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1. 发明专利

JP5574745B2 Calcium phosphate-based water purification material and manufacturing method thereof 有权
公开(公告)号：JP5574745B2
公开(公告)日：2014-08-20
申请号：JP2010037729
申请日：2010-02-23
申请人：幸雄柳沢 , 章弘山崎 , 淳飯塚 , 潔野中 , 裕香酒井 , 日本コンクリート工業株式会社
发明人：幸雄柳沢 , 章弘山崎 , 淳飯塚 , 潔野中 , 裕香酒井 , 雅人本間
IPC分类号： C02F1/42 , B01J20/04 , B01J20/30 , B01J39/12 , C01B25/32 , C01F11/46

2. 发明专利

JP5461802B2 Dephosphorization material and dephosphorization equipment 有权
公开(公告)号：JP5461802B2
公开(公告)日：2014-04-02
申请号：JP2008208758
申请日：2008-08-13
申请人：幸雄柳沢 , 章弘山崎 , 淳飯塚 , 伍郎茂原 , 日本コンクリート工業株式会社
发明人：幸雄柳沢 , 章弘山崎 , 淳飯塚 , 伍郎茂原 , 康之早川
IPC分类号： C02F1/58 , B01D9/02 , C05B7/00

3. 发明专利

JP2010260015A Dephosphorizing material, dephosphorizing apparatus, and dephosphorizing by-product 有权
标题翻译：脱磷材料，去磷化装置和脱磷化副产物
公开(公告)号：JP2010260015A
公开(公告)日：2010-11-18
申请号：JP2009113860
申请日：2009-05-08
申请人： Atsushi Iizuka , Goro Mobara , Nippon Concrete Ind Co Ltd , Akihiro Yamazaki , Yukio Yanagisawa , 章弘山崎 , 日本コンクリート工業株式会社 , 柳沢幸雄 , 伍郎茂原 , 淳飯塚
发明人： YANAGISAWA YUKIO , YAMAZAKI AKIHIRO , IIZUKA ATSUSHI , MOBARA GORO
IPC分类号： C02F1/58 , B01D9/02 , C02F11/00
CPC分类号： C02F1/5236 , C02F2101/105 , C04B18/16 , C04B2111/00767 , Y02W30/91 , Y02W30/95
摘要： PROBLEM TO BE SOLVED: To provide a dephosphorizing material having an excellent reaction rate of a dephosphorizing treatment, readily removing phosphorus from wastewater containing phosphorus, and, moreover, being very easy to manufacture. SOLUTION: The dephosphorizing material is manufactured from concrete sludge produced by one of the processes of centrifugal molding of a concrete product, concrete manufacturing, cleaning of a concrete manufacturing apparatus, and cleaning of a concrete transport vehicle. The dephosphorizing material is used for the dephosphorizing treatment in a dephosphorizing apparatus 1 including a reaction tank 2 provided with a wastewater supply means 3, a dephosphorizing material supply means 4, and a recovering means 6. In the dephosphorizing apparatus 1, phosphorus is removed from the wastewater containing phosphorus like sewage, etc. on the basis of chemical equation: 10Ca 2+ +6PO 4 3- +2OH - →Ca 10 (PO 4 ) 6 (OH) 2 and a dephosphorizing by-product crystallized through the reaction is recovered by the recovering means 6. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供具有优异的脱磷处理反应速率的脱磷材料，容易从含有磷的废水中除去磷，而且非常容易制造。解决方案：脱磷材料由混凝土制品的离心成型，混凝土制造，混凝土制造装置的清洗和混凝土输送车辆的清洗之一制造的混凝土污泥制成。脱磷材料用于脱磷装置1的脱磷处理，脱磷装置1包括设置有废水供给装置3的反应槽2，脱磷材料供给装置4和回收装置6.在脱磷装置1中，基于化学方程式的含磷污水等废水：10Ca 2 + + 6PO 4 3 - + 2OH （OH）SB SB2和SBB2（SBB）（SB SB）4和/ 通过反应结晶的产物通过回收装置6回收。版权所有（C）2011，JPO＆INPIT

