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    • 1. 发明专利
    • Sodium secondary battery module
    • 钠二次电池模块
    • JP2005005006A
    • 2005-01-06
    • JP2003164496
    • 2003-06-10
    • Hitachi Eng Co LtdHitachi Ltd日立エンジニアリング株式会社株式会社日立製作所
    • MITSUYOSHI TADAHIKOKUSAKABE KOJIHATO HISAMITSUSAITO YOSHINORIHIRANUMA TAKESHISUDO KENJIKIKUCHI KENZOSUZUKI MITSUGI
    • H01M10/39
    • Y02E60/12
    • PROBLEM TO BE SOLVED: To provide a sodium secondary battery module that is preferable for use for an electric power storage device and an electric vehicle or the like.
      SOLUTION: The sodium secondary battery module uses a sodium secondary battery which includes a negative pole chamber that holds sodium, a positive pole chamber that holds a positive pole active material, and a cap tube for a solid electrolyte that separates the negative pole chamber from the positive pole chamber. The sodium secondary battery is laterally placed in a horizontal direction or an oblique direction and held in a holding container 101, then a plurality of holding containers are arranged perpendicularly or vertically in a heat insulating vessel 20. A flat portion is provided at least at a part of upper/lower and/or right/left portions of the holding containers. A plurality of the holding containers arranged perpendicularly in the heat insulating vessel are mutually supported by a part of upper/lower portions of the holding containers where the flat portion is provided, and/or a plurality of the holding containers arranged horizontally in the heat insulating vessel are mutually supported by a part of right/left portions where the flat portion is provided, by which a density and efficiency of energy of the module are improved, movement of the holding containers held in the heat insulating vessel caused by vibrations and earthquakes or the like is prevented, and the module of higher mounting stability is obtained for the sodium secondary battery held in the holding containers.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供优选用于蓄电装置和电动车辆等的钠二次电池模块。 解决方案:钠二次电池模块使用钠二次电池,其包括保持钠的负极室,保持正极活性材料的正极室和用于分离负极的固体电解质的帽管 室从正极室。 钠二次电池在水平方向或倾斜方向上横向放置并保持在保持容器101中,然后将多个保持容器垂直或垂直地布置在绝热容器20中。平坦部分至少设置在 保持容器的上/下和/或右/左部分的一部分。 在绝热容器中垂直设置的多个保持容器由设置有平坦部分的保持容器的上部/下部的一部分相互支撑,和/或多个保持容器沿水平方向排列在绝热容器 容器由设置有平坦部分的右部/左部的一部分相互支撑,由此模块的能量的密度和效率得到改善,保持在隔热容器中的保持容器由振动和地震引起的运动或 防止了保持在保持容器中的钠二次电池的安装稳定性更高的模块。 版权所有(C)2005,JPO&NCIPI
    • 2. 发明专利
    • Secondary sodium battery
    • 二次电池
    • JP2003068354A
    • 2003-03-07
    • JP2001256372
    • 2001-08-27
    • Hitachi Eng Co LtdHitachi Ltd日立エンジニアリング株式会社株式会社日立製作所
    • MITSUYOSHI TADAHIKOMADOKORO MANABUHATO HISAMITSUKIKUCHI KENZOSAKAGUCHI SHIGERUKOMATSU SEIICHISADO TETSUYA
    • H01M2/02H01M10/39
    • Y02E60/12
    • PROBLEM TO BE SOLVED: To provide a secondary sodium battery capable of both a battery efficiency improvement and a large-capacity proper for utilizing in such as a power storage apparatus and an electric vehicle. SOLUTION: The secondary sodium battery includes a negative pole chamber 4 storing a liquid sodium 7, a positive pole chamber 5 storing a positive active material 14, and a solid electrolyte bag pipe 1 separating the negative pole chamber 4 and the positive pole chamber 5. The secondary sodium battery is characterized with placing the solid electrolyte bag pipe 1 in a horizontal direction or a diagonal direction, installing to laminate carbon fiber mat in an axis direction of the solid electrolyte bag pipe 1 as a porous conductive material 12 between a side surface of the solid electrolyte bag pipe 1 in the positive pole chamber 5 and a positive pole bath 3 comprising the positive pole chamber 5, or a current collector 11 provided in the positive pole chamber 5.
