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    • 3. 发明专利
    • METHOD FOR FORMING CRYSTALLINE THIN MEMBRANE
    • JPH08133881A
    • 1996-05-28
    • JP27332494
    • 1994-11-08
    • HITACHI LTD
    • SHIGENIWA MASAHIROMURAKAMI HIDEKAZUKUJIRAI YUTAKAKIYOTA YUKIHIRO
    • C30B1/02H01L21/20H01L21/203
    • PURPOSE: To provide a method for forming a good crystalline thin membrane in the process of piling the thin membrane consisting of a second material on a base plate consisting of a first material, then heat-treating the membrane for crystallization, first by piling the second material upto the thickness of the lattice constant from the first atomic layer while keeping the migration distance of the constituting atoms of the second material to its lattice constant or less, then piling the material upto the required thickness by making the migration distance larger than the lattice distance. CONSTITUTION: This method for forming a crystalline thin membrane comprises using e.g. SiO2 as a first material and Si as a second material. By conducting the piling of a membrane with a long migration distance, the density of the membrane becomes non uniform and the crystallinity of the solid phase grown membrane becomes low. Therefore, in this method, once the material is piled thinly with the short migration distance and then piled upto the required thickness with the long migration distance. Once spreading Si atoms over uniformly by piling at a low temperature, countless unbonded Si-linkages are protruding uniformly on the surface of the base plate.
    • 10. 发明专利
    • MANUFACTURE OF SEMICONDUCTOR DEVICE
    • JPH07115137A
    • 1995-05-02
    • JP26210393
    • 1993-10-20
    • HITACHI LTD
    • KUJIRAI YUTAKAMURAKAMI HIDEKAZUKIMURA SHINICHIRO
    • H01L27/092H01L21/8238
    • PURPOSE:To enable a semiconductor device to be lessened in number of manufacturing processes and protected against contamination caused by heavy metals by a method wherein an Si substrate is locally irradiated with excimer laser ray to form an Si oxide film, and the Si oxide film is selectively grown and then removed in a vacuum by heating. CONSTITUTION:The surface of an Si substrate 11 isolated by an oxide film 12 is locally irradiated with excimer laser ray 13 in an oxidizing atmosphere for the formation of an Si oxide film 14. Then, an Si film 15 is epitaxially grown with gas such as SiH4, Si2H6, or SiH2Cl2 on a part of the substrate 11 where no oxide film is present. Thereafter, the Si substrate 11 is heated in a vacuum to remove the Si oxide film 14 by sublimating. By this setup, as only processes of oxidation, epitaxial growth., and sublimation of oxide film are used, a semiconductor crevice of this constitution can be lessened in number of manufacturing processes and protected against contamination caused by heavy metals which are usually mixed into the device accompanying the use of organic photoresist or the implantation of ions.