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    • 1. 发明专利
    • Semiconductor storage element, and method of manufacturing the same
    • 半导体存储元件及其制造方法
    • JP2010087089A
    • 2010-04-15
    • JP2008252411
    • 2008-09-30
    • Toshiba Corp株式会社東芝
    • INO TSUNEHIROFUJII AKISUKEFUJIKI JUNTAKASHIMA AKIRASHINGU MASAOMATSUSHITA DAISUKEYASUDA NAOKIMURAOKA KOICHI
    • H01L21/8247H01L27/115H01L29/788H01L29/792
    • H01L29/792H01L29/517H01L29/66833
    • PROBLEM TO BE SOLVED: To provide a semiconductor storage element that can accumulate and erase electric charge with higher efficiency than a conventional charge storage film using SiN, and holds the accumulated electric charge for a long time, and to provide a method of manufacturing the semiconductor storage element.
      SOLUTION: The semiconductor storage element includes: a source region and a drain region provided in a semiconductor substrate; a tunnel insulating film provided on the semiconductor substrate between the source region and the drain region; a charge storage film provided on the tunnel insulating film; a block insulating film provided on the charge storage film; a gate electrode provided on the block insulating film; and a region containing gas molecules, the region being provided in a neighborhood of an interface between the charge storage film and the block insulating film.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种半导体存储元件,其可以比使用SiN的常规电荷存储膜更高的效率地累积和擦除电荷,并且长时间保持积累的电荷,并且提供一种方法 制造半导体存储元件。 解决方案:半导体存储元件包括:设置在半导体衬底中的源极区域和漏极区域; 设置在所述源极区域和所述漏极区域之间的所述半导体衬底上的隧道绝缘膜; 设置在隧道绝缘膜上的电荷存储膜; 设置在电荷存储膜上的块状绝缘膜; 设置在所述块绝缘膜上的栅电极; 以及包含气体分子的区域,该区域设置在电荷存储膜和块绝缘膜之间的界面附近。 版权所有(C)2010,JPO&INPIT
    • 2. 发明专利
    • Semiconductor device and method of manufacturing the same
    • 半导体器件及其制造方法
    • JP2010192579A
    • 2010-09-02
    • JP2009033840
    • 2009-02-17
    • Toshiba Corp株式会社東芝
    • SHINGU MASAOTAKASHIMA AKIRAMURAOKA KOICHI
    • H01L21/8247H01L27/115H01L29/788H01L29/792
    • H01L29/788H01L21/28273H01L21/28282H01L27/11521H01L27/11568H01L29/42324H01L29/4234H01L29/513H01L29/66825
    • PROBLEM TO BE SOLVED: To provide a semiconductor device wherein some reliability deterioration is controlled that is caused by an interface between a top insulating layer and an element separation insulating layer.
      SOLUTION: The semiconductor device includes: a semiconductor substrate 11; a laminated structure wherein a tunnel insulating film 12, a charge storage layer 13, a top insulating layer 14, and a control electrode 15 are disposed and laminated in order on the semiconductor substrate; an element separation insulating layer 16 arranged on a lateral side of the laminated structure; and an impurity doping layer 11A formed on both sides of the tunnel insulating film of the semiconductor substrate. The element separation insulating layer consists at least of one of SiO
      2 , SiN, and SiON; the top insulating layer is an oxide containing at least one metal M selected from a group of a rare earth metal, Y, Zr, and Hf, and Si; and respective channel length directional lengths L
      charge , L
      top , and L
      gate of the charge storage layer, the top insulating layer, and the control electrode satisfy the formula: L
      charge , L
      gate top .