4. 发明专利

JP2010042365A Dephosphorizing material, dephosphorizing apparatus and dephosphorization by-product 有权
标题翻译：脱磷材料，脱磷装置和脱磷副产品
公开(公告)号：JP2010042365A
公开(公告)日：2010-02-25
申请号：JP2008208758
申请日：2008-08-13
申请人： Atsushi Iizuka , Goro Mobara , Nippon Concrete Ind Co Ltd , Akihiro Yamazaki , Yukio Yanagisawa , 章弘山崎 , 日本コンクリート工業株式会社 , 柳沢幸雄 , 伍郎茂原 , 淳飯塚
发明人： YANAGISAWA YUKIO , YAMAZAKI AKIHIRO , IIZUKA ATSUSHI , MOBARA GORO
IPC分类号： C02F1/58 , B01D9/02 , C05B7/00
摘要： PROBLEM TO BE SOLVED: To provide a dephosphorizing material and a dephosphorizing apparatus having excellent reaction rate of a dephosphorizing treatment and easily removing phosphorus from phosphorus-containing waste water, and to provide a dephosphorization by-product.
SOLUTION: The dephosphorizing apparatus 1 carries out the dephosphorization of the phosphorus-containing waste water using a dephosphorizing material prepared by classifying a pulverized concrete waste material into particles having ≤1 mm particle diameter and is provided with a reaction tank 2. The reaction tank 2 is provided with: a waste water supply means 3 for supplying the phosphorus-containing waste water; a dephosphorizing material supply means 4 for supplying the dephosphorizing material; a stirring means 5 for stirring the phosphorus-containing waste water and the dephosphorizing material; and a recovering means 6 for recovering crystallized material in the reaction tank 2. The phosphorus-containing waste water and the dephosphorizing material supplied into the reaction tank 2 are stirred, and in the reaction tank 2, the calcium phosphate is crystallized, phosphorus is removed from the phosphorus-containing waste water and calcium phosphate which is the crystallized dephosphorization by-product is recovered.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种具有优异的脱磷处理反应速度和容易从含磷废水中除磷的脱磷材料和脱磷装置，并提供脱磷副产物。脱磷装置1使用通过将粉碎的混凝土废料分级成粒径≤1mm的粒子而制备的脱磷材料，进行含磷废水的脱磷，并且设置有反应槽2。反应槽2设有：用于供给含磷废水的废水供给装置3; 用于供给脱磷材料的脱磷材料供给装置4; 用于搅拌含磷废水和脱磷材料的搅拌装置5; 以及回收装置6，用于回收反应槽2中的结晶物质。供给到反应槽2中的含磷废水和脱磷酸物质进行搅拌，在反应槽2中结晶化磷酸钙，除去磷从作为结晶脱磷副产物的含磷废水和磷酸钙中回收。版权所有（C）2010，JPO＆INPIT

5. 发明专利

JP2014148432A Process for producing calcium carbonate and apparatus for producing calcium carbonate 审中-公开
标题翻译：生产碳酸钙的方法和生产碳酸钙的装置
公开(公告)号：JP2014148432A
公开(公告)日：2014-08-21
申请号：JP2013017455
申请日：2013-01-31
申请人： Nippon Concrete Ind Co Ltd , 日本コンクリート工業株式会社 , Akihiro Yamazaki , 章弘山崎 , Atsushi Iizuka , 淳飯塚
发明人： YAMAZAKI AKIHIRO , IIZUKA ATSUSHI , HAYAKAWA YASUYUKI , HONMA MASAHITO , YOSHIDA HIROYUKI
IPC分类号： C01F11/18 , C02F11/00
摘要： PROBLEM TO BE SOLVED: To provide a process for producing calcium carbonate which enables production of calcium carbonate of high purity from concrete waste containing unsolidified cement fine particles.SOLUTION: The concrete waste is subjected to solid-liquid separation by solid-liquid separation means 2, and is separated into a cement-containing liquid, which includes at least a part of cement fine particles, and a solid content. Furthermore, the cement-containing liquid is supplied into a precipitation reaction tank 10 by cement-containing liquid supplying means 11, and carbon dioxide is supplied into the precipitation reaction tank 10 by carbon dioxide supplying means 14. Then, in the precipitation reaction tank 10, calcium contained in the cement-containing liquid and cement fine particles is reacted with carbon dioxide, and calcium carbonate is allowed to crystallize out on the surface of the cement fine particles. Further, the thus crystallized calcium carbonate is separated and recovered by calcium carbonate separation means 4.
摘要翻译：要解决的问题：提供一种生产碳酸钙的方法，其能够从含有未固化的水泥细颗粒的混凝土废料中制备高纯度的碳酸钙。解决方案：混凝土废料通过固液分离装置2进行固液分离并分离成包含水泥微粒的至少一部分的固含量的含水泥液体。此外，含水泥液体由含水泥液体供给单元11供给到析出反应槽10中，二氧化碳通过二氧化碳供给单元14供给到沉淀反应槽10.然后，在析出反应槽10 ，含水泥液体中含有的钙和水泥微粒与二氧化碳反应，使碳酸钙在水泥微粒表面析出。此外，这样结晶的碳酸钙由碳酸钙分离装置4分离和回收。

