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    • 2. 发明专利
    • Photobase generating agent and photocurable resin composition
    • 光电发生剂和光催化树脂组合物
    • JP2010095686A
    • 2010-04-30
    • JP2008270101
    • 2008-10-20
    • Asahi Kasei E-Materials Corp旭化成イーマテリアルズ株式会社
    • SHIMIZU KATSUYAHIGASHIMOTO HISANORI
    • C08G59/68C07C225/22C08G18/18C08G73/10G03F7/004G03F7/038
    • PROBLEM TO BE SOLVED: To provide a photobase generating agent expressing good photocurability in photocuring of a photocurable resin, and a photocurable resin composition prepared by using the generating agent. SOLUTION: The photobase generating agent includes a 2-aminotropon derivative represented by formula (1) (wherein X is a 1-20C carbon atom group; R 1 and R 2 are each independently hydrogen, alkyl, alkenyl, cycloalkyl, aralkyl or aryl; R 3 -R 12 are each independently hydrogen, carboxy, alkoxycarbonyl, cyano, formyl, acyl, nitro, nitroso, alkyl, alkenyl, cycloalkyl, aralkyl, aryl, hydroxy, mercapto, alkyl thioether, alkoxy, halogen, or amino; and at least two of R 1 -R 12 may be bonded to each other to form a saturated or unsaturated ring). COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种在光固化性树脂的光固化中表现出良好的光固化性的光致产生剂和使用该发生剂制备的光固化性树脂组合物。 解决方案:光产碱剂包括由式(1)表示的2-氨基酮衍生物(其中X为1-20C碳原子基团; R 1 和R 2 < SP>各自独立地为氢,烷基,烯基,环烷基,芳烷基或芳基; R 3为各自独立地为氢,羧基,烷氧基羰基,氰基,甲酰基,酰基 ,硝基,亚硝基,烷基,烯基,环烷基,芳烷基,芳基,羟基,巯基,烷基硫醚,烷氧基,卤素或氨基;以及至少两个R 1, / SP>可以彼此键合以形成饱和或不饱和的环)。 版权所有(C)2010,JPO&INPIT
    • 3. 发明专利
    • High polarity prepolymer and photosensitive resin composition containing it
    • 高极性预聚物和含有它的感光树脂组合物
    • JP2009235295A
    • 2009-10-15
    • JP2008085196
    • 2008-03-28
    • Asahi Kasei E-Materials Corp旭化成イーマテリアルズ株式会社
    • SHIMIZU KATSUYA
    • C08G18/71B41N1/12C08F290/06C08G18/46C09K11/06H01L21/027H01L29/786H01L31/10H01L51/42H01L51/50H05B33/10
    • Y02E10/549
    • PROBLEM TO BE SOLVED: To produce a polymer having excellent solvent resistance by using a prepolymer having excellent solvent resistance, to provide a printing plate and a printing master plate improved in printing precision and printing durability by using the above polymer, and to provide methods for producing the following with high precision: a conductive layer; an organic luminescent layer; a photoelectric conversion layer for an organic thin film solar battery; a thin film semiconductor patterned layer; a photosensitive layer of an electrophotographic photoreceptor; an electron-accepting organic layer and/or an electron-donating organic layer constituting a photovoltaic element for a photosensor; a polysilane thin film of an optical switching element; and an organic luminescent layer for a lighting system, a display device, a backlight in a display device, an interior/exterior plane emission light source. SOLUTION: The prepolymer for producing a printing plate or printing master plate consists of a repeating unit with a solubility parameter of ≥20 J 1/2 /cm 3/2 . A photosensitive resin composition for producing a printing plate or printing master plate contains a polymer (a) formed of the prepolymer. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题为了通过使用具有优异的耐溶剂性的预聚物制备具有优异的耐溶剂性的聚合物,提供通过使用上述聚合物提高印刷精度和印刷耐久性的印刷版和印刷母版,以及 提供高精度生产下列方法:导电层; 有机发光层; 用于有机薄膜太阳能电池的光电转换层; 薄膜半导体图案层; 电子照相感光体的感光层; 构成光电传感器的光电元件的受电子有机层和/或给电子有机层; 光开关元件的聚硅烷薄膜; 以及用于照明系统的有机发光层,显示装置,显示装置中的背光,内部/外部平面发射光源。 解决方案:用于制备印刷版或印刷母版的预聚物由溶解度参数≥20J的重复单元 / SP> 3/2 。 用于制造印刷版或印刷母版的感光性树脂组合物含有由预聚物形成的聚合物(a)。 版权所有(C)2010,JPO&INPIT
