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1. 发明专利

JPS61100567A Pyridinecarboxyamide derivative 失效
标题翻译：吡啶甲酰胺衍生物
公开(公告)号：JPS61100567A
公开(公告)日：1986-05-19
申请号：JP22368884
申请日：1984-10-23
申请人： Daicel Chem Ind Ltd
发明人： UEDA YOICHIRO , HIRAKO YOSHIYUKI , MASAMOTO KAZUHISA , GOTO YUKIHISA , YAGIHARA HIROMU , MORISHIMA YASUO , OSABE HIROKAZU
IPC分类号： C07D405/06 , A01N43/08 , A01N43/40 , A61K31/4402 , A61K31/4406 , A61K31/4409 , A61K31/4418 , A61K31/4425 , A61K31/443 , A61K31/455 , A61P29/00 , C07D213/00 , C07D213/82 , C07D307/00 , C07D405/04
摘要： NEW MATERIAL:The compound of formula I [R is H or -(CH2)n-R1 (n is 1-3; R1 is H, OH, alkoxy, SH, alkylthio, amino, alkyl, 5- or 6- membered heterocyclic group, aryl, etc.); R2 is halogen, alkyl, OH, alkoxy, aryloxy, carboxy or alkoxycarbonyl; R3 is H, halogen or alkyl] or its acid addition salt. EXAMPLE:1-Butyl-N-(2,6-diethylphenyl)-1,4-dihydro-2,6-dimethyl--4-oxo- 3-pyridine carboxamide. USE:It suppresses the growth of plant and exhibits anti-inflammatory effect. PREPARATION:The compound of formula I can be prepared by reacting the 3-aminocrotonic acid anilide derivative of formula II with 2,2,6-trimethyl-4H-1,3- dioxin-4-one of formula III in a proper solvent under heating (e.g. at 100-140 deg.C).
摘要翻译：新物质：式I化合物[R为H或 - （CH 2）n -R 1（n为1-3; R 1为H，OH，烷氧基，SH，烷硫基，氨基，烷基，5-或6-元杂环基团，芳基等）; R2是卤素，烷基，OH，烷氧基，芳氧基，羧基或烷氧基羰基; R3是H，卤素或烷基]或其酸加成盐。实施例：1-丁基-N-（2,6-二乙基苯基）-1,4-二氢-2,6-二甲基-4-氧代-3-吡啶甲酰胺。用途：抑制植物生长，具有抗炎作用。制备：式I化合物可以通过将式II的3-氨基巴豆酸苯胺衍生物与式III的2,2,6-三甲基-4H-1,3-二恶英-4-酮在合适的溶剂中反应来制备，加热（例如在100-140℃）。

2. 发明专利

JPS5927856A Alpha-chloroacetamide compound 失效
标题翻译： ALPHA-氯乙酰胺化合物
公开(公告)号：JPS5927856A
公开(公告)日：1984-02-14
申请号：JP13775482
申请日：1982-08-06
申请人： Daicel Chem Ind Ltd
发明人： YAGIHARA HIROMU , HIRAKO YOSHIYUKI , MORISHIMA YASUO
IPC分类号： A01N37/20 , C07C67/00 , C07C231/00 , C07C233/17 , C07C233/18
摘要： NEW MATERIAL:The compound of formula I (R is trimethylcyclohexenyl or trimethylcyclohexadienyl; A is H, chloroacetyl, trimethylsilyl or 2-hydroxyethyl; n is 2 or 3).
EXAMPLE: N-( 2-Hydroxyethyl )-N-3, 5, 5-trimethyl-1-cyclohexen-1-yl)-α-chloroacetamide.
USE: Herbicide having plant growth suppressing activity.
PROCESS: The compound of e.g. formula III can be prepared by reacting trimethylcyclohexanone with amino alcohol or its derivative, and reacting the resultant intermediate of formula II with chloroacetyl chloride in an inert solvent such as toluene in the presence of triethylamine.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新物质：式Ⅰ化合物（R为三甲基环己烯基或三甲基环己二烯基; A为H，氯乙酰基，三甲基甲硅烷基或2-羟乙基; n为2或3）。实施例：N-（2-羟乙基）-N-3,5,5-三甲基-1-环己烯-1-基）-α-氯乙酰胺。用途：除草剂具有植物生长抑制活性。方法：式III可以通过使三甲基环己酮与氨基醇或其衍生物反应制备，并使所得到的式II的中间体与氯乙酰氯在惰性溶剂如甲苯中，在三乙胺存在下反应。

