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    • 2. 发明专利
    • Rubber composition for automobile vibration isolating component and rubber member for automobile vibration isolating component using the same
    • 用于汽车振动隔离元件的橡胶组合物和使用其的汽车振动隔离组件的橡胶组件
    • JP2011088968A
    • 2011-05-06
    • JP2009242074
    • 2009-10-21
    • Fukoku Co LtdHonda Motor Co LtdShin-Etsu Chemical Co Ltd信越化学工業株式会社本田技研工業株式会社株式会社フコク
    • SUNAOKA MOTOYUKITAKEUCHI KAZUOYOKOYAMA KAZUTAKAOGAWA MIKIHITOYOSHIDA TAKASHIYAMAZAKI TOSHIOYOSHIDA MASAYUKINAKAMURA TSUTOMU
    • C08L83/07B60K5/12C08F299/08C08J3/24C08K3/36C08L23/08C08L83/06F16F1/36F16F15/08
    • PROBLEM TO BE SOLVED: To provide a rubber composition for providing an automobile vibration isolating component excellent in high damping property, long-term durability, stable temperature dependence, and low-temperature property in particular; and to provide a rubber member for the automobile vibration isolating component formed by curing the composition.
      SOLUTION: The rubber member is obtained by curing a composition, which is prepared by compounding components (C) and (B) with a mixture of components (A) and (B) mixed at a specific ratio, with an organic peroxide curing agent (E). The component (A) is an organopolysiloxane having the polymerization degree of 100 or more, containing a diphenylsiloxane unit represented by formula [I] and/or a phenylmethylsiloxane unit represented by formula [II] in the molecule, and having at least two silicon atom-coupling alkenyl groups in the molecule. The component (B) is an ethylene-α-olefin-nonconjugated polyene random copolymer rubber wherein the nonconjugated polyene consists of at least one kind of terminal vinyl group-containing norbornene compound represented by general formula [III] or [IV]. The component (C) is reinforcing silica with a specific surface area of 50 m
      2 /g or more. The component (D) is an organosilane or siloxane represented by general formula [V].
      COPYRIGHT: (C)2011,JPO&INPIT
    • 解决方案:提供一种用于提供高阻尼性,长期耐久性,稳定的温度依赖性和低温特性优异的汽车隔振部件的橡胶组合物。 并提供通过固化组合物形成的汽车隔振部件的橡胶构件。 解决方案:通过将组分(C)和(B)与特定比例混合的组分(A)和(B)的混合物与有机过氧化物混合制备的组合物固化,获得橡胶构件。 固化剂(E)。 组分(A)是分子中具有聚合度为100以上的含有由式[I]表示的二苯基硅氧烷单元和/或由式[II]表示的苯基甲基硅氧烷单元并且具有至少两个硅原子的有机聚硅氧烷 - 分子中的烯基。 组分(B)是乙烯-α-烯烃 - 非共轭多烯无规共聚物橡胶,其中非共轭多烯由通式[III]或[IV]表示的至少一种含末端乙烯基的降冰片烯化合物组成。 组分(C)是比表面积为50m 2 / SP / g以上的增强二氧化硅。 组分(D)是由通式[V]表示的有机硅烷或硅氧烷。 版权所有(C)2011,JPO&INPIT
    • 4. 发明专利
    • Silicone rubber composition for wire-coating
    • 硅胶橡胶组合物用于电线涂层
    • JP2005089587A
    • 2005-04-07
    • JP2003323925
    • 2003-09-17
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • KOIKE YOSHIAKIYAMAZAKI TOSHIO
    • C08L83/07C08K3/36C09D183/14H01B3/46H01B7/17
    • PROBLEM TO BE SOLVED: To obtain a silicone rubber composition for wire-coating, which provides silicone rubber in which a coating layer of silicone rubber is not bonded or not stuck fast to an electric wire in vulcanization in application for coating electric wire such as tinned copper wire, copper wire, etc., and which has excellent electric properties such as electrical insulating properties, etc., and heat resistance.