    • 要解决的问题:提供能够提高电池效率的二次钠电池和适用于诸如蓄电装置和电动车辆的大容量的二次钠电池。 解决方案:二次钠电池包括存储液体钠7的负极室4,存储正极活性物质14的正极室5和分离负极室4和正极室5的固体电解质袋管1。 二次钠电池的特征在于将固体电解质袋管1放置在水平方向或对角线方向,安装以将碳纤维毡沿着固体电解质袋管1的轴线方向层叠,作为多孔导电材料12在侧面 的正极室5中的固体电解质袋管1和包括正极室5的正极槽3或设置在正极室5中的集电体11。
    • 6. 发明专利
    • Sodium sulfur battery
    • JP2004087273A
    • 2004-03-18
    • JP2002246077
    • 2002-08-27
    • Hitachi Ltd株式会社日立製作所
    • MITSUYOSHI TADAHIKOMADOKORO MANABUKUSAKABE KOJIHATO HISAMITSUKIKUCHI KENZO
    • H01M10/39
    • Y02E60/12
    • PROBLEM TO BE SOLVED: To provide a sodium sulfur batter that is suited for a power storage apparatus, an electric automobile and the like, can improve battery efficiency and increase a capacity, and is mechanically reliable. SOLUTION: In the sodium sulfur battery, liquid sodium 7 is accommodated in a negative electrode chamber 4 composed of the inside of a solid electrolyte bag pipe 1 and a negative electrode container 2. A positive electrode active substance 14 composed of sulfur or/and sodium polysulfide is accommodated in a positive electrode chamber 5 composed of the outside of the solid electrolyte bag pipe and a positive electrode container 3. A collector 11 in a cylindrical shape or the like is provided along the outside of the solid electrolyte bag pipe. Then, a porous conductive material 12 or/and a porous material 13 is filled into the gap between the collector and the solid electrolyte bag pipe. In the sodium sulfur battery, the solid electrolyte bag pipe is inclined in a horizontal direction or in an oblique direction, and the side lower section or/and the side upper section of the collector and the positive electrode container are brought into contact or joined with each other. COPYRIGHT: (C)2004,JPO
    • 9. 发明专利
    • Sodium sulfur battery
    • 硫酸钠电池
    • JP2005005007A
    • 2005-01-06
    • JP2003164497
    • 2003-06-10
    • Hitachi Ltd株式会社日立製作所
    • MITSUYOSHI TADAHIKOHATO HISAMITSUSAITO YOSHINORIHIRANUMA TAKESHITOKOI HIROMI
    • H01M10/39
    • Y02E60/12
    • PROBLEM TO BE SOLVED: To provide a sodium sulfur battery which is preferable for use for an electric power storage device and an electric vehicle or the like.
      SOLUTION: The sodium sulfur battery includes a negative pole container 2 which holds sodium, a positive pole container 3 which holds a positive pole active material consisting of sulfur and/or sodium polysulfide, and a solid electrolyte 1 which separates the negative pole container from the positive pole container. Porous materials 13, 13' consisting of glass fiber or glass particles are installed between a porous conductive material 17 and the solid electrolyte provided in the positive pole container, and silicon dioxide included in the glass fiber or the glass particles is 80 weight percent or more.With such an arrangement, battery capacity is improved, deterioration of battery characteristics is reduced, a decline in the battery capacity is prevented even if a current density is made higher, and the effectively used sodium sulfur battery is obtained.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供优选用于蓄电装置和电动车辆等的钠硫电池。 解决方案:钠硫电池包括保持钠的负极容器2,保持由硫和/或多硫化钠组成的正极活性材料的正极容器3和分离负极的固体电解质1 容器从正极容器。 由玻璃纤维或玻璃颗粒构成的多孔材料13,13'安装在多孔导电材料17和设置在正极容器中的固体电解质之间,包含在玻璃纤维或玻璃颗粒中的二氧化硅为80重量%以上 通过这样的配置,电池容量提高,电池特性的劣化降低,即使电流密度变高,也能够防止电池容量的下降,得到有效使用的钠硫电池。 版权所有(C)2005,JPO&NCIPI