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    • 2. 发明专利
    • Polyimide film and method for producing the same
    • 聚酰亚胺膜及其制造方法
    • JP2014034590A
    • 2014-02-24
    • JP2012175013
    • 2012-08-07
    • Mitsui Chemicals Inc三井化学株式会社
    • SAKATA YOSHIHIROFUKUKAWA KENICHIOKAZAKI MASAKIURAGAMI TATSUNOBUMATSUDA TOSHINORIONO YOSUKEYAMASHITA WATARU
    • C08J5/18B29C41/12C08G73/10G02B5/20G02F1/1333H01L51/50H05B33/02
    • PROBLEM TO BE SOLVED: To provide a polyimide film and a method for producing the same, the film having high optical transparency and a small in-plane retardation.SOLUTION: A production method is provided for a polyimide film having overall light transmittance of 80% or more and an in-plane retardation of 10 nm or less. The method includes steps of: (a) applying a polyimide precursor-containing solution containing a polyimide precursor on a substrate; (b) heating a polyimide precursor film comprising the coating film of the polyimide precursor-containing solution until an imidization rate of the polyimide precursor reaches 90% or more and the residual amount of the solvent is reduced to 1 mass% or less; (c) peeling off the film obtained in step (b) from the substrate; and (d) heating the film obtained in step (c) again. In the step (d), a heating temperature of the film obtained in step (c) is controlled to be equal to or lower than the glass transition temperature of the polyimide.
    • 要解决的问题:为了提供一种聚酰亚胺膜及其制造方法,该膜具有高的光学透明度和小的面内延迟。解决方案:提供了一种制备方法,该聚酰亚胺膜的总透光率为80% 以上,面内延迟为10nm以下。 该方法包括以下步骤:(a)在基材上涂布含有聚酰亚胺前体的含聚酰亚胺前体溶液; (b)加热含有聚酰亚胺前体的溶液的涂膜的聚酰亚胺前体膜,直到聚酰亚胺前体的酰亚胺化率达到90%以上,溶剂的残留量为1质量%以下。 (c)从基板剥离步骤(b)中获得的膜; 和(d)再次加热步骤(c)中获得的膜。 在步骤(d)中,将步骤(c)中获得的膜的加热温度控制在等于或低于聚酰亚胺的玻璃化转变温度。
    • 3. 发明专利
    • Method for manufacturing polyimide film
    • 制备聚酰亚胺膜的方法
    • JP2012233021A
    • 2012-11-29
    • JP2011100333
    • 2011-04-28
    • Mitsui Chemicals Inc三井化学株式会社
    • MATSUDA TOSHINORIONO YOSUKEKAGAYAMA AKISHISAKATA YOSHIHIROYAMASHITA WATARUFUKUKAWA KENICHI
    • C08J5/18C08G73/10
    • PROBLEM TO BE SOLVED: To provide a method for manufacturing a polyimide film, which does not cause appearance defects and a decrease in strength, and whitening and the like involved in the imidization reaction.SOLUTION: The method for manufacturing a polyimide film includes: (a) a step of coating on a support a polyamic acid-containing solution obtained by reacting a specific tetracarboxylic dianhydride with a specific diamine in a solvent; (b) a step of drying the solvent in the polyamic acid-containing solution at a temperature of 150°C or lower until a polyamic acid-containing film composed of a coating film of the polyamic acid-containing solution becomes tack-free; (c) a step of peeling the polyamic acid-containing film from the support; and (d) a step of fixing and heating the polyamic acid-containing film while the temperature is being raised from 150°C or lower to imidize the polyamic acid to thereby obtain the polyimide film.
    • 要解决的问题:提供一种不引起外观缺陷和强度降低的方法,以及涉及酰亚胺化反应的美白等。 聚酰亚胺膜的制造方法包括:(a)在载体上涂布通过使特定的四羧酸二酐与特定的二胺在溶剂中反应得到的含聚酰胺酸的溶液的工序; (b)在150℃以下的温度下干燥含有聚酰胺酸的溶液中的溶剂,直到由含聚酰胺酸的溶液的涂膜组成的含聚酰胺酸的膜变得无粘性的步骤; (c)从载体剥离含聚酰胺酸的膜的步骤; 和(d)在将温度从150℃以上升温至聚酰胺酸酰亚胺化的同时,对含有聚酰胺酸的膜进行固定加热的步骤,得到聚酰亚胺膜。 版权所有(C)2013,JPO&INPIT