      SOLUTION: The silicone rubber composition for wire-coating comprises (A) 100 parts by mass of organopolysiloxane crude rubber having an average composition formula: R
      1
      a SiO
      (4-a)/2 (R is a nonsubstituted or substituted monofunctional hydrocarbon group; (a) is a positive number of 1.8-2.3) and containing at least two alkenyl groups bonded to a silicon atom in one molecule, (B) 10-100 parts by mass of a reinforcing filler, (C) 0.1-5 parts by mass of a phenyl group-containing silicone oil and (D) 0.1-5 parts by mass of an organic peroxide.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:为了获得用于涂布电线的硫化用硅线橡胶组合物,其提供硅橡胶的涂层没有粘合或不紧固在电线上的硅橡胶 例如镀锡铜线,铜线等,并且具有优异的电性能如电绝缘性能等,并且具有耐热性。 解决方案:用于电线涂布的硅橡胶组合物包含(A)100质量份具有平均组成式:R 1的有机聚硅氧烷粗橡胶, (4-a)/ 2 (R是非取代或取代的单官能烃基;(a)是1.8-2.3的正数),并且在一个上含有至少两个与硅原子键合的烯基 分子,(B)10-100质量份增强填料,(C)0.1-5质量份含苯基的硅油和(D)0.1-5质量份的有机过氧化物。 版权所有(C)2005,JPO&NCIPI
    • 5. 发明专利
    • Liquid silicone rubber composition for light conductive plate
    • 液体硅橡胶组合物用于轻导电板
    • JP2008291124A
    • 2008-12-04
    • JP2007138724
    • 2007-05-25
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • YAMAZAKI TOSHIOUNO TAKAOUBUKATA SHIGERU
    • C08L83/04C08K5/56
    • PROBLEM TO BE SOLVED: To provide a composition giving a cured film having high transparency, hardness and flexibility and most suitable as a light conductive plate of a backlight device for illuminating a key pad of a cellphone. SOLUTION: The hydrosilylated curable liquid silicone rubber composition for a light conductive plate contains, as essential components, (A) a silicone resin having an alkenyl group composed of units selected from M (R 3 SiO 1/2 ), Q (SiO 4/2 ), D (R 2 SiO 2/2 ) and T (RSiO 3/2 ) units (wherein R is a 1-6C monovalent hydrocarbon group and at least two in one molecule are alkenyl groups; and the sum of the M and Q units is ≥80 mol% and the molar ratio of the M unit to the Q unit is in the range of 0.5-1.5), (B) an organopolysiloxane containing an alkenyl group, exhibiting liquid state at room temperature and having an average polymerization degree of ≤2,000, (C) an organopolysiloxane exhibiting a raw rubber state at room temperature, containing an alkenyl group and having an average polymerization degree of >2,000, (D) an organohydrogenpolysiloxane containing a hydrogen atom bonded to a silicon atom, and (E) a hydrosilylation reaction catalyst. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种给出具有高透明度,硬度和柔韧性的固化膜的组合物,并且最适合作为用于照亮手机的键盘的背光装置的导光板。 解决方案:用于导光板的氢化硅烷化可固化液体硅橡胶组合物含有作为必要组分的(A)具有由选自M(R SB 3 SiO 2, ),Q(SiO 4/2 / SB),D(R SB 2 SiO 2 SB 2/2 / SB)) 和T(RSiO 3/3 / SB)单元(其中R是1-6C单价烃基,一分子中至少两个分子是烯基; M和Q单元的总和≥80 摩尔%,M单元与Q单元的摩尔比在0.5-1.5的范围内),(B)含有烯基的有机聚硅氧烷,在室温下呈现液态并且平均聚合度≤2,000, (C)在室温下显示生橡胶状态的有机聚硅氧烷,含有链烯基并且平均聚合度> 2,000,(D)含有与硅原子键合的氢原子的有机氢聚硅氧烷,(E)氢化硅烷化反应 CATA LYST。 版权所有(C)2009,JPO&INPIT
    • 7. 发明专利
    • Addition curing silicone rubber composition and its cured product
    • 添加固化硅酮橡胶组合物及其固化产品
    • JP2008255227A
    • 2008-10-23
    • JP2007099068
    • 2007-04-05
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • MEGURIYA NORIYUKIIDE SHINICHIYAMAZAKI TOSHIO
    • C08L83/07
    • C08L83/04C08G77/045C08G77/12C08G77/20C08L83/00
    • PROBLEM TO BE SOLVED: To provide an addition curing silicone rubber composition giving a cured material generating reduced amount of a low molecular weight siloxane component volatilizing from the cured product and free from the problems such as clouding or haze, contact fault, adhesion failure, and hydrophobicization of the surface caused by the deposition of the volatilized low-molecular weight siloxane component on the surrounding surfaces, and to provide a cured material of the composition. SOLUTION: The addition curing silicone rubber composition comprises; (A) 100 pts.mass of an organopolysiloxane containing at least two alkenyl groups bonded to a silicon atom in one molecule; (B) 0.3-20 pts.mass of an organohydrogenpolysiloxane containing at least two SiH functional groups in one molecule; and (C) a catalytic amount of an addition reaction catalyst, wherein the content of the organopolysiloxane having a degree of polymerization of ≤10 and containing at least one SiH functional group in one molecule is ≤0.5 mass% based on the sum of the components (A), (B) and (C). The invention further provides a cured silicone rubber obtained by curing the composition. