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    • 7. 发明专利
    • PRODUCTION OF CHITOSAN DERIVATIVE
    • JPH04149202A
    • 1992-05-22
    • JP27599390
    • 1990-10-15
    • KAO CORP
    • INA YOSHIMITSUNAKAMURA KOICHI
    • C08B37/08C11D3/22
    • PURPOSE:To obtain the title derivative excellent in humectant activity etc., having, as structural unit, an N,N-dicarboxymethylglucosamine derivative by reaction at a specified pH level of a monohaloacetic acid or its salt with a chitosan derivative having a specific structural unit. CONSTITUTION:A chitosan derivative having a structural unit of formula I [R and R are each H, formula II, III, IV, etc., (M is H, alkali metal atom, etc.; EO is ethylene oxide; PO is propylene oxide; (p) is 0-5; (q) is 0-5; (p) and (q) are not zero at the same time); R is H or formula II; R and R are not H at the same time] is made to react at pH 6-11 with a compound of formula V ((x) is halogen) or its salt and, if needed, salt exchange is carried out (e.g. using ammonium salt, diethanolammonium salt), thus obtaining the objective derivative having a structural unit of formula VI [M is H, alkali metal atom, alkylammonium (ammonium etc., may be substituted by other group(s)), etc.].