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    • 6. 发明专利
    • Alpha-1, 4 glucan-grafted cellulose
    • ALPHA-1,4葡聚糖纤维素
    • JP2009293017A
    • 2009-12-17
    • JP2009111922
    • 2009-05-01
    • Ezaki Glico Co LtdKagoshima Univ国立大学法人 鹿児島大学江崎グリコ株式会社
    • KADOKAWA JUNICHITAKABA TAKESHIHOSOYA KAYO
    • C08B33/00C12P19/26
    • C08B15/06
    • PROBLEM TO BE SOLVED: To provide α-1, 4 glucan-grafted cellulose which is obtained by grafting α-1, 4 glucan having ≥25 degree of polymerization into cellulose to impart a clathrate function of the α-1, 4 glucan to the cellulose. SOLUTION: The α-1, 4 glucan-grafted cellulose is a graft polymer obtained by bonding an α-1, 4 glucan side chain to the main chain of the cellulose. The terminal carbon atom at the 1-position of the α-1, 4 glucan side chain is covalently bonded via an -NH- group to the carbon atom at the 6-position in at least one glucose residue of the cellulose main chain. Two hydrogen groups are bonded the terminal carbon atom at the 1-position or one oxygen atom is bonded thereto. The cellulose main chain has ≥25 degree of polymerization and the α-1, 4 glucan side chain has ≥25 degree of polymerization. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供通过将具有≥25聚合度的α-1,4-葡聚糖接枝到纤维素中而获得的α-1,4-葡聚糖接枝纤维素,以赋予α-1,4的包合功能 葡聚糖至纤维素。 解决方案:α-1,4-葡聚糖接枝纤维素是通过将α-1,4-葡聚糖侧链键合到纤维素的主链而获得的接枝聚合物。 α-1,4-葡聚糖侧链1位的末端碳原子通过-NH-基团与纤维素主链的至少一个葡萄糖残基中的6位的碳原子共价结合。 两个氢基键合在1位上的末端碳原子或一个氧原子键合。 纤维素主链聚合度≥25,α-1,4-葡聚糖侧链聚合度≥25。 版权所有(C)2010,JPO&INPIT
    • 9. 发明专利
    • METHOD FOR CONVERTING GLUCOSE TO α-1,4-GLUCAN
    • 将葡萄糖转化为α-1,4-GLUCAN的方法
    • JP2010148407A
    • 2010-07-08
    • JP2008328854
    • 2008-12-24
    • Ezaki Glico Co Ltd江崎グリコ株式会社
    • ODAN KOJIWATANABE HIROSHITAKABA TAKESHI
    • C12P19/04C12N15/09
    • PROBLEM TO BE SOLVED: To provide a method for efficiently producing α-1,4-glucan from glucose.
      SOLUTION: The method includes a step of producing α-1,4-glucan by reacting a solution containing glucose, a polyphosphoric acid, a primer, a polyphosphate glucokinase, a phosphoglucomutase and α-1,4-glucan phosphorylase. The glucose concentration in the solution at the start of the reaction is 100-2,000 mM, the pH of the solution at the start of the reaction is 5.7-12, and the ratio (Pi/Glc) of the molar concentration of the free phosphoric acid to the molar concentration of the glucose in the solution at the start of the reaction is ≤0.15.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题:提供从葡萄糖有效生产α-1,4-葡聚糖的方法。 解决方案:该方法包括通过使含有葡萄糖,多磷酸,引物,多磷酸葡糖激酶,磷酸葡萄糖变位酶和α-1,4-葡聚糖磷酸化酶的溶液反应来生产α-1,4-葡聚糖的步骤。 反应开始时溶液中的葡萄糖浓度为100-2,000mM,反应开始时溶液的pH为5.7-12,游离磷酸的摩尔浓度比(Pi / Glc) 在反应开始时,酸与溶液中葡萄糖的摩尔浓度不等于0.15。 版权所有(C)2010,JPO&INPIT
    • 10. 发明专利
    • Amylose synthesis in dimethyl sulfoxide
    • 氨基磺酸合成二甲基硅氧烷
    • JP2009270012A
    • 2009-11-19
    • JP2008121691
    • 2008-05-07
    • Ezaki Glico Co LtdKagoshima Univ国立大学法人 鹿児島大学江崎グリコ株式会社
    • KADOKAWA JUNICHIIZAWA HIRONORITAKABA TAKESHIHOSOYA KAYO
    • C08B30/20C12P19/04
    • PROBLEM TO BE SOLVED: To provide synthetic amylose dissolved in an organic solvent phase having dimethyl sulfoxide as a major component.
      SOLUTION: A method, involving synthesizing amylose in an aqueous solvent phase having water as a major component and obtaining the synthesized amylose in a dissolved form in an organic solvent phase having dimethyl sulfoxide as a major component, comprises a step of bringing an amylose synthesis enzyme into contact with an amylose synthesis substrate in an aqueous solvent phase to synthesize amylose, wherein although the aqueous solvent phase is in contact with the organic solvent phase in a hydrogel or on its surface, the contact between the water in the aqueous solvent phase and the dimethyl sulfoxide in the organic solvent phase is restricted by the hydrogel, and consequently the dimethyl sulfoxide does not substantially infiltrate into the aqueous solvent phase from the organic solvent phase, and the synthesized amylose migrates into the organic solvent phase from the aqueous solvent phase, and the synthesized amylose is obtained in a dissolved form in the organic solvent phase.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 待解决的问题:提供溶解在以二甲基亚砜为主要成分的有机溶剂相中的合成直链淀粉。 解决方案:涉及在具有水作为主要成分的水性溶剂相中合成直链淀粉并以溶解形式在二甲基亚砜作为主要成分的有机溶剂相中获得合成的直链淀粉的方法包括使 直链淀粉合成酶在水性溶剂相中与直链淀粉合成底物接触以合成直链淀粉,其中尽管水性溶剂相在水凝胶中或其表面上与有机溶剂相接触,水溶剂中的水之间的接触 有机溶剂相中的二甲基亚砜受到水凝胶的限制,因此二甲基亚砜基本上不会从有机溶剂相浸入到水性溶剂相中,合成的直链淀粉从水性溶剂中迁移到有机溶剂相中 在有机溶剂相中以溶解的形式获得合成的直链淀粉。 版权所有(C)2010,JPO&INPIT