    • 4. 发明专利
    • Method for producing substituted cyclopentanone
    • 生产取代环己烷酮的方法
    • JP2011137033A
    • 2011-07-14
    • JP2011047306
    • 2011-03-04
    • Asahi Kasei E-Materials Corp旭化成イーマテリアルズ株式会社
    • SHIMIZU KATSUYAMATSUSHITA FUMIO
    • C07C67/327C07C49/753C07C69/738C11B9/00
    • C07C67/08C07B53/00C07C45/513C07C45/65C07C45/676C07C45/68C07C45/71C07C49/395C07C49/597C07C49/647C07C49/753C07C51/09C07C67/00C07C67/303C07C67/31C07C67/327C07C67/343C07C69/738C07C2601/08C07C2601/10C07D303/04C07D307/33C07C59/347C07C69/716
    • PROBLEM TO BE SOLVED: To provide a method for producing cis-2,3-disubstituted cyclopentanone.
      SOLUTION: The method for producing cis-2,3-disubstituted cyclopentanone includes the following nine processes: the first process for etherifying 3-cyclopentanedione; the second process for transferring the compound; the third process for etherifying the compound; the fourth process for adding a malonic ester to the compound and simultaneously subjecting the compound to decarboxylation to produce a substituted cyclopentenone; the fifth process for selectively oxidizing a double bond of a side chain of the substituted cyclopentenone; the sixth process for hydrolyzing an oxirane ring of the compound to produce a diol; the seventh process for hydrogenating the double bond in a five-membered ring of the compound; the eighth process for changing the diol of the compound into dioxolane; and the ninth process for decomposing the compound in the presence of a carboxylic anhydride to produce a substituted cyclopentanone represented by formula (29). In formula (29), R
      46 is hydrogen or a 1C-8C substituted group and may be the same as R
      44 ; R
      47 is hydrogen or a 1C-8C substituted group and may be the same as R
      45 ; and R
      46 may be the same as R
      47 .
      COPYRIGHT: (C)2011,JPO&INPIT
    • 待解决的问题:提供顺式-2,3-二取代环戊酮的制备方法。 解决方案:顺式-2,3-二取代环戊酮的制备方法包括以下九个方法:第一种醚化3-环戊二酮的方法; 转移化合物的第二种方法; 化合物醚化的第三种方法; 向化合物中加入丙二酸酯并同时使化合物脱羧以产生取代的环戊烯酮的第四种方法; 选择性氧化取代环戊烯酮侧链双键的第五种方法; 水解该化合物的环氧乙烷环以制备二醇的第六种方法; 用于氢化化合物的五元环中的双键的第七种方法; 将化合物的二醇变为二氧戊环的第八个方法; 和在羧酸酐存在下分解化合物以制备由式(29)表示的取代的环戊酮的第九种方法。 在式(29)中,R 46是氢或1C-8C取代的基团,可以与R 44相同; R 47 是氢或1C-8C取代的基团,并且可以与R 45相同; 和R 46 可以与R 47 相同。 版权所有(C)2011,JPO&INPIT
    • 6. 发明专利
    • Printer and printed matter making method
    • 打印机和打印件制作方法
    • JP2009241470A
    • 2009-10-22
    • JP2008091955
    • 2008-03-31
    • Asahi Kasei E-Materials Corp旭化成イーマテリアルズ株式会社
    • SHIMIZU KATSUYA
    • B41F17/14B41M1/04
    • PROBLEM TO BE SOLVED: To provide a printer suitable for printing of an electronic device or the like requiring a pattern formation of high precision on a prescribed position of a printing base material, and to provide a method for making printed matter using the printer.
