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    • 6. 发明专利
    • Resin composition for exterior automotive trim and use thereof
    • 用于外部汽车试验的树脂组合物及其用途
    • JP2005146013A
    • 2005-06-09
    • JP2003381452
    • 2003-11-11
    • Mitsui Chemicals IncToyota Motor Corpトヨタ自動車株式会社三井化学株式会社
    • SUGIMOTO YOSHIOSAKAI IKUNORIFUJIYAMA NORIAKISHOJI NAOKI
    • B29C45/00C08K3/00C08K5/00C08L53/00
    • PROBLEM TO BE SOLVED: To provide a resin composition for exterior automotive trim having excellent fluidity during molding, excellent balance among physical properties such as flexural modulus, impact resistance, hardness and brittle temperature and a low heat shrinkage percentage, exhibiting excellent fluidity during injection molding, having excellent dimensional stability without unevenness of coating properties and gloss during continuous molding and readily molding injection molded products with slight flow marks and weld marks accompanying the molding, and to provide exterior automotive trim parts obtained by injection molding the resin composition for the exterior automotive trim, causing the slight flow marks and weld marks, having excellent coating properties and appearance, suitably usable in use without coating and having various kinds of durability and excellent strength with slight stress concentration. SOLUTION: The resin composition for the exterior automotive trim comprises a polypropylene resin composition composed of a polypropylene component (A), an elastomeric polymer composition (B) and an inorganic filler (C) and a specific amount of a specified additive. COPYRIGHT: (C)2005,JPO&NCIPI
    • 解决问题:提供一种成型时流动性优异的汽车外饰用树脂组合物,弯曲弹性模量,耐冲击性,硬度和脆性温度等物理性能与低热收缩率之间的平衡优异,具有优异的流动性 在注射成型时,具有优异的尺寸稳定性,连续成型时的涂布性能和光泽不均匀,并且容易地模制具有轻微流痕的注塑产品和伴随成型的焊缝,并提供通过将树脂组合物注射成型而获得的外部汽车饰件 外部汽车装饰件,引起轻微的流痕和焊痕,具有优异的涂层性能和外观,可适用于无涂层使用,具有各种耐久性和优异的强度,轻微的应力集中。 解决方案:用于汽车外饰件的树脂组合物包括由聚丙烯组分(A),弹性体聚合物组合物(B)和无机填料(C)组成的聚丙烯树脂组合物和特定量的特定添加剂。 版权所有(C)2005,JPO&NCIPI
    • 7. 发明专利
    • Propylene-based block copolymer, propylene-based resin composition obtained from the same, and molding obtained from the composition
    • 基于丙烯的嵌段共聚物,由其获得的基于丙烯的树脂组合物和由组合物获得的模塑
    • JP2011195661A
    • 2011-10-06
    • JP2010062398
    • 2010-03-18
    • Mitsui Chemicals Inc三井化学株式会社
    • SUGIMOTO YOSHIOITAKURA KEITAMATSUNAGA KAZUHISAMATSUDA YUICHI
    • C08F297/08C08F4/654
    • PROBLEM TO BE SOLVED: To provide a propylene block copolymer excellent in molding appearance and a rigidity-impact resistance balance and further excellent in injection molding fluidity, and to provide a propylene-based resin composition and an injection molding obtained from the propylene block copolymer, and an automobile component comprising the injection molding.SOLUTION: The propylene-based block copolymer is obtained through a step of producing a propylene polymer component and a step of producing a propylene-ethylene copolymer rubber component and has the following requirements satisfying the respective specified ranges. The requirements are: [1] a melt flow rate; [2] a moiety (Dsol) soluble with n-decane at room temperature and a moiety (Dinsol) insoluble with n-decane at room temperature; [3] a molecular weight distribution of Dsol; [4] an intrinsic viscosity of Dsol; [5] a molecular weight distribution and Mz/Mw of Dinsol; [6] a pentad fraction of Dinsol; and [7] the value of CSD defined by formula (i):CSD=([EE]×[PP])/([PE]/2)in Dsol. In formula (i), [EE], [PP] and [PE] represent molar fractions of ethylene chains in Dsol, propylene chains in Dsol and propylene-ethylene chains, respectively.
    • 要解决的问题:提供成型外观和刚性 - 抗冲击平衡优异的丙烯嵌段共聚物,并且进一步优异的注塑流动性,并且提供丙烯系树脂组合物和由丙烯嵌段共聚物获得的注塑成型, 以及包含注射成型体的汽车部件。解决方案:通过制备丙烯聚合物组分的步骤和生产丙烯 - 乙烯共聚物橡胶组分的步骤获得丙烯基嵌段共聚物,并且满足各自规定的范围的以下要求 。 要求是:[1]熔体流动速率; [2]在室温下可溶于正癸烷的部分(Dsol)和在室温下与正癸烷不溶的部分(Dinsol); [3] Dsol的分子量分布; [4] Dsol的特性粘度; [5] Dinsol的分子量分布和Mz / Mw; [6] Dinsol的五分分数; 和[7]由Dsol定义的CSD的值:CSD =([EE]×[PP])/([PE] / 2)。 在式(i)中,[EE],[PP]和[PE]分别表示Dsol中的乙烯链,Dsol和丙烯 - 乙烯链中的丙烯链的摩尔分数。