on a solid basis; and Y is the number of (etherified) methylol groups per one benzene ring of the component (b)]. The mixture is dissolved or dispersed in an org. solvent (d) in such an amount as to give 10-50wt% resin on a solid basis.