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1. 发明专利

JPS61100567A Pyridinecarboxyamide derivative 失效
标题翻译：吡啶甲酰胺衍生物
公开(公告)号：JPS61100567A
公开(公告)日：1986-05-19
申请号：JP22368884
申请日：1984-10-23
申请人： Daicel Chem Ind Ltd
发明人： UEDA YOICHIRO , HIRAKO YOSHIYUKI , MASAMOTO KAZUHISA , GOTO YUKIHISA , YAGIHARA HIROMU , MORISHIMA YASUO , OSABE HIROKAZU
IPC分类号： C07D405/06 , A01N43/08 , A01N43/40 , A61K31/4402 , A61K31/4406 , A61K31/4409 , A61K31/4418 , A61K31/4425 , A61K31/443 , A61K31/455 , A61P29/00 , C07D213/00 , C07D213/82 , C07D307/00 , C07D405/04
摘要： NEW MATERIAL:The compound of formula I [R is H or -(CH2)n-R1 (n is 1-3; R1 is H, OH, alkoxy, SH, alkylthio, amino, alkyl, 5- or 6- membered heterocyclic group, aryl, etc.); R2 is halogen, alkyl, OH, alkoxy, aryloxy, carboxy or alkoxycarbonyl; R3 is H, halogen or alkyl] or its acid addition salt. EXAMPLE:1-Butyl-N-(2,6-diethylphenyl)-1,4-dihydro-2,6-dimethyl--4-oxo- 3-pyridine carboxamide. USE:It suppresses the growth of plant and exhibits anti-inflammatory effect. PREPARATION:The compound of formula I can be prepared by reacting the 3-aminocrotonic acid anilide derivative of formula II with 2,2,6-trimethyl-4H-1,3- dioxin-4-one of formula III in a proper solvent under heating (e.g. at 100-140 deg.C).
摘要翻译：新物质：式I化合物[R为H或 - （CH 2）n -R 1（n为1-3; R 1为H，OH，烷氧基，SH，烷硫基，氨基，烷基，5-或6-元杂环基团，芳基等）; R2是卤素，烷基，OH，烷氧基，芳氧基，羧基或烷氧基羰基; R3是H，卤素或烷基]或其酸加成盐。实施例：1-丁基-N-（2,6-二乙基苯基）-1,4-二氢-2,6-二甲基-4-氧代-3-吡啶甲酰胺。用途：抑制植物生长，具有抗炎作用。制备：式I化合物可以通过将式II的3-氨基巴豆酸苯胺衍生物与式III的2,2,6-三甲基-4H-1,3-二恶英-4-酮在合适的溶剂中反应来制备，加热（例如在100-140℃）。

2. 发明专利

JPS5927856A Alpha-chloroacetamide compound 失效
标题翻译： ALPHA-氯乙酰胺化合物
公开(公告)号：JPS5927856A
公开(公告)日：1984-02-14
申请号：JP13775482
申请日：1982-08-06
申请人： Daicel Chem Ind Ltd
发明人： YAGIHARA HIROMU , HIRAKO YOSHIYUKI , MORISHIMA YASUO
IPC分类号： A01N37/20 , C07C67/00 , C07C231/00 , C07C233/17 , C07C233/18
摘要： NEW MATERIAL:The compound of formula I (R is trimethylcyclohexenyl or trimethylcyclohexadienyl; A is H, chloroacetyl, trimethylsilyl or 2-hydroxyethyl; n is 2 or 3).
EXAMPLE: N-( 2-Hydroxyethyl )-N-3, 5, 5-trimethyl-1-cyclohexen-1-yl)-α-chloroacetamide.
USE: Herbicide having plant growth suppressing activity.
PROCESS: The compound of e.g. formula III can be prepared by reacting trimethylcyclohexanone with amino alcohol or its derivative, and reacting the resultant intermediate of formula II with chloroacetyl chloride in an inert solvent such as toluene in the presence of triethylamine.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新物质：式Ⅰ化合物（R为三甲基环己烯基或三甲基环己二烯基; A为H，氯乙酰基，三甲基甲硅烷基或2-羟乙基; n为2或3）。实施例：N-（2-羟乙基）-N-3,5,5-三甲基-1-环己烯-1-基）-α-氯乙酰胺。用途：除草剂具有植物生长抑制活性。方法：式III可以通过使三甲基环己酮与氨基醇或其衍生物反应制备，并使所得到的式II的中间体与氯乙酰氯在惰性溶剂如甲苯中，在三乙胺存在下反应。

