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    • 3. 发明专利
    • Electronic component firing tool
    • 电子元件火花工具
    • JP2005041777A
    • 2005-02-17
    • JP2004275113
    • 2004-09-22
    • Mitsui Mining & Smelting Co Ltd三井金属鉱業株式会社
    • IZUTSU YASUHISATAKAHASHI NORIYUKIHOSHINO KAZUTOMOUCHIDA TOMIHIRO
    • C04B41/87C04B35/64F27D5/00
    • PROBLEM TO BE SOLVED: To provide an electronic component firing tool whose durability for a long term is improved by solving the problems that the durability for a long term lacks such that a surface layer is peeled from an intermediate layer and the like as the adherence between the intermediate layer and the surface layer for a conventional electronic component firing tool is inadequate and by adjusting the kind of a metal at the surface layer. SOLUTION: In the electronic component firing tool is comprised of a base material, the intermediate layer composed of a metal oxide coated on the surface of the base material and a stabilized zirconia surface layer formed on the intermediate layer, the stabilized zirconia surface layer and the intermediate layer are yttria-stabilized zirconia. As the intermediate layer or a partially molten intermediate layer and the surface layer consist of the yttria-stabilized zirconia in this electronic component firing tool, which means that both layers to be joined contain the same component, affinity is increased very much and the durability for a long term is improved and therefore, the electronic component firing tool can be used for a long term. COPYRIGHT: (C)2005,JPO&NCIPI
    • 解决的问题:提供一种通过解决长期的耐久性不足以使表面层从中间层等剥离等问题而提高长期耐久性的电子部件点火工具,作为 传统的电子部件烧制工具的中间层和表面层之间的附着力不足,并且通过调整表面层上的金属的种类。 解决方案:电子部件烧制工具由基材构成,由涂覆在基材表面上的金属氧化物构成的中间层和形成在中间层上的稳定的氧化锆表面层,稳定的氧化锆表面 层和中间层是氧化钇稳定的氧化锆。 作为该电子部件烧成工具中的中间层或部分熔融的中间层,表面层由氧化钇稳定化的氧化锆构成,这意味着被接合的两个层含有相同的成分,亲和力增加非常大,耐久性 长期改进,因此可以长期使用电子部件点火工具。 版权所有(C)2005,JPO&NCIPI
    • 6. 发明专利
    • Solid oxide fuel cell and its manufacturing method
    • 固体氧化物燃料电池及其制造方法
    • JP2008010325A
    • 2008-01-17
    • JP2006180436
    • 2006-06-29
    • Mitsui Mining & Smelting Co Ltd三井金属鉱業株式会社
    • KUNISAKI TOSHIYATAKAHASHI KAZUAKIHOSHINO KAZUTOMO
    • H01M8/02H01M8/12
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a solid electrolyte fuel cell provided with a dense solid electrolyte membrane. SOLUTION: The solid electrolyte fuel cell is provided with a solid electrolyte membrane containing ceria and titanium into which rare earth oxide or calcium oxide has been doped, and the content of titanium oxide in the solid electrolyte membrane is 0.001 to 10 wt.% in TiO 2 conversion, and suitably manufactured by forming a fuel electrode and the solid electrolyte membrane containing titanium by simultaneously calcining them after film-forming a green for the solid electrolyte membrane containing titanium compound on one face of the green for the fuel electrode. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种设置有致密固体电解质膜的固体电解质燃料电池。 解决方案:固体电解质燃料电池设置有含有二氧化铈和钛的固体电解质膜,掺杂有稀土氧化物或氧化钙,固体电解质膜中的氧化钛的含量为0.001〜10重量%。 在TiO 2 转化率中,通过在含有钛化合物的固体电解质膜的一面上成膜绿色后,同时煅烧它们,同时煅烧含有钛的固体电解质膜, 绿色为燃料电极。 版权所有(C)2008,JPO&INPIT
    • 7. 发明专利
    • Method of manufacturing solid oxide fuel cell
    • 制造固体氧化物燃料电池的方法
    • JP2007200664A
    • 2007-08-09
    • JP2006016656
    • 2006-01-25
    • Mitsui Mining & Smelting Co Ltd三井金属鉱業株式会社
    • KUNISAKI TOSHIYATAKAHASHI KAZUAKIHOSHINO KAZUTOMO
    • H01M8/02H01M4/86H01M8/12
