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    • 63. 发明专利
    • MEMBRANE WITH HIGHER HYDROPHILIC NATURE
    • JPH0445831A
    • 1992-02-14
    • JP15116290
    • 1990-06-08
    • KURARAY CO
    • NAKAHARA SEIICHIOKAMOTO TAKEHIKO
    • B01D71/08B01D69/02B01D71/34B01D71/82
    • PURPOSE:To obtain such a separation membrane which can easily be made hydrophilic and does not change its performance by incorporating at least one kind of alginic acid and alginic acid salt in the production process of the separation membrane from hydrophobic polymers by dry-wet or wet method. CONSTITUTION:In the production process of a separation membrane from hydrophobic polymers such as polysulfone, polyether sulfone, polyaryl sulfone, polyvinylidene fluoride, polyamide imide, etc., by dry-wet or wet method, at least one kind of alginic acid and the salt of its derv. (partially methylesterified alginic acid, carbomethoxy alginic acid, etc.,) into the polymers above mentioned. The add amt. of alginic acid salt into the source liquid for spinning depends on the kind and concn. of hydrophobic polymers, fine-pore forming agent, swelling agent, and solvent, and the higher the concn. of these, the add amt. becomes the smaller. Thereby, a separation membrane comprising hydrophobic polymers can easily be made hydrophilic, and the obtd. membrane is excellent, showing no change in its performance after repeatedly dried.
    • 64. 发明专利
    • POROUS HOLLOW FIBER MEMBRANE
    • JPH03258330A
    • 1991-11-18
    • JP5934690
    • 1990-03-09
    • KURARAY CO
    • KOMATSU KENSAKUOKAMOTO TAKEHIKOKUSUDO OSAMU
    • B01D63/02B01D69/02B01D69/08B01D71/68D01D5/24D01F6/76
    • PURPOSE:To obtain a hydrophilic hollow fiber membrane having high water permeability, excellent fractionating property and small reduction of flux by forming such a porous structure comprising a dense layer of the inner surface and a reticular structure in a manner that the reticular structure partially has openings to give pores to the outer surface, and specifying the permeation rate for pure water to a certain value or larger. CONSTITUTION:The porous hollow fiber membrane contains 0.5-10% hydrophilic polymers (e.g. polyvinylpyrrolidone) to hydrophobic polymers (preferably, polysulfone or polyethersulfone). This membrane has a porous structure comprising 0.5-5mum-thick dense layer having fine pores of various shapes with 10-50% porosity and a reticular structure formed continuously to the dense layer. The outer surface of the membrane has pores with the maximum pore diameter of 0.5-5mum which are formed by partial opening of the reticular structure. The permeation rate for pure water of the membrane at 25 deg.C is specified to >=800l/m .hr.kg/cm . The obtd. porous hollow fiber membrane is excellent in water permeability and fractionating property, and moreover, it is hydrophilic.