3. 发明专利

JPS5726647A Preparation of quaternary ammonium salt having propyl group 失效
标题翻译：具有丙烯酸的季铵盐的制备
公开(公告)号：JPS5726647A
公开(公告)日：1982-02-12
申请号：JP10021780
申请日：1980-07-22
申请人： Daicel Chem Ind Ltd
发明人： YAGIHARA HIROMU , OKABAYASHI TOKUO
IPC分类号： B01J27/00 , B01J23/44 , B01J27/02 , B01J27/20 , C07C67/00 , C07C209/00 , C07C209/70 , C07C211/62 , C07C211/63
摘要： PURPOSE: To prepare the titled compound useful as a raw material for the preparation of synthetic zeolite, etc., economically, by reducing a quaternary ammonium salt having an allyl group with hydrogen in the presence of a Pd catalyst supported on a carrier comprising a sulfate or a carbonate, and a bromine compound.
CONSTITUTION: The titled compound of formula II is prepared by reducing the ammonium salt of formula I (R is 1W12C alkyl or cycloalkyl; n is 1W4) with hydrogen. The reaction is carried out in the presence of (A) a Pd catalyst supported on a carrier comprising a sulfate or a carbonate and (B) a bromine compound such as HBr, KBr, NaBr, etc. The amount of the catalyst is 0.1W20mol%, based on the compound of formula I, and that of the bromine compound is 0.05W5pts.wt. per 1pt.wt. of the catalyst.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：为了制备用作制备合成沸石等的原料的标题化合物，经济上通过在负载在包含硫酸盐的载体上的Pd催化剂存在下还原具有烯丙基的季铵盐或碳酸酯和溴化合物。构成：通过用氢还原式I的铵盐（R是1-12C烷基或环烷基; n是1-4）制备式II的标题化合物。反应在（A）负载在包含硫酸盐或碳酸盐的载体上的Pd催化剂和（B）溴化合物如HBr，KBr，NaBr等的存在下进行。催化剂的量为0.1- 20mol％，基于式I化合物，溴化合物为0.05-5pts.wt。每1pt.wt 的催化剂。

4. 发明专利

JPS5726646A Preparation of quaternary ammonium salt having propyl group 失效
标题翻译：具有丙烯酸的季铵盐的制备
公开(公告)号：JPS5726646A
公开(公告)日：1982-02-12
申请号：JP10021680
申请日：1980-07-22
申请人： Daicel Chem Ind Ltd
发明人： YAGIHARA HIROMU , OKABAYASHI TOKUO
IPC分类号： B01J23/00 , B01J23/44 , C07C67/00 , C07C209/00 , C07C209/70 , C07C211/63
摘要： PURPOSE: To prepare the titled compound useful as a raw material for the preparation of synthetic zeolite, etc., economically, by reducing a quaternary ammonium salt having an allyl group with hydrogen in the presence of a Pd catalyst supported on a carrier comprising a sulfate or a carbonate, at a specific temperature.
CONSTITUTION: The titled compound of formula II is prepared by reducing the quaternary ammonium salt of formula I (R is 1W12C alkyl or cycloalkyl; n is 1W3) with hydrogen. The reaction is carried out in the presence of a Pd catalyst supported on a carrier comprising a sulfate or a carbonate, at -10W+20°C, pref. -10W+10°C. The amount of the catalyst is 0.1W20mol% based on the compound of formula I.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：为了制备用作制备合成沸石等的原料的标题化合物，经济上通过在负载在包含硫酸盐的载体上的Pd催化剂存在下还原具有烯丙基的季铵盐或碳酸盐。构成：通过用氢还原式I的季铵盐（R是1-12C烷基或环烷基; n为1-3）制备式II的标题化合物。反应在负载在包含硫酸盐或碳酸盐的载体上的Pd催化剂的存在下，在-10- + 20℃，优选的情况下进行。 -10〜+ 10℃ 基于式I化合物，催化剂的量为0.1-20mol％。

