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    • 2. 发明专利
    • Solid oxide fuel cell and its manufacturing method
    • 固体氧化物燃料电池及其制造方法
    • JP2008010325A
    • 2008-01-17
    • JP2006180436
    • 2006-06-29
    • Mitsui Mining & Smelting Co Ltd三井金属鉱業株式会社
    • KUNISAKI TOSHIYATAKAHASHI KAZUAKIHOSHINO KAZUTOMO
    • H01M8/02H01M8/12
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a solid electrolyte fuel cell provided with a dense solid electrolyte membrane. SOLUTION: The solid electrolyte fuel cell is provided with a solid electrolyte membrane containing ceria and titanium into which rare earth oxide or calcium oxide has been doped, and the content of titanium oxide in the solid electrolyte membrane is 0.001 to 10 wt.% in TiO 2 conversion, and suitably manufactured by forming a fuel electrode and the solid electrolyte membrane containing titanium by simultaneously calcining them after film-forming a green for the solid electrolyte membrane containing titanium compound on one face of the green for the fuel electrode. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种设置有致密固体电解质膜的固体电解质燃料电池。 解决方案:固体电解质燃料电池设置有含有二氧化铈和钛的固体电解质膜,掺杂有稀土氧化物或氧化钙,固体电解质膜中的氧化钛的含量为0.001〜10重量%。 在TiO 2 转化率中,通过在含有钛化合物的固体电解质膜的一面上成膜绿色后,同时煅烧它们,同时煅烧含有钛的固体电解质膜, 绿色为燃料电极。 版权所有(C)2008,JPO&INPIT
    • 3. 发明专利
    • Method of manufacturing solid oxide fuel cell
    • 制造固体氧化物燃料电池的方法
    • JP2007200664A
    • 2007-08-09
    • JP2006016656
    • 2006-01-25
    • Mitsui Mining & Smelting Co Ltd三井金属鉱業株式会社
    • KUNISAKI TOSHIYATAKAHASHI KAZUAKIHOSHINO KAZUTOMO
    • H01M8/02H01M4/86H01M8/12
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide the method of manufacturing a solid oxide fuel cell having a porous fuel electrode and a dense solid electrolyte membrane. SOLUTION: The fuel electrode and the solid electrolyte membrane are formed by forming a green for the solid electrolyte film on one surface of a green for the fuel electrode, and then baking them in a condition that a contraction coefficient becomes over 20% but 30% or less at the same time. The green preferably contains 60-99 wt.% raw material powder and 1-40 wt.% pore forming agent, and the average particle size of the pore forming agent is preferably 1 nm to 5 μm. The obtained solid oxide fuel cell has the fuel electrode having a porosity of 10-50% and a relative density of 50-90% after baking. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供具有多孔燃料电极和致密固体电解质膜的固体氧化物燃料电池的制造方法。 解决方案:燃料电极和固体电解质膜通过在用于燃料电极的绿色的一个表面上形成用于固体电解质膜的绿色而形成,然后在收缩系数超过20%的条件下烘烤, 但同时为30%以下。 绿色优选含有60-99重量%的原料粉末和1-40重量%的成孔剂,并且成孔剂的平均粒径优选为1nm至5μm。 得到的固体氧化物型燃料电池,具有10-50%的孔隙率和50-90%的相对密度的燃料电极。 版权所有(C)2007,JPO&INPIT
    • 4. 发明专利
    • Ceria based solid electrolyte fuel cell and its manufacturing method
    • 基于CERIA的固体电解质燃料电池及其制造方法
    • JP2006059611A
    • 2006-03-02
    • JP2004238871
    • 2004-08-18
    • Mitsui Mining & Smelting Co Ltd三井金属鉱業株式会社
    • HOSHINO KAZUTOMOKUNISAKI TOSHIYATAKAHASHI KAZUAKI
    • H01M4/86H01M4/88H01M8/02H01M8/12
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a ceria based solid electrolyte fuel cell which has a porous fuel pole and a dense solid electrolyte membrane. SOLUTION: This is the ceria based solid electrolyte fuel cell in which the fuel pole and the ceria based solid electrolyte membrane are formed by simultaneous calcination, and in which the porosity of the fuel pole after calcination is 10 to 50%, and in which the relative density of the fuel pole after calcination is 50 to 90%. After green for the ceria based solid electrolyte membrane is formed on one face of the green for the fuel pole of which the relative density is 30 to 70%, this is manufactured by simultaneously calcining both materials under a condition that shrinkage factor becomes 10 to 20%, and by forming the fuel pole and the ceria based solid electrolyte membrane. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种具有多孔燃料极和致密固体电解质膜的二氧化铈基固体电解质燃料电池。 解决方案:这是基于二氧化铈的固体电解质燃料电池,其中通过同时煅烧形成燃料极和二氧化铈基固体电解质膜,其中煅烧后燃料极的孔隙率为10〜50%,其中 煅烧后燃料极的相对密度为50〜90%。 在用于相对密度为30〜70%的燃料极的绿色一面形成二氧化铈基固体电解质膜的绿色后,通过在收缩率为10〜20的条件下同时煅烧两种材料来制造 %,并且通过形成燃料极和二氧化铈基固体电解质膜。 版权所有(C)2006,JPO&NCIPI