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1. 发明专利

JPH07313219A MULTI-COLOR MIRROR BALL AND MANUFACTURE THEREOF 失效
公开(公告)号：JPH07313219A
公开(公告)日：1995-12-05
申请号：JP10689494
申请日：1994-05-20
申请人： CITIZEN WATCH CO LTD
发明人： TAMAI YOICHI , ENOMOTO MITSUGI , MIYAMOTO KONOE
IPC分类号： G02B27/00 , A44C1/00 , A44C27/00 , C23C14/14
摘要： PURPOSE:To provide a multi-color mirror ball, by which design can be varied, and the mechanical strength can be made excellent. CONSTITUTION:A multi-color mirror ball is made by using a gold alloy as a raw material 10, and formed by a polyhedron comprising a carbon hard coat 13, the surface of which has a spherical surface, and which is formed by dry plating, and a mirror finished surface 10a formed by a mechanical means, where the raw material 10 is exposed, and the carbon hard coat 13 and the mirror finished surface 10 are different in color tone.

2. 发明专利

JPH05287526A 失效
公开(公告)号：JPH05287526A
公开(公告)日：1993-11-02
申请号：JP8253392
申请日：1992-04-04
申请人： CITIZEN WATCH CO LTD
发明人： ENOMOTO MITSUGI , SHINOMIYA HIDEO
IPC分类号： C23C14/32 , C23C14/24 , C23C14/50
摘要： PURPOSE:To enable the formation of uniform thin films on as many materials to be treated as possible at one time and to improve the maintenance property of the device. CONSTITUTION:The materials 16 to be treated are respectively mounted to plural mounting means 61 turned by endless chains 62, 72 of a jig 6, by which the thin films can be formed on the many materials 16 to be treated at one time. The jig 60 is mounted turnably onto a stationary table 67 fixed in a bell- jar 11. The treatment is executed by rotating this jig to the rotating position optimum for thin film formation, by which the uniform thin films are formed on the materials 16 to be treated. The conduction of the operation simply by rotating the jig 60 is then enabled without removing the jig from the bell-jar.

3. 发明专利

JPH04218683A MULTICOLORED ORNAMENT AND ITS PRODUCTION 失效
公开(公告)号：JPH04218683A
公开(公告)日：1992-08-10
申请号：JP8136591
申请日：1991-03-22
申请人： CITIZEN WATCH CO LTD
发明人： NAOI KOICHI , ENOMOTO MITSUGI , TAGAWA HIROSHI
IPC分类号： A44C27/00 , C23C14/04 , C23C14/06 , C23C16/04 , C23C16/26 , C23C28/00 , C23C30/00
摘要： PURPOSE:To produce a multicolored ornament excellent in resistance to wear and corrosion with a simple technique by forming a carbon hard layer on the surface of the ornament base material, removing a part of the layer and then forming the layer of a metal plating, a coating, a cloisonne, etc., in the cavity. CONSTITUTION:An intermediate layer 2 of Si, SiO2, Ge, TiN, TiC, TiCN, WC, etc., is formed on the surface of a stainless steel member 1 as the ornament base material, and a carbon hard layer 3 is formed thereon by CVD, PVD method, etc. A part of the carbon layer 3 and intermediate layer 2 is removed by a laser beam 4, and the plating layer of groups IVa, Va and VIa metals, their nitride, carbide, carbonitride and carbonitroxide, metals such as Fe, Co, Ni, Ru, Rh, Pd, Pt, Au and Ag and their alloy, a coating, cloisonne, etc., are formed in the cavity as the layer 5. A multicolored ornament is easily produced in this way without the need for a troublesome procedure such as masking.