6. 发明专利

JP2013039551A Method for producing water cleaning material 有权
标题翻译：生产水清洗材料的方法
公开(公告)号：JP2013039551A
公开(公告)日：2013-02-28
申请号：JP2011179882
申请日：2011-08-19
申请人： Univ Of Tokyo , 国立大学法人東京大学 , Akihiro Yamazaki , 章弘山崎 , Tohoku Univ , 国立大学法人東北大学 , Yuka Sakai , 裕香酒井 , Nippon Concrete Ind Co Ltd , 日本コンクリート工業株式会社
发明人： YANAGISAWA YUKIO , YAMAZAKI AKIHIRO , IIZUKA ATSUSHI , SAKAI YUKA , SASAKI TAKESHI , HAYAKAWA YASUYUKI , HONMA MASAHITO
IPC分类号： B01J41/10 , B28C7/16 , C02F1/42
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a water cleaning material at low cost.SOLUTION: The hydration of a cement content is performed by mixing at least either of a concrete waste containing cement and a cement with water, dispersing at least one of cement and the concrete waste into water, and making the hydration reaction of the cement content progress. The cement content after hydration is separated into a cement hydrate and a hydration water by solid-liquid separation. The obtained cement hydrate being a solid content is heat-treated to obtain a water cleaning material. Since such a method for production of the water cleaning material does not need any particular facility or process, the elevation of production cost can be prevented. Further, since at least one of cement and the concrete waste, and water only are used as raw materials, the increase of raw material cost can also be prevented and thus, the water cleaning material can be produced at low cost.
摘要翻译：要解决的问题：提供一种以低成本制造水清洗材料的方法。解决方案：水泥含量的水化是通过将含水泥的混凝土废料和水泥中的至少一种与水混合，将至少一种水泥和混凝土废物分散在水中，并进行水合反应水泥含量进度。水合后的水泥含量通过固液分离分离成水泥水合物和水化水。将获得的固体含量的水泥水合物进行热处理以获得水清洗材料。由于这种用于生产水清洗材料的方法不需要任何特定的设备或工艺，因此可以防止生产成本的提高。此外，由于水泥和混凝土废料中的至少一种和水仅用作原料，因此也可以防止原材料成本的增加，从而可以低成本地生产水清洗材料。版权所有（C）2013，JPO＆INPIT

7. 发明专利

JP2010023007A Method and apparatus for treating waste water containing boron 审中-公开
标题翻译：用于处理含有硼的废水的方法和装置
公开(公告)号：JP2010023007A
公开(公告)日：2010-02-04
申请号：JP2008191200
申请日：2008-07-24
申请人： Atsushi Iizuka , Hironori Nagasawa , Akihiro Yamazaki , Yukio Yanagisawa , 章弘山崎 , 柳沢幸雄 , 寛規長澤 , 淳飯塚
发明人： YANAGISAWA YUKIO , YAMAZAKI AKIHIRO , IIZUKA ATSUSHI , NAGASAWA HIRONORI
IPC分类号： C02F1/469 , B01D61/44 , B01D61/46
摘要： PROBLEM TO BE SOLVED: To provide a method for treating waste water containing boron capable of sufficiently recovering a boron constituent without removing an anion of a coexisting strong acid in advance irrespective of the pH of waste water causing ionization of boric acid, and furthermore capable of recovering the boron constituent with low energy consumption by a compact apparatus.
SOLUTION: The method for treating waste water containing boron includes a process for generating a boric acid ion in the waste water by reacting the waste water containing boron with a hydroxide ion generated from a first bipolar membrane, a process for separating the boric acid ion from the waste water by passing the boric acid ion through an anion exchange membrane, a process for generating concentrated boric acid by reacting the boric acid ion passed through the anion exchange membrane with a hydrogen ion generated from a second bipolar membrane, and a process for recovering the concentrated boric acid.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种处理含硼能够充分回收硼成分的废水的方法，而不用预先排除引起硼酸离子化的废水的pH，而不去除共存强酸的阴离子，以及还能够通过紧凑的装置以低能量消耗来回收硼成分。解决方案：用于处理含硼废水的方法包括通过使含硼废水与由第一双极膜产生的氢氧根离子反应而在废水中产生硼酸离子的方法，用于分离硼的方法通过使硼酸离子通过阴离子交换膜从废水中除去酸离子，通过使通过阴离子交换膜的硼酸离子与由第二双极膜产生的氢离子反应产生浓缩硼酸的方法，以及回收浓缩硼酸的方法。版权所有（C）2010，JPO＆INPIT