5. 发明专利

JPS59148733A Beta-phenoxy-alpha-methylenepropionic acid derivative 失效
标题翻译： β-苯氧基-α-甲基衍生物衍生物
公开(公告)号：JPS59148733A
公开(公告)日：1984-08-25
申请号：JP2128183
申请日：1983-02-10
申请人： Daicel Chem Ind Ltd
发明人： YAGIHARA HIROMU , HIRAKO YOSHIYUKI , MORISHIMA YASUO , MASAMOTO KAZUHISA
IPC分类号： C07C69/736 , A01N39/02 , A01N41/06 , C07C49/255 , C07C49/84 , C07C67/00 , C07C235/28 , C07C239/00 , C07C251/66 , C07C301/00 , C07C311/46 , C07C325/00 , C07C327/22
摘要： NEW MATERIAL:The compound of formula I [Z is group of formula II (R
1 and R
2 are H, 1W4C lower alkyl, phenyl, benzyl or -C
6 H
4 SO
2 NH
2 ), -OC
6 H
5 , -SC
6 H
5 , or -O-N=C(CH
3 )
2 ].
EXAMPLE: 2-Methylene-3-phenoxypropionic acid anilide.
USE: A plant growth suppressing agent.
PREPARATION: The compound of formula I )can be prepared e.g. by reacting 2- phenoxymethylacrylic acid of formula III with an amine, phenol, thiophenol, etc. of formula H-Z in an inert solvent in the presence of a dehydrative condensation agent at -30W+100°C, if necessary in the presence of a base.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新物质：式I化合物[Z为式II基团（R1和R2为H，1-4C低级烷基，苯基，苄基或-C6H4SO2NH2），-OC6H5，-SC6H5或-ON = C（CH3） 2]。实施例：2-亚甲基-3-苯氧基丙酸苯胺。用途：植物生长抑制剂。制备：式I）的化合物可以例如制备。通过在惰性溶剂中，在脱水缩合剂存在下，在-30- + 100℃下，使式III的2-苯氧基甲基丙烯酸与式HZ的胺，苯酚，苯硫酚等反应，如有必要，一个基地

6. 发明专利

JPS59144731A Beta-substituted phenoxy-alpha-methylenepropionic acid derivative 失效
标题翻译：取代的苯氧基 - 氨基甲酸衍生物衍生物
公开(公告)号：JPS59144731A
公开(公告)日：1984-08-18
申请号：JP1860083
申请日：1983-02-07
申请人： Daicel Chem Ind Ltd
发明人： YAGIHARA HIROMU , HIRAKO YOSHIYUKI , MORISHIMA YASUO , MASAMOTO KAZUHISA
IPC分类号： C07C69/734 , A01N37/06 , A01N39/02 , A01N43/34 , A01N43/40 , A01N43/42 , A01N43/54 , A01N43/60 , A01N43/78 , C07C51/00 , C07C51/347 , C07C59/60 , C07C59/68 , C07C67/00 , C07C67/34 , C07C201/00 , C07C205/36 , C07C205/38 , C07C213/00 , C07C217/84 , C07C217/92 , C07C313/00 , C07C323/20 , C07D213/64 , C07D215/20 , C07D215/22 , C07D215/36 , C07D239/34 , C07D241/44 , C07D277/68
摘要： NEW MATERIAL:The β-substituted phenoxy-α-methylenepropionic acid derivative of formula I (A is phenyl, benzyl, pyridyl, naphthyl, quinolynyl, pyrimidyl, benzothiazolyl or quinoxalinyl; X is O, S, NH or NCH
3 ; R is H or 1W4C alkyl).
EXAMPLE: 2-Methylene-3-[4-(2-naphthylamino)phenoxy]propionic acid.
USE: Useful as a plant-growth regulator. Remarkably effective to suppress the growth of plants, and utilizable also as a herbicide.
PREPARATION: The compound of formula I can be prepared e.g. by reacting the substituted phenol of formula II with β,β'-dibromoisobutyric acid in the presence of a solvent such as ethanol and an alkali (e.g. 3mol of NaOH based on 1mol of the phenol), and esterifying the resultant β-substituted α-methylene-propionic acid.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新物质：式Ⅰ的β-取代苯氧基-α-亚甲基丙酸衍生物（A为苯基，苄基，吡啶基，萘基，喹啉基，嘧啶基，苯并噻唑基或喹喔啉; X为O，S，NH或NCH 3; R为H或 1-4C烷基）。实施例：2-亚甲基-3- [4-（2-萘基氨基）苯氧基]丙酸。用途：作为植物生长调节剂有用。显着有效地抑制植物的生长，也可用作除草剂。制备：式I化合物可以制备如通过在溶剂如乙醇和碱（例如基于1mol苯酚的3mol NaOH）存在下使式II的取代的苯酚与β，β'-二溴异丁酸反应，并酯化所得β-取代的α- 亚甲基丙酸。