4. 发明专利

JPH0153350B2 失效
公开(公告)号：JPH0153350B2
公开(公告)日：1989-11-14
申请号：JP10515582
申请日：1982-06-18
申请人： CITIZEN WATCH CO LTD
发明人： SASANUMA KYOJU , KOSHI MASAO , TAKAHASHI AKIKIMI , SHIMIZU SHOTARO , ENOMOTO MITSUGI , YOSHIKAWA YOJI
IPC分类号： C23C14/32 , H01J37/32

5. 发明专利

JPH04128375A MULTICOLORED ORNAMENTS AND ITS PRODUCTION 失效
公开(公告)号：JPH04128375A
公开(公告)日：1992-04-28
申请号：JP24634490
申请日：1990-09-18
申请人： CITIZEN WATCH CO LTD
发明人： TAKIE ATSUSUKE , IKEDA SHINJI , ENOMOTO MITSUGI , TAGAWA HIROSHI
IPC分类号： G04B37/22 , C23C14/04 , C23C14/06 , C23C14/58
摘要： PURPOSE:To obtain the ornaments constituted of a golden color tone film substantially consisting of titanium nitride and a gray color tone film by irradiating a part of the surface of a black color tone film substantially consisting of titanium, nitrogen, carbon, and oxygen, with a laser beam. CONSTITUTION:An atmosphere contg. nitrogen, oxygen and carbon dioxide is formed in a vacuum vessel. Metal titanium is thereafter bombarded by an electron beam and is heated to evaporate the titanium. A DC voltage is then impressed between an evaporating source of the metal titanium which is an anode and a base material 1 which is a cathode, and an ion current is passed to form the black color tone film 2 consisting of the titanium, nitrogen, carbon, and oxygen on a base material 1. The base material 1 formed with the black color tone film 2 is taken out and the black color tone film 2 is irradiated with the laser according to the specified patterns on the black color tone film by using a YAG laser device. The part irradiated with the laser constitutes the golden color tone film 3 and the multicolored ornaments having the beautiful black color tone and golden color tone are obtd. The multicolored ornaments having the beautiful three tones of the black color tone, the gray color tone and the golden color tone are obtd. by changing the output of the laser and irradiating the laser.

6. 发明专利

JPH03291369A ORNAMENT 失效
公开(公告)号：JPH03291369A
公开(公告)日：1991-12-20
申请号：JP9300590
申请日：1990-04-10
申请人： CITIZEN WATCH CO LTD
发明人： ENOMOTO MITSUGI , AIHARA MASAKADO , TAGAWA HIROSHI
IPC分类号： A44C5/00 , C23C14/06 , C23C14/14 , C23C14/24 , C23C14/58
摘要： PURPOSE:To produce a superior ornament capable of withstanding long time use by forming a hard film of a color similar to that of a coated film by a dry plating method on the position between a base material and the coated film at the time of producing the ornament in which the coated film is applied to the base material. CONSTITUTION:For example, a watchband 11 made of stainless steel is put into a vacuum tank in an ion plating apparatus and the inside of this vacuum tank is evacuated to carry out required cleaning, and then, a gaseous mixture of argon, nitrogen, and ethylene is ionized and allowed to react with similarly ionized titanium, by which a hard film consisting of a brown titanium carbonitride film 12 of about 1.5mu film thickness is formed on the watchband 11. Subsequently, this watchband 11 is taken out from the vacuum tank and is subjected to electrostatic coating with an acrylic brown coating having a color tone similar to that of the brown titanium carbonitride film 12 and then to baking, by which a brown coated film 13 is formed. By this method, the brown watchband excellent in wear resistance and corrosion resistance and capable of long use in the attractive state can be obtained.

7. 发明专利

JPH01111869A BARREL TYPE ION PLATING DEVICE 失效
公开(公告)号：JPH01111869A
公开(公告)日：1989-04-28
申请号：JP26631287
申请日：1987-10-23
申请人： CITIZEN WATCH CO LTD
发明人： SAWADA HIDETAKA , IKEDA SHINJI , ENOMOTO MITSUGI , YOSHIKAWA YOJI
IPC分类号： C23C14/32
摘要： PURPOSE:To improve the efficiency of film formation and to form a uniform film having high adhesiveness by disposing an arc discharge evaporation source in a rotating body. CONSTITUTION:A rotary shaft 11 at one end of the rotating body 2 of an approximately circular cylinderical shape in a vacuum vessel 1 is rotated by a motor 3 via a bearing 8 and the other end of the rotating body 2 is supported by a supporting base 9 and a roller 10 at the sliding contact point internally provided thereto. The negative bias from the base 9 and the roller 10 is impressed to the rotating body 2. On the other hand, the arc discharge evaporation source 4 is constituted by integrating an electrode 4a and a metal 4b to be evaporated. Cooling water from a water cooling copper tube 6 is introduced to the water path on the joint surfaces thereof, by which said electrode and metal are cooled. Small-sized objects 7 to be treated are put into the rotating body 2 and are brought into contact with the rotating body 2, by which the negative bias is impressed thereto. The metal 4b is then evaporated and ionized by utilizing the arc discharge, by which the thin films are formed on the surfaces of the objects 7. Since the metal 4b is not melted at this time, the positions and directions are freely settable according to conditions. The efficiency of the film formation is thus improved.