      SOLUTION: The printer includes a reciprocal linear stage, a stage driving unit for driving the linear stage, a rotatably pivoted plate cylinder, and a plate cylinder driving unit for rotating the plate cylinder, wherein a printing base material is mounted on the linear stage, and an ink on a printing plate loaded or formed on the plate cylinder is transferred on the printing base material. The printer also includes a synchronization mechanism for driving the stage driving unit and the plate cylinder driving unit while synchronizing, a mechanism for adjusting the distance between the plate cylinder and the printing base material, and a mechanism for adjusting a mounting position and a mounting angle of the printing base material on the linear stage.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供一种适合于在印刷基材的规定位置上需要高精度图案形成的电子设备等的印刷,并提供一种使用该印刷基材制造印刷品的方法 打印机。 解决方案:打印机包括一个往复式线性平台,用于驱动线性平台的平台驱动单元,一个可旋转枢转的印版滚筒,以及一个用于旋转印版滚筒的印版滚筒驱动单元,其中打印基材安装在 并且在印版滚筒上装载或形成的印版上的墨水被转印到印刷基材上。 打印机还包括用于驱动平台驱动单元和印版滚筒驱动单元同步的同步机构,用于调节印版滚筒和印刷基材之间的距离的机构,以及用于调节安装位置和安装角度的机构 的印刷基材在线性阶段上。 版权所有(C)2010,JPO&INPIT
    • 7. 发明专利
    • Print method
    • 打印方法
    • JP2009184116A
    • 2009-08-20
    • JP2008023153
    • 2008-02-01
    • Asahi Kasei E-Materials Corp旭化成イーマテリアルズ株式会社
    • SHIMURA TADASHITOMITA YOKOSHIMIZU KATSUYA
    • B41N1/12B41C1/05B41M1/04B41M1/08B41M1/10B41N1/14B41N1/16
    • PROBLEM TO BE SOLVED: To reduce the density nonuniformity of dots which occurs by the vibration of a printing machine when printing is carried out by the use of the printing machine equipped with a forme produced from a resin composition for a laser carving printing original plate. SOLUTION: In a print method, the forme produced from the resin composition for the laser carving printing original plate containing a resin (a) which contains a polycarbonate diol composed of a repeating unit expressed by formula (1) and a polymerizable unsaturated group and has a number average molecular weight of 300-50,000, an organic compound (b) which has a polymerizable unsaturated group and a number average molecular weight of below 1,000 and a photopolymerization initiator (c) is arranged on a cylinder, the printing machine in which ink is transferred onto the base material for printing by rotating the cylinder is used, and the print speed of the printing machine is 10-1,000 m/min. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:为了减少由印刷机的振动而产生的点的密度不均匀性,通过使用装备有由激光雕刻印刷用树脂组合物制成的印版的印刷机进行印刷 原版 解决方案:在印刷方法中,由含有由式(1)表示的重复单元构成的聚碳酸酯二醇和聚合性不饱和基团的树脂(a)的激光雕刻印刷原版用树脂组合物 基团,数均分子量为300〜50000,具有聚合性不饱和基,数均分子量为1000以下的有机化合物(b)和光聚合引发剂(c)配置在圆筒上,印刷机 使用油墨通过旋转气缸而转印到基材上进行印刷,并且印刷机的印刷速度为10-1,000m / min。 版权所有(C)2009,JPO&INPIT
    • 9. 发明专利
    • Photocurable type resin composition and cured product thereof
    • 光固型树脂组合物及其固化产品
    • JP2010174210A
    • 2010-08-12
    • JP2009021311
    • 2009-02-02
    • Asahi Kasei E-Materials Corp旭化成イーマテリアルズ株式会社
    • SHIMIZU KATSUYAHIGASHIMOTO HISANORI
    • C08G59/66
    • PROBLEM TO BE SOLVED: To provide a photocurable type resin composition with a clear difference in the curability due to the presence or absence of light irradiation.