7. 发明专利

JPS59157051A Beta-oxy-alpha-methylenepropionic acid 失效
标题翻译： BETA-OXY-ALPHA-METHYLENEPROPIONIC ACID
公开(公告)号：JPS59157051A
公开(公告)日：1984-09-06
申请号：JP2939083
申请日：1983-02-25
申请人： Daicel Chem Ind Ltd
发明人： YAGIHARA HIROMU , HIRAKO YOSHIYUKI , MORISHIMA YASUO , MASAMOTO KAZUHISA
IPC分类号： A01N39/02 , C07C51/00 , C07C59/42 , C07C59/66 , C07C59/68 , C07C67/00 , C07C213/00 , C07C217/84 , C07C313/00 , C07C323/20
摘要： NEW MATERIAL:A β-oxy-α-methylenepropionic acid shown by the formula I (A is benzene nucleus-containing group such as fluorophenyl, methylthiophenyl, naphthylaminophenyl, or biphenyl, or tetrahydronaphthyl).
EXAMPLE: 2-Methylene-3-(4-fluorophenoxy)propionic acid.
USE: Useful as a herbicide or plant growth regulator. Excellent for controlling the growth of plant.
PREPARATION: A phenol shown by the formula II is reacted with β, β-dibromoisobutyric acid in a solvent such as ethanol, etc. in the presence of preferably three times the molar amount of NaOH, to give a compound shown by the formula I .
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新材料：由式I表示的β-氧-α-亚甲基丙酸（A为含苯基的基团，例如氟苯基，甲硫基苯基，萘基氨基苯基或联苯基或四氢萘基）。实施例：2-亚甲基-3-（4-氟苯氧基）丙酸。用途：用作除草剂或植物生长调节剂。非常适用于控制植物生长。制备：在优选三倍摩尔量的NaOH的存在下，将式II所示的苯酚与β，β-二溴异丁酸在溶剂如乙醇等中反应，得到式I所示的化合物。

8. 发明专利

JPS5772941A Reduction of allyl group-containing quaternary ammonium salt 失效
标题翻译：减少含有全氟代四季铵盐
公开(公告)号：JPS5772941A
公开(公告)日：1982-05-07
申请号：JP14985180
申请日：1980-10-24
申请人： Daicel Chem Ind Ltd
发明人： YAGIHARA HIROMU , OKABAYASHI TOKUO
IPC分类号： C07B61/00 , B01J23/44 , B01J27/02 , B01J27/20
CPC分类号： Y02P20/52
摘要： PURPOSE: To obtain a propyl group-containing quaternary ammonium salt easily, by isomerizing an allyl group of an allyl (cyclo)aclkylammonium hydroxide to give a novel propenyl compound, followed by subjecting this compound to catalytic reduction.
CONSTITUTION: A quaternary ammonium salt shown by the formulaI(R is 1W12C alkyl, or cycloalkyl; n is 1, 2, or 3), for example, is isomerized in a solvent of a lower aliphatic alcohol/nonproton solvent, to give a novel quaternary ammonium salt shown by the formula II. If necessary, this salt is neutraized with a compound shown by the formula HX (X
- is OH
- , Cl
- , or Br
- ), and is reduced with molecular hydrogen in the presence of a palladium catalyst supported by a carrier, e.g., sulfate, carbonate, to give a quaternary ammonium salt shown by the formula III. This compound is useful as an additive for plastic products, surface active agent, raw material for organic synthesis, etc.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：通过将烯丙基（环）烷基氢氧化铵的烯丙基异构化得到新的丙烯基化合物，然后使该化合物进行催化还原，可以容易地得到含丙基的季铵盐。构成：例如，在低级脂族醇/非质子溶剂的溶剂中异构化式I所示的季铵盐（R为1-12C烷基或环烷基; n为1,2或3），得到式II所示的新型季铵盐。如果需要，该盐用式HX（X - ，OH - ，Cl - 或Br - ）所示的化合物中和，并在钯的存在下用分子氢还原由载体例如硫酸盐，碳酸盐负载的催化剂，得到式III所示的季铵盐。该化合物可用作塑料制品，表面活性剂，有机合成原料等的添加剂。