3. 发明专利

JPS61100550A Preparation of dialkylaminoethanol 失效
标题翻译：对二氨基苯乙醇的制备
公开(公告)号：JPS61100550A
公开(公告)日：1986-05-19
申请号：JP22234284
申请日：1984-10-23
申请人： Daicel Chem Ind Ltd
发明人： HIRAKO YOSHIYUKI , FURUKAWA SHOJI
IPC分类号： C07C213/04 , C07C67/00 , C07C213/00 , C07C215/08
摘要： PURPOSE: To obtain selecting the titled compound useful as an alkyd resin coating material, a catalyst for foaming polyurethane, etc. in high yield without any by-product, by reacting dialkylamine with ethylene oxide under specific conditions through the liquid-phase semi-batch method.
CONSTITUTION: A dialkylamine expressed by formula I (R
1 and R
2 are respectively 1W4C lower alkyl) is reacted with ethylene oxide to obtain a dialkylaminoethanol expressed by formula II. The reaction is carried out by the liquid phase semi-batch method in such a way that the ethylene oxide is fed continuously into a solution of the dialkylamine in a solvent to effect the reaction, and the reaction is finally stopped when the molar ratio of dialkylamine to ethylene oxide reaches at 2W3:1. By the above-mentioned method, the reaction progresses selectively and finishes without causing any reaction of ethylene oxide with the aimed compound and the solvent.
COPYRIGHT: (C)1986,JPO&Japio
摘要翻译：目的：通过液相半分批处理，在特定条件下使二烷基胺与环氧乙烷反应，选择可用作醇酸树脂涂料的标题化合物，高产率的聚氨酯发泡催化剂，无任何副产物方法。构成：由式I表示的二烷基胺（R 1和R 2分别为1-4C的低级烷基）与环氧乙烷反应，得到式Ⅱ表示的二烷基氨基乙醇。反应通过液相半间歇法进行，使得环氧乙烷连续进料到溶剂中的二烷基胺溶液中进行反应，当二烷基胺的摩尔比到环氧乙烷达到2-3：1。通过上述方法，反应进行选择性并完成，而不引起环氧乙烷与目标化合物和溶剂的任何反应。

4. 发明专利

JPS59148733A Beta-phenoxy-alpha-methylenepropionic acid derivative 失效
标题翻译： β-苯氧基-α-甲基衍生物衍生物
公开(公告)号：JPS59148733A
公开(公告)日：1984-08-25
申请号：JP2128183
申请日：1983-02-10
申请人： Daicel Chem Ind Ltd
发明人： YAGIHARA HIROMU , HIRAKO YOSHIYUKI , MORISHIMA YASUO , MASAMOTO KAZUHISA
IPC分类号： C07C69/736 , A01N39/02 , A01N41/06 , C07C49/255 , C07C49/84 , C07C67/00 , C07C235/28 , C07C239/00 , C07C251/66 , C07C301/00 , C07C311/46 , C07C325/00 , C07C327/22
摘要： NEW MATERIAL:The compound of formula I [Z is group of formula II (R
1 and R
2 are H, 1W4C lower alkyl, phenyl, benzyl or -C
6 H
4 SO
2 NH
2 ), -OC
6 H
5 , -SC
6 H
5 , or -O-N=C(CH
3 )
2 ].
EXAMPLE: 2-Methylene-3-phenoxypropionic acid anilide.
USE: A plant growth suppressing agent.
PREPARATION: The compound of formula I )can be prepared e.g. by reacting 2- phenoxymethylacrylic acid of formula III with an amine, phenol, thiophenol, etc. of formula H-Z in an inert solvent in the presence of a dehydrative condensation agent at -30W+100°C, if necessary in the presence of a base.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新物质：式I化合物[Z为式II基团（R1和R2为H，1-4C低级烷基，苯基，苄基或-C6H4SO2NH2），-OC6H5，-SC6H5或-ON = C（CH3） 2]。实施例：2-亚甲基-3-苯氧基丙酸苯胺。用途：植物生长抑制剂。制备：式I）的化合物可以例如制备。通过在惰性溶剂中，在脱水缩合剂存在下，在-30- + 100℃下，使式III的2-苯氧基甲基丙烯酸与式HZ的胺，苯酚，苯硫酚等反应，如有必要，一个基地