      SOLUTION: The photocurable type resin composition includes (a) a compound of a 2-aminotropone derivative shown by formula (1), (b) a compound having two or more structures of 3-mercaptopropionic acid ester in the molecule and (c) a resin having two or more functional groups reactive with a thiol group, wherein R
      1 and R
      2 are each independently hydrogen, alkyl or aryl, R
      3 -R
      7 are each independently hydrogen, carboxyl, alkoxycarbonyl, cyano, formyl, acyl, nitro, nitroso, alkyl, aryl, hydroxy, thiol, alkoxy, halogen or amino, and R
      1 -R
      7 may be bound to each other to form a saturated ring or an unsaturated ring, and may independently have an univalent group made by elimiating one hydrogen atom from the compound shown by formula (1) as a substituent.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供由于存在或不存在光照射而导致的固化性差的光固化型树脂组合物。 光固化型树脂组合物包含(a)式(1)所示的2-氨基酮衍生物的化合物,(b)分子中具有2个以上结构的3-巯基丙酸酯的化合物和( c)具有两个或更多个与硫醇基反应的官能团的树脂,其中R SP 1和R SP 2各自独立地为氢,烷基或芳基,R 3 硝基,亚硝基,烷基,芳基,羟基,硫醇,烷氧基,卤素或氨基,R 1和R 2各自独立地为氢,羧基,烷氧基羰基,氰基, SP> 1 -R 7 可以彼此结合以形成饱和环或不饱和环,并且可以独立地具有通过从所示化合物中除去一个氢原子而形成的一价基团 通过式(1)作为取代基。 版权所有(C)2010,JPO&INPIT
    • 10. 发明专利
    • Laser-engraved printing original plate
    • 激光雕刻原版
    • JP2009214461A
    • 2009-09-24
    • JP2008061683
    • 2008-03-11
    • Asahi Kasei E-Materials Corp旭化成イーマテリアルズ株式会社
    • MORI MASAHIROSHIMIZU KATSUYA
    • B41N1/12B41C1/05C08F290/06C08G18/81
    • B41C1/05B41N1/22
    • PROBLEM TO BE SOLVED: To provide a laser-engraved printing original plate which can be subjected to near-infrared laser engraving, excellent in solvent resistance and is sufficiently suppressed from being swollen by various solvents contained in a solvent ink used in printing. SOLUTION: The laser-engraved printing original plate is obtained by thermosetting a resin layer consisting of a resin composition. The resin composition includes a polycarbonate diol consisting of a repeating unit represented by general formula (1) and also includes resin (a) with a number average molecular weight of 300 to 300,000, an organic compound (b) with a number average molecular weight below 10,000 and having polymerizable unsaturated groups, a laser absorbing agent (c), and a thermopolymerization initiator (d). COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种能够经受近红外激光雕刻的激光雕刻印刷原版,具有优异的耐溶剂性,并且被充分地抑制在用于印刷的溶剂油墨中所含的各种溶剂溶胀 。

      解决方案:通过将由树脂组合物构成的树脂层热固化而获得激光雕刻印刷原版。 树脂组合物包括由通式(1)表示的重复单元构成的聚碳酸酯二醇,数均分子量为300〜300,000的数均分子量的数均分子量(b)的数均分子量的有机化合物(b) 10,000,具有聚合性不饱和基团,激光吸收剂(c)和热聚合引发剂(d)。 版权所有(C)2009,JPO&INPIT