8. 发明专利

JPS63117784A SCISSORS 失效
公开(公告)号：JPS63117784A
公开(公告)日：1988-05-21
申请号：JP26461486
申请日：1986-11-06
申请人： CITIZEN WATCH CO LTD
发明人： ENOMOTO MITSUGI , KOMINE ISAO , ARAKAWA ISAMU
IPC分类号： B26B13/00

9. 发明专利

JPS63464A VACUUM FORMING DEVICE FOR THIN FILM 失效
公开(公告)号：JPS63464A
公开(公告)日：1988-01-05
申请号：JP14181986
申请日：1986-06-18
申请人： CITIZEN WATCH CO LTD
发明人： ENOMOTO MITSUGI , YOSHIKAWA YOJI , SHINOMIYA HIDEO
IPC分类号： C23C14/32 , C23C14/24
摘要： PURPOSE:To prevent the quality deterioration of a thin film formed on a work by forming a vacuum vessel of a vacuum forming device for thin films into a specific construction to prevent the intrusion of harmful moisture and gas into the vessel at the time of an exchanging, etc., of the work in the vessel. CONSTITUTION:The body 11a of the vacuum vessel 11 of the vacuum forming device for thin films by a vapor deposition, sputtering, or ion plating method is so constructed that said body can be largely opened and closed by a large door 12. A frame part 13a projecting outward is provided to the large door 12 and further, a slender small window 13 and small door 14 are installed thereto. An evaporating source 6 and a mechanism for supporting the work are provided in the vacuum vessel 11. A device 17 for replenishing an evaporating material is disposed in the evaporating source 6. The exchange operation can be carried out through the small window 13 without the need for opening the large door 12 to exchange the work if such device is used. The replenishment of the evaporating material can be made while the large door 12 is held closed. To use the small window/3, an inert gas is ejected from many small holes 16a of the pipe 16 provided to the inside wall of the body 11a to maintain the pressure in the vessel under the atmospheric pressure or above. The deterioration of the vapor deposited film by the oxygen and moisture contained in the air to be intruded into the vessel 11 is thereby prevented.

10. 发明专利

JP2000008250A REED FOR HIGH-SPEED LOOM 失效
公开(公告)号：JP2000008250A
公开(公告)日：2000-01-11
申请号：JP12563599
申请日：1999-05-06
申请人： CITIZEN WATCH CO LTD
发明人： MIYA YUKIO , KIZAKI SHIGERU , SUGIYAMA OSAMU , HATAYAMA AKITERU , SHIBUYA YOSHITSUGU , ENOMOTO MITSUGI , NAOI KOICHI , FUKAZAWA YUJI , MINAMITANI TAKANORI , SHIMIZU SHOTARO , TAGAWA HIROSHI
IPC分类号： D03D49/62
摘要： PROBLEM TO BE SOLVED: To provide a reed for high-speed looms, comprising reed blades, suitable for diversified types of fibers (e.g. natural and synthetic fibers, and fibers of new materials) and improved in durability and resistance to wear. SOLUTION: This reed for high-speed looms comprises a number of reed blades, with a thin plate of metal (e.g. stainless steel) as the base 24, parent blades on both right and left sides, and a pair of edge metals on the upper and lower ends for each reed blade, wherein the reed blade which is adjacent to the parent blade and arranged orderly one by one towards the reed center is coated with a diamond-like film 28 via an intermediate layer 26, at least for the section containing the portion which would be otherwise worn most severely.

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