5. 发明专利

JPS59144731A Beta-substituted phenoxy-alpha-methylenepropionic acid derivative 失效
标题翻译：取代的苯氧基 - 氨基甲酸衍生物衍生物
公开(公告)号：JPS59144731A
公开(公告)日：1984-08-18
申请号：JP1860083
申请日：1983-02-07
申请人： Daicel Chem Ind Ltd
发明人： YAGIHARA HIROMU , HIRAKO YOSHIYUKI , MORISHIMA YASUO , MASAMOTO KAZUHISA
IPC分类号： C07C69/734 , A01N37/06 , A01N39/02 , A01N43/34 , A01N43/40 , A01N43/42 , A01N43/54 , A01N43/60 , A01N43/78 , C07C51/00 , C07C51/347 , C07C59/60 , C07C59/68 , C07C67/00 , C07C67/34 , C07C201/00 , C07C205/36 , C07C205/38 , C07C213/00 , C07C217/84 , C07C217/92 , C07C313/00 , C07C323/20 , C07D213/64 , C07D215/20 , C07D215/22 , C07D215/36 , C07D239/34 , C07D241/44 , C07D277/68
摘要： NEW MATERIAL:The β-substituted phenoxy-α-methylenepropionic acid derivative of formula I (A is phenyl, benzyl, pyridyl, naphthyl, quinolynyl, pyrimidyl, benzothiazolyl or quinoxalinyl; X is O, S, NH or NCH
3 ; R is H or 1W4C alkyl).
EXAMPLE: 2-Methylene-3-[4-(2-naphthylamino)phenoxy]propionic acid.
USE: Useful as a plant-growth regulator. Remarkably effective to suppress the growth of plants, and utilizable also as a herbicide.
PREPARATION: The compound of formula I can be prepared e.g. by reacting the substituted phenol of formula II with β,β'-dibromoisobutyric acid in the presence of a solvent such as ethanol and an alkali (e.g. 3mol of NaOH based on 1mol of the phenol), and esterifying the resultant β-substituted α-methylene-propionic acid.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新物质：式Ⅰ的β-取代苯氧基-α-亚甲基丙酸衍生物（A为苯基，苄基，吡啶基，萘基，喹啉基，嘧啶基，苯并噻唑基或喹喔啉; X为O，S，NH或NCH 3; R为H或 1-4C烷基）。实施例：2-亚甲基-3- [4-（2-萘基氨基）苯氧基]丙酸。用途：作为植物生长调节剂有用。显着有效地抑制植物的生长，也可用作除草剂。制备：式I化合物可以制备如通过在溶剂如乙醇和碱（例如基于1mol苯酚的3mol NaOH）存在下使式II的取代的苯酚与β，β'-二溴异丁酸反应，并酯化所得β-取代的α- 亚甲基丙酸。

6. 发明专利

JPS59134748A Beta-substituted-alpha-methylenepropionic acid ester 失效
标题翻译：甲基替代阿尔法 - 甲基戊酸酯
公开(公告)号：JPS59134748A
公开(公告)日：1984-08-02
申请号：JP611083
申请日：1983-01-18
申请人： Daicel Chem Ind Ltd
发明人： YAGIHARA HIROMU , HIRAKO YOSHIYUKI , MORISHIMA YASUO , MASAMOTO KAZUHISA
IPC分类号： C07C69/734 , A01N37/06 , A01N43/14 , A01N43/16 , A01N43/40 , A01N43/42 , C07C67/00 , C07C69/736 , C07C239/00 , C07C239/20 , C07C253/00 , C07C255/54 , C07C313/00 , C07C323/54 , C07C323/56 , C07C323/61 , C07C323/62 , C07D213/70 , C07D215/20 , C07D311/16
摘要： NEW MATERIAL:A compound shown by the formula IV (X is O, or S; A is cyclic hydrocarbon group of phenyl, benzyl, naphthyl and cyclohexyl, monofunctional group obtained by removing H from cyclic compound of pyridine, quinoline, 4-methylcoumain, and 9-fluorenone, or diethylamino; with the proviso that two or less H of aromatic A may be replaced with substituent group such as CH
3 , OCH
3 , SCH
3 , CF
3 , Cl, etc.).
EXAMPLE: 2-Methylene-3-(4-fluorophenoxy)propionic acid methyl ester.
USE: A plant growth regulator. Expected to be useful as a herbicide.
PROCESS: For example, a phenol or thiophenol shown by the formula I is reacted with β,β-dibromoisobutyric acid shown by the formula II in a solvent such as ethanol, etc. in the presence of an alkali such as NaOH, etc. to give a compound shown by the formula III, which is esterified, to give a compound shown by the formula IV.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新材料：式IV化合物（X为O或S; A为苯基，苄基，萘基和环己基的环状烃基，通过从吡啶的环状化合物除去H而得到的单官能团，喹啉，4-甲基香豆素，和9-芴酮或二乙基氨基;条件是两个或更少的芳族A的H可以被诸如CH 3，OCH 3，SCH 3，CF 3，Cl等的取代基代替。实施例：2-亚甲基-3-（4-氟苯氧基）丙酸甲酯。用途：植物生长调节剂。预期用作除草剂。方法：例如，式I所示的苯酚或苯硫酚在溶剂如乙醇等中，在碱如NaOH等的存在下，与式II所示的β，β-二溴异丁酸反应，得到得到式III化合物，其被酯化，得到式IV所示的化合物。

