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    • 8. 发明专利
    • PRODUCTION OF RE123 OXIDE SUPERCONDUCTIVE BULK BODY
    • JP2000247795A
    • 2000-09-12
    • JP4733899
    • 1999-02-25
    • RAILWAY TECHNICAL RES INST
    • NAKAMURA YUICHIFUJIMOTO HIROYUKI
    • C30B29/22
    • PROBLEM TO BE SOLVED: To provide a simplified and stabilized production process for a large sized bulk body of high orientation by decomposing and melting raw materials for the bulk body at a temperature higher than the decomposition and melting point of an oxide to be prepared, then reducing the temperature lower than the decomposition and melting point and sowing a seed crystal to the melt. SOLUTION: The bulk body of RE123 oxide superconductor that is represented by a general formula: REBa2Cu3Ox (RE is one or two or more kinds of rare earth elements) and has a 123 phase crystal structure is prepared by melting and coagulating method. In this preparation, raw materials (or their precursors) for the bulk body are held at a temperature higher than the decomposition and melting point of the 123 phase of REBa2Cu3Ox oxide to be prepared. Then, the molten product is cooled down below the crystallization temperature. By utilizing the time until the crystallization is initiated, seed crystals are brought into contact with the treated raw materials and they are kept at the crystal growth temperature or they are slowly cooled down along a temperature gradient, thereby obtaining the objective bulk body of RE123 oxide superconductor mainly comprising the RE123 phase from the seed crystals.