9. 发明专利

JPS59134748A Beta-substituted-alpha-methylenepropionic acid ester 失效
标题翻译：甲基替代阿尔法 - 甲基戊酸酯
公开(公告)号：JPS59134748A
公开(公告)日：1984-08-02
申请号：JP611083
申请日：1983-01-18
申请人： Daicel Chem Ind Ltd
发明人： YAGIHARA HIROMU , HIRAKO YOSHIYUKI , MORISHIMA YASUO , MASAMOTO KAZUHISA
IPC分类号： C07C69/734 , A01N37/06 , A01N43/14 , A01N43/16 , A01N43/40 , A01N43/42 , C07C67/00 , C07C69/736 , C07C239/00 , C07C239/20 , C07C253/00 , C07C255/54 , C07C313/00 , C07C323/54 , C07C323/56 , C07C323/61 , C07C323/62 , C07D213/70 , C07D215/20 , C07D311/16
摘要： NEW MATERIAL:A compound shown by the formula IV (X is O, or S; A is cyclic hydrocarbon group of phenyl, benzyl, naphthyl and cyclohexyl, monofunctional group obtained by removing H from cyclic compound of pyridine, quinoline, 4-methylcoumain, and 9-fluorenone, or diethylamino; with the proviso that two or less H of aromatic A may be replaced with substituent group such as CH
3 , OCH
3 , SCH
3 , CF
3 , Cl, etc.).
EXAMPLE: 2-Methylene-3-(4-fluorophenoxy)propionic acid methyl ester.
USE: A plant growth regulator. Expected to be useful as a herbicide.
PROCESS: For example, a phenol or thiophenol shown by the formula I is reacted with β,β-dibromoisobutyric acid shown by the formula II in a solvent such as ethanol, etc. in the presence of an alkali such as NaOH, etc. to give a compound shown by the formula III, which is esterified, to give a compound shown by the formula IV.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新材料：式IV化合物（X为O或S; A为苯基，苄基，萘基和环己基的环状烃基，通过从吡啶的环状化合物除去H而得到的单官能团，喹啉，4-甲基香豆素，和9-芴酮或二乙基氨基;条件是两个或更少的芳族A的H可以被诸如CH 3，OCH 3，SCH 3，CF 3，Cl等的取代基代替。实施例：2-亚甲基-3-（4-氟苯氧基）丙酸甲酯。用途：植物生长调节剂。预期用作除草剂。方法：例如，式I所示的苯酚或苯硫酚在溶剂如乙醇等中，在碱如NaOH等的存在下，与式II所示的β，β-二溴异丁酸反应，得到得到式III化合物，其被酯化，得到式IV所示的化合物。

10. 发明专利

JPS5770843A Reduction of quaternary ammonium salt having allyl group 失效
标题翻译：减少具有ALLYL集团的季铵盐
公开(公告)号：JPS5770843A
公开(公告)日：1982-05-01
申请号：JP14602380
申请日：1980-10-17
申请人： Daicel Chem Ind Ltd
发明人： YAGIHARA HIROMU , OKABAYASHI TOKUO
IPC分类号： C07B61/00 , B01J31/24
CPC分类号： Y02P20/52
摘要： PURPOSE: To prepare the titled compound useful as an additive for plastic molded article, a surface-active agent, etc. in high yield, by reducing a quaternary ammonium salt having an allyl group with H
2 in the presence of a complex of rhodium metal or ruthenium metal as a reduction catalyst.
CONSTITUTION: A quaternary ammonium salt having a propyl group of formula II is prepared by the catalytic reduction of an allyl group-containing quaternary ammonium salt of formulaI(R is alkyl or cycloalkyl; n is 1W4) with molecular hydrogen. The reduction is carried out in the presence of a catalyst composed of a complex of rhodium metal or ruthenium metal (prepared by coordinating a ligand such as triphenyl phosphine to a halide of rhodium or ruthenium), in pref. anhydrous or hydrated lower aliphatic alcohol.
USE: Raw material for organic synthesis, etc.
COPYRIGHT: (C)1982,JPO&Japio
摘要翻译：目的：通过在铑金属络合物或铑金属络合物的存在下，通过用H 2还原具有烯丙基的季铵盐，以高产率制备用作塑料模制品添加剂，表面活性剂等的标题化合物钌金属作为还原催化剂。构成：具有式II丙基的季铵盐通过用分子氢催化还原含有烯丙基的式I的季铵盐（R为烷基或环烷基; n为1-4）制备。在由铑金属或钌金属络合物（通过将配位体如三苯基膦配位到铑或钌的卤化物制备）的催化剂存在下进行还原。无水或水合的低级脂族醇。用途：有机合成原料等

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