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种半导体器件,其中由顶部绝缘层和元件隔离绝缘层之间的界面引起的一些可靠性劣化被控制。 解决方案:半导体器件包括:半导体衬底11; 其中在半导体衬底上依次层叠隧道绝缘膜12,电荷存储层13,顶部绝缘层14和控制电极15的叠层结构; 布置在层叠结构的侧面上的元件分离绝缘层16; 以及形成在半导体衬底的隧道绝缘膜两侧的杂质掺杂层11A。 元件分离绝缘层至少由SiO 2,SiN和SiON中的一种构成; 顶部绝缘层是含有选自稀土金属,Y,Zr和Hf中的至少一种金属M的氧化物和Si; 以及电荷存储层,顶部绝缘层和控制层的各个沟道长度方向长度L 电荷,L 顶部和L 栅极 电极满足下列公式:L 电荷,L 栅极 顶部。 版权所有(C)2010,JPO&INPIT
    • 3. 发明专利
    • Nonvolatile semiconductor storage device and method of manufacturing the same
    • 非易失性半导体存储器件及其制造方法
    • JP2010182963A
    • 2010-08-19
    • JP2009026603
    • 2009-02-06
    • Toshiba Corp株式会社東芝
    • TAKASHIMA AKIRASHINGU MASAOMURAOKA KOICHI
    • H01L21/8247H01L21/316H01L21/8242H01L27/108H01L27/115H01L29/788H01L29/792
    • H01L21/28282H01L21/02145H01L21/02156H01L21/02161H01L21/28273H01L27/11521H01L27/11568H01L29/4234H01L29/513
    • PROBLEM TO BE SOLVED: To provide a nonvolatile semiconductor storage device that reduces a leakage current in a high electric field region or low electric field region, and to provide a method of manufacturing the same. SOLUTION: The nonvolatile semiconductor storage device includes source/drain regions 111 provided in surface regions of a semiconductor substrate 101 and provided apart from each other, a tunnel insulating film 102 provided on a channel between the source/drain regions 111, a charge storage layer 103 provided on the tunnel insulating film 102, a first dielectric film 105 provided on the charge storage layer 103 and containing lantern aluminum silicon oxide or oxynitride, a second dielectric film 106 provided on the first dielectric film 105 and containing oxide or oxynitride containing at least one of hafnium (Hf), zirconium (Zr), titanium (Ti), and rare-earth metal, and a control gate electrode 107 provided on the second dielectric film 106. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种降低高电场区域或低电场区域中的漏电流的非易失性半导体存储装置,并提供其制造方法。 解决方案:非易失性半导体存储装置包括设置在半导体衬底101的表面区域并且彼此分开设置的源极/漏极区域111,设置在源极/漏极区域111之间的沟道上的隧道绝缘膜102, 设置在隧道绝缘膜102上的电荷存储层103,设置在电荷存储层103上并包含铝氧化铝或氧氮化物的第一电介质膜105,设置在第一电介质膜105上并含有氧化物或氮氧化物的第二电介质膜106 含有铪(Hf),锆(Zr),钛(Ti)和稀土金属中的至少一种,以及设置在第二电介质膜106上的控制栅电极107.权利要求(C) JPO&INPIT
    • 6. 发明专利
    • Semiconductor device, and method for manufacturing semiconductor device
    • 半导体器件及制造半导体器件的方法
    • JP2009239216A
    • 2009-10-15
    • JP2008086770
    • 2008-03-28
    • Toshiba Corp株式会社東芝
    • SHINGU MASAOKIKUCHI SACHIKOTAKASHIMA AKIRAINO TSUNEHIROMURAOKA KOICHI
    • H01L21/8247H01L27/115H01L29/78H01L29/788H01L29/792
    • H01L29/792H01L21/28282H01L21/31604H01L29/513H01L29/517H01L29/66833
    • PROBLEM TO BE SOLVED: To suppress characteristic variation of a semiconductor device by suppressing reaction of high-dielectric-constant insulating films to other component members even after a heat treatment when the semiconductor device is manufactured by forming a gate insulating film and an interlayer insulating film of the thermally stable high-dielectric-constant insulating films.