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种加成固化硅橡胶组合物,其产生固化物,其产生少量从固化产物挥发的低分子量硅氧烷组分,并且没有诸如混浊或雾度,接触错误,粘附性 由挥发的低分子量硅氧烷组分沉积在周围表面引起的表面失效和疏水化,并提供组合物的固化材料。 解决方案:加成固化硅橡胶组合物包含: (A)在一分子中含有至少两个与硅原子键合的烯基的有机聚硅氧烷100磅; (B)在一分子中含有至少两个SiH官能团的有机氢聚硅氧烷0.3-20份; 和(C)催化量的加成反应催化剂,其中聚合度为≤10且在一个分子中含有至少一个SiH官能团的有机聚硅氧烷的含量基于组分的总和为≤0.5质量% (A),(B)和(C)。 本发明还提供通过固化该组合物获得的固化硅橡胶。 版权所有(C)2009,JPO&INPIT
    • 8. 发明专利
    • Addition curable type silicone rubber composition and cured article of the same
    • 添加固化型硅橡胶组合物及其固化物品
    • JP2009185257A
    • 2009-08-20
    • JP2008029247
    • 2008-02-08
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • MEGURIYA NORIYUKIYAMAZAKI TOSHIOUNO TAKAO
    • C08L83/07C08K5/5415C08L83/04C08L83/05
    • PROBLEM TO BE SOLVED: To provide an addition curable type silicone rubber composition having less volatilizing amount of a low molecular siloxane component from the cured article, and obtaining the cured article without having problems such that the formation of cloudiness or dullness, cause of contact point disorder, adhesion inhibition, making its surface as hydrophobic, etc., are developed by the attachment of the volatilized low molecular siloxane to surroundings, and the cured article of the same.
      SOLUTION: This addition curable type silicone rubber composition comprises (A) an organopolysiloxane containing an alkenyl group, (B) a resin-based copolymer consisting mainly of a R
      3 SiO
      1/2 unit and a SiO
      2 unit and having 0.5 to 1.5 molar ratio of the R
      3 SiO
      1/2 unit to the SiO
      2 unit [R
      3 SiO
      1/2 /SiO
      2 ], (C) an organohydrogen polysiloxane containing ≥2 SiH functional groups in one molecule and (D) an addition reaction catalyst, having ≤0.5 mass% content of organopolysiloxane having ≤10 degree of polymerization and containing ≥1 SiH functional group in one molecule based on the whole of the composition, and giving a transparent cured article. The addition curable type silicone rubber composition can give a transparent cured material suitable for an optical member without causing the problems of forming the cloudiness or dullness in its surrounding member.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了提供从固化制品中挥发量低的低分子量硅氧烷成分的加成固化型硅橡胶组合物,并且获得固化制品而没有形成浑浊或暗淡的问题,导致 的接触点紊乱,粘附抑制,使其表面为疏水性等,通过将挥发的低分子硅氧烷连接到周围环境及其固化制品来开发。 解决方案:该可加成固化型硅橡胶组合物包含(A)含有烯基的有机聚硅氧烷,(B)主要由R SB 3 SiO 1 / 2 单元和SiO 2 单元,并且具有0.5至1.5摩尔比的R SB 3 SiO 2 SB 1 1/2 单元与 (C)含有有机氢聚硅氧烷的有机氢聚硅氧烷,其含有 ≥2个SiH官能团,(D)加成反应催化剂,基于整个组成,在一个分子中具有≤10个聚合度且含有≥1个SiH官能团的有机聚硅氧烷的含量≤0.5质量% 给出透明的固化制品。 加成固化型硅橡胶组合物可以得到适合于光学部件的透明固化材料,而不会引起在其周围部件中形成浑浊或浑浊的问题。 版权所有(C)2009,JPO&INPIT
    • 9. 发明专利
    • Ink-jet silicone ink composition for inkjet and image formation method
    • 用于喷墨和图像形成方法的INK-JET硅酮墨水组合物
    • JP2007326994A
    • 2007-12-20
    • JP2006160791
    • 2006-06-09
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • YAMAZAKI TOSHIOYOSHIDA MASAYUKIKOIKE YOSHIAKINAKAMURA TSUTOMU
    • B41J2/01B41M5/00B41M5/50B41M5/52C09D11/00C09D11/322C09D11/326C09D11/38
    • C09D11/30
    • PROBLEM TO BE SOLVED: To obtain a silicone ink composition that is suitably useful for printing by an ink-jet printer and coating and to provide a method for image formation, with which printing with the ink composition by an ink-jet printer and coating are carried out and the image of the ink composition is crosslinked and/or adhered to a recording medium.
