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    • 6. 发明专利
    • Surface treatment of copper
    • 铜表面处理
    • JPS6141775A
    • 1986-02-28
    • JP16253684
    • 1984-08-01
    • Hitachi Chem Co Ltd
    • KANEKO YOICHINAKASO AKISHIOKAMURA TOSHIRO
    • C23C18/40H05K3/38H05K3/46H05K3/18
    • C23C18/40H05K3/384
    • PURPOSE:To improve the adhesive property of copper to a resin layer such as prepreg by surface treatment by treating the copper with an aqueous soln. contg. copper ions, a complexing agent, a reducing agent, hydroxyl ions and Zr or Bi. CONSTITUTION:A copper lined laminated plate worked into a circuit is immersed in an aqueous soln. contg. copper ions from copper sulfate or the like, a complexing agent such as EDTA, a reducing agent, hydroxyl ions from NaOH or the like, and one or more kinds of components selected among Zr, Bi and compounds thereof. A heterocyclic compound contg. nitrogen such as 1,10- phenanthroline may be added to the aqueous soln. The immersed plate is taken out and after-treated with hydrochloric acid, an aqueous soln. of ammonium persulfate or the like. By this surface treatment the adhesive property of the copper surface to a resin layer such as prepreg, an etching resist or a plating resist is improved.
    • 目的:通过用水溶液处理铜,通过表面处理来提高铜对树脂层如预浸料的粘合性能。 对比 铜离子,络合剂,还原剂,羟基离子和Zr或Bi。 构成:将铜衬层压板浸入电路中浸入水溶液中。 对比 来自硫酸铜等的铜离子,EDTA等络合剂,还原剂,NaOH等的羟基离子,以及选自Zr,Bi及其化合物的一种或多种成分。 杂环化合物 可以向水溶液中加入氮,例如1,10-菲咯啉。 将浸渍板取出并用盐酸,水溶液进行后处理。 的过硫酸铵等。 通过该表面处理,提高了铜表面与树脂层如预浸料,抗蚀剂或电镀抗蚀剂的粘合性。