7. 发明专利

JPS58194801A Plant growth suppressing agent 失效
标题翻译：植物生长抑制剂
公开(公告)号：JPS58194801A
公开(公告)日：1983-11-12
申请号：JP7721882
申请日：1982-05-07
申请人： Daicel Chem Ind Ltd
发明人： YAGIHARA HIROSHI , HIRAKO YOSHIYUKI , MORISHIMA YASUO , MASAMOTO KAZUHISA , MATSUNAKA SHIYOUICHI , UDA TAKASHI , KOSUGI HIROSHI
IPC分类号： A01N39/02 , A01N39/00 , A01N41/10 , A01N43/40
摘要： PURPOSE: To provide an agent having growth suppressing activity and herbicidal activity to plants, and especially effective to gramineous plants, by using an α- methylenepropionic acid derivative as an active component.
CONSTITUTION: The objective agent contains the α-methylenepropionic acid derivative of formula [A is phenyl, naphthyl, pyridyl, benzyl or cyclohexyl which may have substituent group selected from lower alkyl, lower alkoxy and halogen on the ring; X is -S(O)
n - (n is 0W2) or -O-; R is lower alkyl or H] as an active component. The active component of formula includes novel compounds, and can be synthesized e.g. by reacting a phenol of formula A-X'H with β-bromo-α- methylenepropionic acid in the presence of a solvent and an alkali.
COPYRIGHT: (C)1983,JPO&Japio
摘要翻译：目的：通过使用α-亚甲基丙酸衍生物作为活性成分，提供对植物具有生长抑制活性和除草活性，特别是对禾本科植物有效的药剂。构成：目标剂含有式[A为苯基，萘基，吡啶基，苄基或环己基的α-亚甲基丙酸衍生物，其可以具有选自环上的低级烷基，低级烷氧基和卤素的取代基; X是-S（O）n - （n是0-2）或-O-; R是低级烷基或H]作为活性组分。式的活性组分包括新化合物，可以合成例如通过在溶剂和碱的存在下使式A-X'H的苯酚与β-溴-α-亚甲基丙酸反应。

8. 发明专利

JPS59157051A Beta-oxy-alpha-methylenepropionic acid 失效
标题翻译： BETA-OXY-ALPHA-METHYLENEPROPIONIC ACID
公开(公告)号：JPS59157051A
公开(公告)日：1984-09-06
申请号：JP2939083
申请日：1983-02-25
申请人： Daicel Chem Ind Ltd
发明人： YAGIHARA HIROMU , HIRAKO YOSHIYUKI , MORISHIMA YASUO , MASAMOTO KAZUHISA
IPC分类号： A01N39/02 , C07C51/00 , C07C59/42 , C07C59/66 , C07C59/68 , C07C67/00 , C07C213/00 , C07C217/84 , C07C313/00 , C07C323/20
摘要： NEW MATERIAL:A β-oxy-α-methylenepropionic acid shown by the formula I (A is benzene nucleus-containing group such as fluorophenyl, methylthiophenyl, naphthylaminophenyl, or biphenyl, or tetrahydronaphthyl).
EXAMPLE: 2-Methylene-3-(4-fluorophenoxy)propionic acid.
USE: Useful as a herbicide or plant growth regulator. Excellent for controlling the growth of plant.
PREPARATION: A phenol shown by the formula II is reacted with β, β-dibromoisobutyric acid in a solvent such as ethanol, etc. in the presence of preferably three times the molar amount of NaOH, to give a compound shown by the formula I .
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：新材料：由式I表示的β-氧-α-亚甲基丙酸（A为含苯基的基团，例如氟苯基，甲硫基苯基，萘基氨基苯基或联苯基或四氢萘基）。实施例：2-亚甲基-3-（4-氟苯氧基）丙酸。用途：用作除草剂或植物生长调节剂。非常适用于控制植物生长。制备：在优选三倍摩尔量的NaOH的存在下，将式II所示的苯酚与β，β-二溴异丁酸在溶剂如乙醇等中反应，得到式I所示的化合物。

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