      SOLUTION: The ink-jet silicone ink composition comprises (A) an organopolysiloxane containing two or more alkenyl groups in the molecule, (B) an organohydrogenpolysiloxane containing two or more hydrosilyl groups in the molecule, (C) a platinum-based catalyst, (D) a reaction controller, (E) pigment, (F) a dispersant and (G) a solvent. The method for image formation comprises ink-jet printing on an ink composition recording medium, curing and adhering the image of ink composition to the recording medium.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:获得适用于通过喷墨打印机和涂料印刷的硅氧烷油墨组合物,并提供一种图像形成方法,通过喷墨打印机与油墨组合物进行印刷 并进行涂布,并且油墨组合物的图像被交联和/或粘附到记录介质上。 喷墨性硅油墨组合物包含(A)分子中含有2个以上烯基的有机聚硅氧烷,(B)分子中含有2个以上氢化甲硅烷基的有机氢聚硅氧烷,(C)铂系 催化剂,(D)反应控制剂,(E)颜料,(F)分散剂和(G)溶剂。 图像形成方法包括在油墨组合物记录介质上喷墨印刷,固化并将油墨组合物的图像粘附到记录介质上。 版权所有(C)2008,JPO&INPIT
    • 10. 发明专利
    • Method for molding silicone rubber composition
    • 硅橡胶组合物成型方法
    • JP2005220263A
    • 2005-08-18
    • JP2004030894
    • 2004-02-06
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • KOIKE YOSHIAKIYAMAZAKI TOSHIONAKAMURA TSUTOMU
    • C08J3/20C08K3/34C08K5/14C08L83/04C08L83/05
    • PROBLEM TO BE SOLVED: To provide a method for molding a silicone rubber composition in which foaming is suppressed even when carrying out ordinary pressure hot-air curing by using an inexpensive wet silica.
      SOLUTION: The method for molding the silicone rubber composition in which the wet silica is compounded comprises adding a curing agent such as an organic peroxide or an organohydrogenpolysiloxane and a hydrosilylation catalyst to a compound within 48 hr after compounding an organopolysiloxane represented by formula (I): R
      a SiO
      (4-a)/2 (wherein Rs are the same or different kinds of unsaturated or substituted monovalent hydrocarbon groups; a is a positive number of 1.97 to 2.03) as a base polymer with the wet silica.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 待解决的问题:提供一种即使在使用便宜的湿法二氧化硅进行常压热风固化时也抑制发泡的硅橡胶组合物的成型方法。 解决方案:将湿二氧化硅复合成型的硅橡胶组合物的成型方法,包括在将式(I)表示的有机聚硅氧烷配合后,在48小时内向化合物中添加有机过氧化物,有机氢聚硅氧烷,氢化硅烷化催化剂等固化剂 (I):R SB a(S-1)/ 2 SB(4-a)/ 2 SB(其中Rs是相同或不同种类的不饱和或取代的一价烃基; a是正数 为1.97至2.03)作为与湿二氧化硅的基础聚合物。 版权所有(C)2005,JPO&NCIPI