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide the method of manufacturing a solid oxide fuel cell having a porous fuel electrode and a dense solid electrolyte membrane. SOLUTION: The fuel electrode and the solid electrolyte membrane are formed by forming a green for the solid electrolyte film on one surface of a green for the fuel electrode, and then baking them in a condition that a contraction coefficient becomes over 20% but 30% or less at the same time. The green preferably contains 60-99 wt.% raw material powder and 1-40 wt.% pore forming agent, and the average particle size of the pore forming agent is preferably 1 nm to 5 μm. The obtained solid oxide fuel cell has the fuel electrode having a porosity of 10-50% and a relative density of 50-90% after baking. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供具有多孔燃料电极和致密固体电解质膜的固体氧化物燃料电池的制造方法。 解决方案:燃料电极和固体电解质膜通过在用于燃料电极的绿色的一个表面上形成用于固体电解质膜的绿色而形成,然后在收缩系数超过20%的条件下烘烤, 但同时为30%以下。 绿色优选含有60-99重量%的原料粉末和1-40重量%的成孔剂,并且成孔剂的平均粒径优选为1nm至5μm。 得到的固体氧化物型燃料电池,具有10-50%的孔隙率和50-90%的相对密度的燃料电极。 版权所有(C)2007,JPO&INPIT
    • 8. 发明专利
    • Ceria based solid electrolyte fuel cell and its manufacturing method
    • 基于CERIA的固体电解质燃料电池及其制造方法
    • JP2006059611A
    • 2006-03-02
    • JP2004238871
    • 2004-08-18
    • Mitsui Mining & Smelting Co Ltd三井金属鉱業株式会社
    • HOSHINO KAZUTOMOKUNISAKI TOSHIYATAKAHASHI KAZUAKI
    • H01M4/86H01M4/88H01M8/02H01M8/12
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a ceria based solid electrolyte fuel cell which has a porous fuel pole and a dense solid electrolyte membrane. SOLUTION: This is the ceria based solid electrolyte fuel cell in which the fuel pole and the ceria based solid electrolyte membrane are formed by simultaneous calcination, and in which the porosity of the fuel pole after calcination is 10 to 50%, and in which the relative density of the fuel pole after calcination is 50 to 90%. After green for the ceria based solid electrolyte membrane is formed on one face of the green for the fuel pole of which the relative density is 30 to 70%, this is manufactured by simultaneously calcining both materials under a condition that shrinkage factor becomes 10 to 20%, and by forming the fuel pole and the ceria based solid electrolyte membrane. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种具有多孔燃料极和致密固体电解质膜的二氧化铈基固体电解质燃料电池。 解决方案:这是基于二氧化铈的固体电解质燃料电池,其中通过同时煅烧形成燃料极和二氧化铈基固体电解质膜,其中煅烧后燃料极的孔隙率为10〜50%,其中 煅烧后燃料极的相对密度为50〜90%。 在用于相对密度为30〜70%的燃料极的绿色一面形成二氧化铈基固体电解质膜的绿色后,通过在收缩率为10〜20的条件下同时煅烧两种材料来制造 %,并且通过形成燃料极和二氧化铈基固体电解质膜。 版权所有(C)2006,JPO&NCIPI
    • 9. 发明专利
    • Manufacturing method of cerium based solid electrolyte fuel cell
    • 基于固体电解质燃料电池的制造方法
    • JP2007200663A
    • 2007-08-09
    • JP2006016655
    • 2006-01-25
    • Mitsui Mining & Smelting Co Ltd三井金属鉱業株式会社
    • HOSHINO KAZUTOMOKUNISAKI TOSHIYATAKAHASHI KAZUAKI
    • H01M8/02H01M8/12
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a manufacturing method of a solid electrolyte fuel cell which has a porous fuel electrode and a fine solid electrolyte membrane. SOLUTION: On the whole surface of a cerium based fuel green which contains a pore forming material, a cerium based surface treating green which does not contain a pore forming material is deposited and both are pre-calcined at 800-1400°C at the same time. On the obtained pre-calcined part of the surface treating green, a cerium based solid electrolyte membrane green is deposited. Then, these are cleaned and calcined to form a fuel electrode and a solid electrolyte membrane. A fuel electrode green is desirable to contain 60-99wt.% of a raw material powder and 1-40wt.% of a pore forming material. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种具有多孔燃料电极和细固体电解质膜的固体电解质燃料电池的制造方法。 解决方案:在包含成孔材料的铈基燃料绿的整个表面上沉积不含孔形成材料的处理绿色的铈基表面,并将它们都在800-1400℃下预煅烧 与此同时。 在得到的预处理绿色表面的预煅烧部分上,沉积有铈基固体电解质膜绿色。 然后将它们清洗并煅烧以形成燃料电极和固体电解质膜。 需要一种燃料电极绿,含有60-99wt%的原料粉和1-40wt%的成孔材料。 版权所有(C)2007,JPO&INPIT