      SOLUTION: In the semiconductor device, sidewalls are made of at least one of SiO
      2 , SiN, SiON, and a top insulating film or gate insulating film is made of an oxide of at least one metal M selected from a rare earth metal group consisting of Y, Zr, Hf, and Al, Si so that the number ratio Si/M of Si to the metal M is set to no less than a number ratio at a solid solubility limit of SiO
      2 in a composite oxide including the metal M and Al and the dielectric constant of the top insulating film or gate insulating film is equal to or less than the dielectric constant of Al
      2 O
      3 and so that the number ratio Al/M of Al to the metal M is set to no less than a number ratio Al/M where the crystallization of an oxide of the metal M is suppressed by the reaction of the Al element and set to no more than a number ratio where the crystallization of the Al
      2 O
      3 is suppressed through the action of the metal M.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:即使在通过形成栅极绝缘膜制造半导体器件时,即使在热处理之后也抑制高介电常数绝缘膜与其它部件的反应来抑制半导体器件的特性变化,以及 热稳定的高介电常数绝缘膜的层间绝缘膜。 解决方案:在半导体器件中,侧壁由SiO 2,SiN,SiON中的至少一种制成,并且顶部绝缘膜或栅极绝缘膜由至少一种 金属M选自由Y,Zr,Hf和Al,Si组成的稀土金属组,使得Si与金属M的Si / M的数量比被设定为不小于固溶度极限的数量比 包含金属M和Al的复合氧化物中的SiO 2 和顶部绝缘膜或栅极绝缘膜的介电常数等于或小于Al 2 版权所有(C)2010,JPO&INPIT
    • 7. 发明专利
    • Nonvolatile semiconductor storage device and manufacturing method of the same
    • 非线性半导体存储器件及其制造方法
    • JP2013110193A
    • 2013-06-06
    • JP2011252444
    • 2011-11-18
    • Toshiba Corp株式会社東芝
    • KUSAI HARUKASAKUMA KIWAMUSHINGU MASAOFUJII AKISUKEKIYOTOSHI MASAHIRO
    • H01L21/8247H01L21/336H01L27/115H01L29/788H01L29/792
    • PROBLEM TO BE SOLVED: To inhibit lateral displacement of a charge in a charge storage layer.SOLUTION: A nonvolatile semiconductor storage device according to an embodiment comprises: first through n-th semiconductor layers (n is a natural number more than 1) 12-1-12-3; and first through n-th memory strings S1-S3 employing the first through n-th semiconductor layers 12-1-12-3 as channels. The i-th memory string Si (i is one of 1-n) includes on a surface of the i-th semiconductor layer 12-i in a third direction, a plurality of charge storage layers 16 and a plurality of control gates 18, which correspond to a plurality of memory cells MC. In the i-th memory string, the charge storage layers 16 of at least two memory cells MC adjacent to each other in a second direction are bonded to each other. Further, among the plurality of control gates 18, a metal element 19 for increasing band offset of the plurality of charge storage layers 16 is added.
    • 要解决的问题:为了抑制电荷存储层中的电荷的横向位移。 解决方案:根据实施例的非易失性半导体存储器件包括:第一至第n半导体层(n为大于1的自然数)12-1-12-3; 以及采用第一至第n半导体层12-1-12-3作为通道的第一至第n存储器串S1-S3。 第i个存储器串Si(i是1-n之一)包括在第三方向上的第i个半导体层12-i的表面上,多个电荷存储层16和多个控制栅极18, 其对应于多个存储单元MC。 在第i个存储器串中,在第二方向上彼此相邻的至少两个存储单元MC的电荷存储层16彼此接合。 此外,在多个控制栅极18中,添加用于增加多个电荷存储层16的带偏移的金属元件19。 版权所有(C)2013,JPO&INPIT
    • 10. 发明专利
    • Nonvolatile semiconductor memory device
    • 非易失性半导体存储器件
    • JP2010080646A
    • 2010-04-08
    • JP2008246690
    • 2008-09-25
    • Toshiba Corp株式会社東芝
    • TAKASHIMA AKIRASHINGU MASAOYASUDA NAOKIMURAOKA KOICHI
    • H01L21/8247H01L27/115H01L29/788H01L29/792
    • H01L29/513H01L27/11568H01L29/4234H01L29/792
    • PROBLEM TO BE SOLVED: To improve both the leakage current characteristics in a high electric field region and of a low electric field region.
      SOLUTION: This nonvolatile semiconductor memory device includes a source region 110S and a drain region 110D formed apart from each other inside a semiconductor substrate 101; a first insulating film 102 formed on a channel region between the source region 110S and the drain region 110D; an electric charge storing layer 103 formed on the first insulating film 102; a second insulating film 104, which is formed on the electric charge storing layer 103 and includes a laminated structure, in which a first lanthanum aluminum silicate film and a first silicon oxide film or a first silicon oxynitriding film are stacked; and a control gate electrode 105 formed on the second insulating film 104.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提高高电场区域和低电场区域中的漏电流特性。 解决方案:该非易失性半导体存储器件包括在半导体衬底101内部彼此分开形成的源极区域110S和漏极区域110D; 形成在源极区域110S和漏极区域110D之间的沟道区域上的第一绝缘膜102; 形成在第一绝缘膜102上的电荷存储层103; 第二绝缘膜104,其形成在电荷存储层103上并且包括叠层结构,其中堆叠第一硅酸铝镧硅酸盐膜和第一氧化硅膜或第一氧氮化氮化膜; 以及形成在第二绝缘膜104上的控制栅电极105.版权所有(C)2010,JPO&INPIT