8. 发明专利

JP5344987B2 Dephosphorization material, dephosphorization apparatus and dephosphorization by-product 有权
公开(公告)号：JP5344987B2
公开(公告)日：2013-11-20
申请号：JP2009113860
申请日：2009-05-08
申请人：幸雄柳沢 , 章弘山崎 , 淳飯塚 , 伍郎茂原 , 日本コンクリート工業株式会社
发明人：幸雄柳沢 , 章弘山崎 , 淳飯塚 , 伍郎茂原 , 康之早川
IPC分类号： C02F1/58 , B01D9/02 , C02F11/00
CPC分类号： C02F1/5236 , C02F2101/105 , C04B18/16 , C04B2111/00767 , Y02W30/91 , Y02W30/95
摘要： A dephosphorization material is formed from concrete sludge resulting from centrifugal casting of concrete products, production of concrete, cleaning of concrete production equipment, or cleaning of concrete transporting vehicles. The dephosphorization material is used for dephosphorization treatment by a dephosphorization apparatus that includes a single reaction tank provided with a wastewater supply means, a dephosphorization material supply mean, and a recovery means. The dephosphorization apparatus removes phosphorus from phosphorus-containing wastewater, such as sewage water, based on the formula 10Ca2++6PO43−+2OH−→Ca10(PO4)6(OH)2 and recovers through the recovery means a dephosphorization by-product that precipitates as crystals as a result of the reaction.

9. 发明专利

JP2011173045A Calcium phosphate water cleaning material and method for manufacturing the same 有权
标题翻译：磷酸钙水清洗材料及其制造方法
公开(公告)号：JP2011173045A
公开(公告)日：2011-09-08
申请号：JP2010037729
申请日：2010-02-23
申请人： Atsushi Iizuka , Nippon Concrete Ind Co Ltd , Kiyoshi Nonaka , Yuka Sakai , Akihiro Yamazaki , Yukio Yanagisawa , 章弘山崎 , 日本コンクリート工業株式会社 , 柳沢幸雄 , 裕香酒井 , 潔野中 , 淳飯塚
发明人： YANAGISAWA YUKIO , YAMAZAKI AKIHIRO , IIZUKA ATSUSHI , NONAKA KIYOSHI , SAKAI YUKA , HONMA MASAHITO
IPC分类号： C02F1/42 , B01J20/04 , B01J20/30 , B01J39/12 , C01B25/32 , C01F11/46
摘要： PROBLEM TO BE SOLVED: To provide a calcium phosphate water cleaning material and method for manufacturing the same, capable of attaining low-cost manufacture.
SOLUTION: For example, concrete waste, such as concrete waste material or concrete sludge, is mixed with phosphorus-containing water solution, such as phosphorus-containing waste water. By mixing them, calcium ion and hydroxide ion derived from concrete waste material reacts with phosphate ion derived from phosphorus-containing water solution. Hydroxyapatite which is calcium phosphate crystallized by this action is a primary component. The calcium phosphate water cleaning material uses concrete waste, thereby achieving low-cost manufacture. In addition, concrete waste material is naturally wasted and is effective as measures for environmental problems.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供能够实现低成本制造的磷酸钙水清洗材料及其制造方法。
解决方案：例如混凝土废料，如混凝土废料或混凝土污泥，与含磷废水等含磷水溶液混合。通过混合，来自混凝土废料的钙离子和氢氧根离子与磷含水溶液中的磷酸根离子反应。通过该作用结晶的磷酸钙的羟基磷灰石是主要成分。磷酸钙水清洗剂使用混凝土废料，从而实现低成本制造。此外，混凝土废料自然浪费，作为环境问题的措施也是有效的。版权所有（C）2011，JPO＆INPIT

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